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1.发明公开Procédé de conversion du gaz de synthèse en phase liquide 失效弗尔福亨zur Umsetzung von Synthesegas在flüssiger阶段
公开(公告)号：EP0753562A1
公开(公告)日：1997-01-15
申请号：EP96401465.8
申请日：1996-07-03
摘要： L'invention concerne un procédé de synthèse d'hydrocarbures essentiellement linéaires et saturés C 5+ à partir de gaz de synthèse, la phase gazeuse réactive circulant soit dans le sens descendant, soit dans le sens ascendant à travers une zone de réaction qui comprend un lit fixe de catalyseur, ledit procédé étant caractérisé en ce qu'il comprend la circulation ascendante à travers ladite zone d'une phase liquide inerte, avec une vitesse superficielle supérieure à 0,01 cm/s.
摘要翻译： 一种合成线性饱和度的新方法。 来自合成气的5C +烃，反应性气相上升或下降通过包含固定床催化剂的反应区。 该方法还具有惰性液体的上升流动。 以大于0.01cm / s的表观速度跨越反应区。
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公开(公告)号：EP0199475B2
公开(公告)日：1996-04-17
申请号：EP86302363.6
申请日：1986-03-27
发明人： Brophy, John Howard , Telford, Clive David , Font Freide, Josephus Johannes , Smith, David John Harry
CPC分类号： C01B3/386 , B01J8/20 , C01B2203/0261 , C01B2203/1011 , C01B2203/1041 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/1604 , C07C1/0485 , C07C1/06 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/18 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/46 , C07C2523/745 , C07C2523/75 , C07C2529/06 , C07C2529/87 , Y02E60/324 , Y02P20/52
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公开(公告)号：EP0455308A3
公开(公告)日：1992-01-08
申请号：EP91201048.5
申请日：1991-05-02
IPC分类号： C10G3/00
CPC分类号： B01J23/864 , B01J23/75 , B01J23/76 , B01J23/83 , B01J23/8913 , B01J35/08 , B01J37/0201 , B01J37/0213 , B01J37/08 , B01J37/18 , C07C1/06 , C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2523/83 , C07C2523/86 , C07C2523/89 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2300/1022 , C10G2300/703 , C10G2400/20 , Y02P20/52 , Y02P30/20
摘要： Hydrocarbons are prepared by a process in which a feed comprising methanol is contacted at elevated temperature and pressure with a catalyst comprising:
(i) a porous carrier material selected from the group comprising silica, alumina, and mixtures thereof; (ii) cobalt as a metal component deposited on the porous carrier; and (iii) a promoter selected from the group comprising zirconium, titanium, chromium, ruthenium, iron, magnesium, zinc, thorium and uranium. The feed may further comprise hydrogen or synthesis gas. In cases where the feed comprises both methanol and synthesis gas, methanol in the feed may be prepared from synthesis gas remaining after contact with the aforementioned catalyst.-
4.发明公开Process for reducing methane production and increasing liquid yields in Fischer-Tropsch reactions 失效一种用于减少甲烷产量，增加从费 - 托反应的液体产物的产率的过程。
公开(公告)号：EP0321616A1
公开(公告)日：1989-06-28
申请号：EP87311323.7
申请日：1987-12-22
IPC分类号： C07C1/06
CPC分类号： C07C1/06 , C07C2521/06 , C07C2523/46 , C07C2523/745 , C07C2523/75
摘要： A process for reducing methane formation and increasing liquid yields in Fischer-Tropsch processes for synthesizing hydrocarbons from CO and H₂ comprising adding water and/or an olefin to the top of the reactor bed or to the reactor feed at a point below 10% of the distance from the top to the bottom of the reactor bed and above a point 10% above the bottom of the reactor bed to the top of the reactor bed in an amount sufficient to reduce said methane formation, wherein the molar ratio of water (when employed) to CO is from about 0.1 to about 5.
摘要翻译： 一种用于减少甲烷的形成和增加在费 - 托工艺液体产率从CO和H2，其包含合成烃在点以下的10％中加入水和/或烯烃与反应器床的顶部或反应器进料过程 从顶部向反应器床底部和上方的点10％的反应器床的在（上量足以降低所述甲烷的形成，worin的水的摩尔比在使用时的底部到反应器床的顶部以上的距离 ），以CO为约0.1至约第五
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公开(公告)号：EP0188304A1
公开(公告)日：1986-07-23
申请号：EP86200070.0
申请日：1986-01-15
发明人： Bode, Dirk , Sie, Swan Tiong
CPC分类号： B01J23/75 , B01J23/864 , B01J23/8913 , C07C1/0425 , C07C1/0485 , C07C1/06 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/26 , C07C2523/46 , C07C2523/75 , Y10S208/95
摘要： A process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen wherein the feed is contacted at elevated temperature and pressure with a catalyst comprising 3-60 pbw cobalt, 0.1-100 pbw zirconium, titanium, chromium and/or ruthenium per 100 pbw of carrier, which catalyst is in the form of a fixed bed and has an external surface area S E and wherein together with the feed a hydrocarbon-containing liquid boiling above 100 °C is passed through the catalyst in a downward direction at such a superficial liquid flow velocity V s at the inlet of the bed that the product V s x S E is larger than 1.
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公开(公告)号：EP2867188A1
公开(公告)日：2015-05-06
申请号：EP13733197.1
申请日：2013-06-19
申请人： Chevron U.S.A. Inc.
发明人： THOMAS, David , TRAVIS, Rod , MOPPERT, Michael , KALLI, Christopher John , ELPHINGSTONE, Gerald M., Jr. , CHARLESWORTH, David L.
CPC分类号： C10L3/08 , C07C1/0485 , C07C1/06 , C07C1/12 , C07C7/148 , C10L3/104 , C25B1/04 , C25B15/08 , Y02E60/366 , Y02P20/132 , C07C9/04
摘要： A process for reducing the carbon oxide content in natural gas, by producing a carbon oxide containing natural gas from a geological formation through a natural gas delivery system; providing a reaction zone containing at least one catalyst suitable for hydrocarbon conversion in the natural gas delivery system; introducing hydrogen into the carbon oxide containing natural gas to form a reaction mixture; and passing the reaction mixture to the catalyst in the reaction zone to convert at least a portion of the carbon oxides in the natural gas to hydrocarbons.
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7.发明授权
公开(公告)号：EP2625156B8
公开(公告)日：2014-07-16
申请号：EP11773218.0
申请日：2011-10-05
发明人： MENZEL, Johannes , THIELERT, Holger
CPC分类号： C10L3/08 , B01J8/0453 , B01J8/0492 , C07C1/06 , C07C9/04
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公开(公告)号：EP0753562B1
公开(公告)日：1999-12-15
申请号：EP96401465.8
申请日：1996-07-03
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公开(公告)号：EP0627959B1
公开(公告)日：1997-04-16
申请号：EP93905653.7
申请日：1993-02-24
CPC分类号： B01D29/115 , B01D29/605 , B01D29/92 , B01D36/001 , B01J8/006 , B01J8/22 , C07C1/06 , C07C29/152 , C10G2/342 , Y02P20/52 , C07C31/04
摘要： A method of conducting a continuous multi-phase catalytic reaction such as the conversion of syngas to higher hydrocarbon fuels. Gaseous reactants are introduced via a gas permeable plate into a slurry which includes the product and a finely divided catalyst. The liquid product is separated from the remainder of the slurry by means of a filter unit including a filter member. A pressure differential is established across the filter member by means of a constant level device within the filter unit which maintains a level of filtrate within the filter unit below the level of the slurry. The slurry is maintained in a constant state of agitation by the introduction of the gaseous components as a steam of bubbles. Fluctuations in the pressure differential across the filter member prevent the filter member from clogging, and the gas space is above the filtrate and the slurry are in communication.
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公开(公告)号：EP0627959A1
公开(公告)日：1994-12-14
申请号：EP93905653.0
申请日：1993-02-24
CPC分类号： B01D29/115 , B01D29/605 , B01D29/92 , B01D36/001 , B01J8/006 , B01J8/22 , C07C1/06 , C07C29/152 , C10G2/342 , Y02P20/52 , C07C31/04
摘要： A method of conducting a continuous multi-phase catalytic reaction such as the conversion of syngas to higher hydrocarbon fuels. Gaseous reactants are introduced via a gas permeable plate into a slurry which includes the product and a finely divided catalyst. The liquid product is separated from the remainder of the slurry by means of a filter unit including a filter member. A pressure differential is established across the filter member by means of a constant level device within the filter unit which maintains a level of filtrate within the filter unit below the level of the slurry. The slurry is maintained in a constant state of agitation by the introduction of the gaseous components as a steam of bubbles. Fluctuations in the pressure differential across the filter member prevent the filter member from clogging, and the gas space is above the filtrate and the slurry are in communication.
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