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1.发明授权
公开(公告)号：EP0589588B2
公开(公告)日：2002-03-13
申请号：EP93307016.1
申请日：1993-09-06
CPC分类号： C07C45/517 , C07C1/20 , C07C37/08 , C07C45/53 , C07C2527/054 , Y02P20/52 , C07C49/08 , C07C15/44 , C07C39/04
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公开(公告)号：EP0873983B1
公开(公告)日：2002-02-06
申请号：EP98112218.7
申请日：1993-09-06
CPC分类号： C07C45/517 , C07C1/20 , C07C37/08 , C07C45/53 , C07C2527/054 , Y02P20/52 , C07C49/08 , C07C15/44 , C07C39/04
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公开(公告)号：EP0738698A3
公开(公告)日：1997-08-27
申请号：EP96202123.4
申请日：1993-09-06
CPC分类号： C07C45/517 , C07C1/20 , C07C37/08 , C07C45/53 , C07C2527/054 , Y02P20/52 , C07C49/08 , C07C15/44 , C07C39/04
摘要： A method for enhancing the selectivity of the decomposition of dicumyl peroxide to alpha methyl-styrene, phenol and acetone in the presence of an acidic catalyst comprises carrying out the decomposition at a temperature of from about 80 to 110 o C. A method for preparing phenol and acetone from the decomposition of CHP with an acidic catalyst comprises (a) decomposing CHP at a specific acidic catalyst concentration and temperature thereby forming a composition comprising phenol, acetone and dicumyl peroxide, (b) transferring dicumyl peroxide to a plug flow reactor wherein decomposition of dicumyl peroxide to phenol, acetone and AMS occurs at a lower acidic catalyst concentration and a higher temperature than the catalyst concentration and temperature in step (a).
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4.发明公开
公开(公告)号：EP0738698A2
公开(公告)日：1996-10-23
申请号：EP96202123.4
申请日：1993-09-06
CPC分类号： C07C45/517 , C07C1/20 , C07C37/08 , C07C45/53 , C07C2527/054 , Y02P20/52 , C07C49/08 , C07C15/44 , C07C39/04
摘要： A method for enhancing the selectivity of the decomposition of dicumyl peroxide to alpha methyl-styrene, phenol and acetone in the presence of an acidic catalyst comprises carrying out the decomposition at a temperature of from about 80 to 110 o C.
A method for preparing phenol and acetone from the decomposition of CHP with an acidic catalyst comprises (a) decomposing CHP at a specific acidic catalyst concentration and temperature thereby forming a composition comprising phenol, acetone and dicumyl peroxide, (b) transferring dicumyl peroxide to a plug flow reactor wherein decomposition of dicumyl peroxide to phenol, acetone and AMS occurs at a lower acidic catalyst concentration and a higher temperature than the catalyst concentration and temperature in step (a).摘要翻译： 在酸性催化剂存在下，提高二甲基过氧化物对α-甲基 - 苯乙烯，苯酚和丙酮的分解选择性的方法包括在约80-110℃的温度下进行分解。 用酸性催化剂从CHP分解制备苯酚和丙酮的方法包括（a）在特定酸性催化剂浓度和温度下分解CHP，从而形成包含苯酚，丙酮和过氧化二异丙苯的组合物，（b）将过氧化二异丙苯转移到 活塞式流动反应器，其中过氧化二异丙苯分解成苯酚，丙酮和AMS在较低的酸性催化剂浓度和比步骤（a）中的催化剂浓度和温度更高的温度下发生。
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公开(公告)号：EP2271607B1
公开(公告)日：2018-03-07
申请号：EP09732557.5
申请日：2009-04-16
发明人： NELSON, Mark, E. , SAMUILOVICH, Dykman, Arkady , VLADIMIROVICH, Zinenkov, Andrey , VLADIMIROVICH, Pinson, Victor , NIKOLAYEVICH, Grebenshchikov, Ilja
CPC分类号： C07C37/08 , C07C45/517 , C07C45/53 , C07C407/003 , C07C49/08 , C07C39/04 , C07C409/10
摘要： A method for producing phenol and acetone in a multi-stage process at an elevated temperature from a cumene hydroperoxide mixture comprising cumene, comprises the steps of: a) distilling an amount of cumene from the cumene hydroperoxide mixture until the cumene mass % is 0 to 7 mass % relative to the total mass of the cumene hydroperoxide mixture, b) reacting the cumene hydroperoxide mixture with an acid catalyst form to a second mixture comprising phenol, acetone and dicumyl peroxide in a first stage, and c) decomposing the second mixture in a second stage to produce phenol and acetone, wherein an amount of phenol approximately equal to the amount of distilled from the cumene hydroperoxide mixture is added to the cumene hydroperoxide mixture before the reacting step b). The amount of hydroxyacetone is reduced, thereby, improving the quality of commercial-grade phenol and the products made from the phenol.
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公开(公告)号：EP2197826B1
公开(公告)日：2011-12-28
申请号：EP08731360.7
申请日：2008-03-04
发明人： NELSON, Mark , SEDEREL, William, Lodewyk , DYCKMAN, Arkady, Samuilovich , GREBENSHCHIKOV, Ilya, Nikolaevich , PINSON, Viktor, Vladimirovich , ZINENKO, Andrey, Vladmirovich
CPC分类号： C07C45/517 , C07C37/08 , C07C45/53 , C07C49/08 , C07C39/04
摘要： A method for the production of phenol and acetone from a cumene hydroperoxide mixture comprises a first stage and a second stage and at least two serially connected reactors, wherein the first stage comprises decomposition of a cumene hydroperoxide mixture in the presence of a catalyst mixture to form a dicumyl peroxide mixture, and the second stage comprises formation of a phenol and acetone mixture from decomposition of the dicumyl peroxide mixture formed in the first stage, wherein, the first stage further comprises: a) forming a catalyst mixture by combining sulfuric acid and phenol in a weight ratio of from 2: 1 to 1 : 1000 in a catalyst formation reactor, b) holding the catalyst mixture in the catalyst formation reactor at a temperature of about 20 to 8OoC for about 1 to 600 minutes; and, c)adding the catalyst mixture to the cumene hydroperoxide mixture to form the phenol and acetone mixture. The proposed method permits a significant reduction in the yield of hydroxyacetone that causes deterioration in the quality of commercial phenol.
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7.发明公开Verfahren zur Singlet Sauerstoff Oxidation von organischen Substraten 审中-公开Verfahren zur Singlet Sauerstoff氧化von organischen Substraten
公开(公告)号：EP1403234A2
公开(公告)日：2004-03-31
申请号：EP03019797.4
申请日：2003-08-30
发明人： Emsenhuber, Martin , Kwant, Gerard , van Straaten, Koenraad , Janssen, Madelon , Alsters, Paul , Hoving, Hendrik
IPC分类号： C07B33/00 , C07C409/04
CPC分类号： C07C45/53 , C07B33/00 , C07C45/517
摘要： Verbessertes Verfahren zur Oxidation von organischen Substraten mittels 1 O 2 , bei welchem wasserlösliche, oder in mit Wasser mischbaren organischen Lösungsmitteln lösliche, organische Substrate, die mit 1 O 2 reagieren, in einem mit Wasser mischbaren organischen Lösungsmittel, in Wasser oder in einem Gemisch aus Wasser und mit Wasser mischbaren organischem Lösungsmittel in Gegenwart eines heterogenen oder homogenen Katalysators mit 3-90%igem H 2 O 2 versetzt werden, worauf anschließend an die katalytische Zersetzung von H 2 O 2 zu Wasser und 1 O 2 die Oxidation der Substrate zu den entsprechenden Oxidationsprodukten erfolgt, wobei während der Reaktion Wasser selektiv mittels Membranen aus dem Reaktionsgemisch entfernt wird.
摘要翻译： 有机底物用黑暗的单线态氧（1O 2）改善氧化是通过在水和/或与3-90％过氧化氢的水混溶性溶剂中处理水溶性或水混溶性的有机溶剂的有机底物， 非均相或均相催化剂，使得过氧化物被催化分解成水和10 2氧化底物，水在反应期间被膜选择性地除去。
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8.发明授权
公开(公告)号：EP0589588B1
公开(公告)日：1999-01-20
申请号：EP93307016.1
申请日：1993-09-06
CPC分类号： C07C45/517 , C07C1/20 , C07C37/08 , C07C45/53 , C07C2527/054 , Y02P20/52 , C07C49/08 , C07C15/44 , C07C39/04
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公开(公告)号：EP0873983A2
公开(公告)日：1998-10-28
申请号：EP98112218.7
申请日：1993-09-06
CPC分类号： C07C45/517 , C07C1/20 , C07C37/08 , C07C45/53 , C07C2527/054 , Y02P20/52 , C07C49/08 , C07C15/44 , C07C39/04
摘要： A method for enhancing the decomposition of CHP to phenol and acetone which comprises having additional water in the CHP decomposition reactor.
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公开(公告)号：EP1142855B1
公开(公告)日：2005-08-31
申请号：EP01112781.8
申请日：1993-09-06
CPC分类号： C07C45/517 , C07C1/20 , C07C37/08 , C07C45/53 , C07C2527/054 , Y02P20/52 , C07C49/08 , C07C15/44 , C07C39/04
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