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公开(公告)号：EP0249914B1
公开(公告)日：1991-05-15
申请号：EP87108553.6
申请日：1987-06-13
申请人： UOP
CPC分类号： C07C5/2708 , C07C5/2702 , C07C5/2705 , C07C5/2724 , Y02P20/52 , C07C15/067
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公开(公告)号：EP0120877A1
公开(公告)日：1984-10-10
申请号：EP83902907.0
申请日：1983-09-26
IPC分类号： C07C5
CPC分类号： C07C5/2705 , C07C5/2735 , Y02P20/52 , C07C15/02 , C07C15/08
摘要： Le procédé d'isomérisation d'alkylbenzène, en particulier des xylènes, est basé sur l'application d'un catalyseur qui comprend un support d'oxyde inorganique contenant au moins un composé d'oxyde mélangé de SiO2 et Al2O3 dans n'importe quelle proportion; l'isomérisation est effectuée à une température comprise entre 150 et 300oC sous une pression allant de la pression atmosphérique à quelques atmosphères environ en présence d'un catalyseur ayant été produit par réaction du support avec un composé d'alkyle d'aluminium du type AlRyX3-y' où R est CH3, C2H5 ou C3H7, y vaut 1 ou 2 et X représente Cl, de préférence Al(C2H5)Cl2. Le support peut être imprégné avec du platine et/ou du rhénium. Ce procédé d'isomérisation se caractérise en ce qu'il peut avoir lieu sans promoteur, et en ce que l'isomérisation du xylène dans des conditions modérées donne un degré élevé de conversion et une grande sélectivité. Il a été démontré à l'aide d'exemples que le procédé peut avoir lieu dans des conditions de température allant de 150 à 300oC et sous une pression comprise entre la pression atmosphérique environ et quelques atmosphères, avec de 0 à 30 % d'éthylbenzène dans la matière première d'alimentation et avec ou sans dilution de la matière première d'alimentation avec du toluène. Le procédé s'applique particulièrement bien à la conversion de méta-xylène en orthoxylène et en para-xylène. Des exemples de production du catalyseur sont également donnés.
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公开(公告)号：EP0042226B1
公开(公告)日：1984-08-08
申请号：EP81302343.9
申请日：1981-05-27
CPC分类号： B01J29/7023 , B01J29/7246 , C01B39/48 , C07C5/2705 , C07C5/2708 , Y02P20/52 , Y10S423/36 , C07C15/02
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公开(公告)号：EP0042226A1
公开(公告)日：1981-12-23
申请号：EP81302343.9
申请日：1981-05-27
CPC分类号： B01J29/7023 , B01J29/7246 , C01B39/48 , C07C5/2705 , C07C5/2708 , Y02P20/52 , Y10S423/36 , C07C15/02
摘要： A new zeolite material designated EU-1 having a molar composition expressed by the formula:
wherein R is a monovalent cation or '/n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, gallium or boron, and H 2 0 is water of hydration additional to water notionally present when R is H, and having an X-ray pattern substantially as set out in Tables 1 and 2 is prepared from a reaction mixture containing XO 2 (preferably silica], Y 2 O 3 (preferably alumina) and a dicationic alkylated polymethylene diamine. The new zeolite is useful in catalytic processes, especially xylenes isomerisation.-
5.发明公开System and method for rejecting heat from equipment via endothermic isomerization 审中-公开系统和方法，用于通过吸热异构化输送的热量从设备
公开(公告)号：EP2298646A2
公开(公告)日：2011-03-23
申请号：EP10177204.4
申请日：2010-09-16
CPC分类号： B64D37/34 , B01J8/0285 , B01J2208/00132 , B01J2208/065 , B64D13/00 , B64D33/08 , B64D2013/0614 , B64D2013/0633 , C07C5/2705 , C07C5/2721 , C07C2521/06 , C07C2527/126 , C07C2527/133 , F02C7/12 , F28D7/1607 , F28D21/00 , F28F13/003 , C07C9/16
摘要： A heat exchanger (107) is configured to receive an elevated-temperature process fluid and an isomerization compound (109) capable of endothermic isomerization. When the system is in operation, heat from the elevated temperature process fluid is transferred to the isomerization compound and the isomerisation compound endothermically isomerizes to a higher energy state from. Thus, in a vehicle including an engine and a body, the body houses a catalytic heat exchanger having an output in fluid communication with the engine, and a pump for urging an isomerization compound into the heat exchanger and a sink controller for controlling the pump are provided.
摘要翻译： 的热交换器（107）被配置为接收在升高的温度的过程流体，并在异构化化合物（109），其能够吸热异构化。 当系统处于运行中，从升温过程流体的热被转移到异构化化合物和所述异构化化合物吸热异构化为从较高能量状态。 因此，在车辆包括发动机和一个本体，所述本体容纳具有在与所述发动机流体连通输出催化热交换器，以及用于推压上异构化化合物到热交换器和用于控制泵是宿控制器的泵 提供。
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6.发明公开Process for the preparation of a paraffin isomerisation catalyst 审中-公开Verfahren zur Herstellung von Isomerisationskatalysatoren
公开(公告)号：EP1792650A1
公开(公告)日：2007-06-06
申请号：EP06022965.5
申请日：2006-11-03
申请人： Haldor Topsoe A/S
CPC分类号： B01J21/066 , B01J21/04 , B01J23/6527 , B01J35/002 , B01J37/0018 , B01J37/0045 , C07C5/2705 , C07C2521/04 , C07C2521/06 , C07C2523/30 , C07C2523/44 , C10G45/62 , C07C9/16
摘要： Process for preparation of a paraffin isomerisation catalyst comprising a mixture of a Group IVB metal oxide, a Group VIB metal oxide, a Group IIIA metal oxide and a Group VIII metal, the process comprising the steps of
(a) contacting a hydroxide of the Group IVB metal with an aqueous solution of an oxyanion of the Group VIB metal to provide a mixture,
(b) drying the mixture to provide a dry powder,
(c) kneading the powder with a Group IIIA hydroxide gel and a polymeric cellulose ether compound to form a paste,
(d) shaping the paste to form a shaped material,
(e) calcining the shaped material to form a calcined material,
(f) impregnating the calcined material with an aqueous solution of a Group VIII metal salt to provide the catalyst, and
(g) calcining the catalyst.摘要翻译： 制备包含IVB族金属氧化物，VIB族金属氧化物，IIIA族金属氧化物和VIII族金属的混合物的链烷烃异构化催化剂的方法，该方法包括以下步骤：（a）使本组 IVB金属与第VIB族金属的氧阴离子的水溶液以提供混合物，（b）干燥该混合物以提供干燥粉末，（c）将该粉末与IIIA族氢氧化物凝胶和聚合物纤维素醚化合物捏合至 形成糊状物，（d）使糊状物成形以形成成型材料，（e）煅烧成形材料以形成煅烧材料，（f）用第VIII族金属盐水溶液浸渍煅烧材料，以提供催化剂 ，和（g）煅烧催化剂。
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公开(公告)号：EP0249914A1
公开(公告)日：1987-12-23
申请号：EP87108553.6
申请日：1987-06-13
申请人： UOP
CPC分类号： C07C5/2708 , C07C5/2702 , C07C5/2705 , C07C5/2724 , Y02P20/52 , C07C15/067
摘要： Xylene isomerization is carried out using specific non-zeolitic molecular sieve catalyst, e.g., the silicoaluminophosphate molecular sieves of U.S. Patent No. 4.440.871, to provide improved production of p-xylene from C 8 aromatic compounds and the conversion of ethylenbenzene to a xylene.
摘要翻译： 使用特定的非沸石分子筛催化剂，例如美国专利号4.440.871的硅铝磷酸盐分子筛进行二甲苯异构化，从C8芳族化合物改进生产对二甲苯和将乙烯苯转化成二甲苯。
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公开(公告)号：EP0120877B1
公开(公告)日：1986-09-10
申请号：EP83902907.1
申请日：1983-09-26
IPC分类号： C07C5/27 , C07C15/067
CPC分类号： C07C5/2705 , C07C5/2735 , Y02P20/52 , C07C15/02 , C07C15/08
摘要： The method is based on the application of a catalyst which comprises an inorganic oxide support containing at least one mixed oxide compound of SiO2 and Al2O3 in any proportion, and performing the isomerization at a temperature between 150 and 300o C under a pressure ranging from about atmospheric to a few atmospheres in the presence of a catalyst having been produced by reaction of the support with an aluminium alkyl compound of the type AlRyX3-y, wherein R = CH3, C2H5 or C3H7, y = 1 or 2 and X = Cl, preferably Al(C2H5)Cl2. The support may be impregnated with platinum and/or rhenium. Characteristic features of this method are that the isomerization process can be run without any promotor, and that isomerization of xylene under moderate conditions yields a high degree of conversion and high selectivity. It has been shown by means of examples that the process can be run within the temperature range 150 to 300o C and under a pressure of about atmospheric to a few atmospheres, with from 0 to 30% ethylbenzene in the feed stock and with or without dilution of the feed with toluene. The method is particularly well applicable to converting meta-xylene to ortho- and para-xylene. Also examples of production of the catalyst have been given.
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