公开(公告)号：EP2526129A1

公开(公告)日：2012-11-28

申请号：EP11700894.6

申请日：2011-01-19

申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC)

发明人： ALT, Helmut ,  ELAGAB, Hamdi Ali ,  AL-HUMYDI, Abdulaziz Hamad

IPC分类号： C08F10/00 ,  C08F4/64 ,  C08F4/649 ,  C08F10/02

CPC分类号： C08F10/00 ,  B01J2231/12 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/56 ,  C08F110/02 ,  C08F4/64013 ,  C08F4/68034 ,  C08F4/68224 ,  C08F2500/04

摘要： The invention is directed to a process for the polymerization of ethylene in the presence of a catalyst comprising a Ti, Zr, Hf or V metal centre; and a ligand according to Formula (I), in which B = -CH
2 -, -CH
2 CH
2 -, -CH=CH-, 1,2-phenylene or 2,6-pyridyl, R
1, R
2 , R
3 ,R
4 may be independently of one other the same or different H, C
1 -C
4 alkyl radical, Br or Cl and X =NH, O or S; or a ligand containing a pyridine moiety or a N-allyl-2-benzimidazolyl ligand.

摘要翻译： 本发明涉及在含Ti，Zr，Hf或V金属中心的催化剂存在下聚合乙烯的方法; 和式（I）的配体，其中B = -CH 2 - ， - CH 2 CH 2 - ， - CH = CH-，1,2-亚苯基或2,6-吡啶基，R 1，R 2，R 3，R 4可以独立地 另一个相同或不同的H，C 1 -C 4烷基，Br或Cl和X = NH，O或S; 或含有吡啶部分或N-烯丙基-2-苯并咪唑基配体的配体。

公开(公告)号：EP1951764B1

公开(公告)日：2010-03-17

申请号：EP06827427.3

申请日：2006-11-02

申请人： Equistar Chemicals, LP

发明人： NAGY, Sandor

IPC分类号： C08F4/64 ,  C08F4/659 ,  C08F10/00

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F210/16 ,  Y10S526/901 ,  C08F4/6401 ,  C08F4/659 ,  C08F210/14 ,  C08F4/64013

摘要： A process for polymerizing an alpha-olefin is disclosed. The polymerization is performed in the presence of a catalyst system comprising a three-membered titanacycle. A wide variety of titanacycles can be readily prepared, making this a versatile and inexpensive olefin polymerization process.

公开(公告)号：EP3194409A1

公开(公告)日：2017-07-26

申请号：EP15763347.0

申请日：2015-09-16

申请人： Versalis S.p.A.

发明人： PAMPALONI, Guido ,  RICCI, Giovanni ,  SOMMAZZI, Anna ,  MASI, Francesco ,  LEONE, Giuseppe

IPC分类号： C07F7/00 ,  C08F4/64 ,  C08F4/06

CPC分类号： C07F7/003 ,  C08F4/60013 ,  C08F4/64013 ,  C08F136/06 ,  C08F4/64044

摘要： Pyridine complex of zirconium having general formula (I): • Said pyridine complex of zirconium having general formula (I) may advantageously be used in a catalytic system for the (co)polymerization of conjugated dienes.

摘要翻译： 具有通式（I）的锆的吡啶络合物：·具有通式（I）的锆的所述吡啶络合物可有利地用于共轭二烯的（共）聚合的催化体系中。

公开(公告)号：EP0906321B1

公开(公告)日：2003-04-09

申请号：EP97924036.3

申请日：1997-05-27

申请人： Borealis Technology Oy

发明人： POLAMO, Mika ,  LESKELÄ, Markku ,  HAKALA, Kimmo ,  LÖFGREN, Barbro

IPC分类号： C07F9/00 ,  C07F11/00 ,  C07F7/00 ,  C07F19/00 ,  C08F4/64

CPC分类号： C07F7/006 ,  C08F10/00 ,  C08F10/02 ,  C08F2410/03 ,  C08F4/62 ,  C08F4/64013 ,  C08F4/64044 ,  C08F4/62044

公开(公告)号：EP1141043A1

公开(公告)日：2001-10-10

申请号：EP00955853.7

申请日：2000-08-23

申请人： BP Corporation North America Inc.

发明人： BAGHERI, Vahid ,  EISENBERG, David, C. ,  RATLIFF, Kevin, S. ,  BENDA, Ranier ,  LANIER, Carroll, W.

IPC分类号： C08F10/00 ,  C10G50/02 ,  B01J31/22 ,  B01J31/18 ,  C08F4/642 ,  C08F4/14 ,  C08F4/70

CPC分类号： C10M107/10 ,  B01J31/1805 ,  B01J31/2295 ,  B01J31/26 ,  C08F4/65908 ,  C08F4/65925 ,  C08F10/00 ,  C08F110/14 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2300/703 ,  C10G2400/10 ,  C10M141/00 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2205/028 ,  C10N2220/02 ,  C08F4/14 ,  C08F4/6592 ,  C08F4/65912 ,  C08F2500/02 ,  C08F4/64013 ,  C08F4/7006 ,  C08F4/7019

摘要： A multistep process for the selective production of an oligomer oil having predetermined properties in which the first step involves the polymerization of a feedstock containing one or more C3 to C20 1-olefins in the presence of a catalyst comprising a bulky ligand transition metal catalyst and in which a subsequent step involves the oligomerization of at least a preselected fraction of the product of the first step.

公开(公告)号：EP0805826A2

公开(公告)日：1997-11-12

申请号：EP96907020.0

申请日：1996-01-24

申请人： E.I. DU PONT DE NEMOURS AND COMPANY ,  THE UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL

发明人： JOHNSON, Lynda, Kaye ,  KILLIAN, Christopher, Moore ,  ARTHUR, Samuel, David ,  FELDMAN, Jerald ,  McCORD, Elizabeth, Forrester ,  McLAIN, Stephan, James ,  KREUTZER, Kristina, Ann ,  BENNETT, Margaret, Anne ,  COUGHLIN, Edward, Bryan ,  ITTEL, Steven, Dale ,  PARTHASARATHY, Anju ,  TEMPEL, Daniel, Joseph ,  BROOKHART, Maurice, S.

IPC分类号： C08F ,  C07C251 ,  C07F5 ,  C07F7 ,  C07F9 ,  C07F11 ,  C07F15 ,  C08F4 ,  C08F10 ,  C08F110 ,  C08F132 ,  C08F210 ,  C08F232 ,  C08G61 ,  C08J5 ,  C08L23 ,  C09D123 ,  C09J123 ,  C10M107 ,  C10M119 ,  C10M143

CPC分类号： C09J123/06 ,  C08F10/00 ,  C08F10/02 ,  C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F110/14 ,  C08F210/02 ,  C08F210/14 ,  C08F210/16 ,  C08F232/00 ,  C08L23/02 ,  C09J123/20 ,  C08F4/7006 ,  C08F4/64013 ,  C08F4/80 ,  C08F4/76 ,  C08F4/68034 ,  C08F4/69034

摘要： Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalysed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination of a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected $(a)-diimine nickel complexes with ethylene.

公开(公告)号：EP1789459B1

公开(公告)日：2014-04-30

申请号：EP05782880.8

申请日：2005-09-13

申请人： Ineos Sales (UK) Limited

发明人： GIBSON, Vernon, Charles ,  JACOBSEN, Grant, Berent ,  TOMOV, Atanas Kostadinov

IPC分类号： C08F210/18 ,  C08F4/68

CPC分类号： C08F210/18 ,  C08F10/00 ,  C08F4/69224 ,  C08F4/68224 ,  C08F210/06 ,  C08F232/00 ,  C08F2500/25 ,  C08F4/6925 ,  C08F4/69275 ,  C08F4/6825 ,  C08F4/68215 ,  C08F4/69215 ,  C08F4/69146 ,  C08F4/69034 ,  C08F4/64013

公开(公告)号：EP2666797A2

公开(公告)日：2013-11-27

申请号：EP12736323.2

申请日：2012-01-19

申请人： LG Chem, Ltd.

发明人： NOH, Kyung-Seop ,  LEE, Nan-Young ,  KIM, Won-Hee ,  AN, Sang-Eun ,  JEON, Sang-Jin ,  PARK, Cheon-Il ,  LEE, Choong-Hoon

IPC分类号： C08F297/08 ,  C08F220/16 ,  C08F4/6592

CPC分类号： C08F295/00 ,  C08F4/64013 ,  C08F4/65904 ,  C08F4/6592 ,  C08F210/16 ,  C08F297/08 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/14 ,  C08L23/142 ,  C08F4/64044 ,  C08F210/00

摘要： The present description relates to an olefin block copolymer having excellences in elasticity and heat resistance and its preparation method. The olefin block copolymer includes a plurality of blocks or segments, each of which includes an ethylene or propylene repeating unit and an α-olefin repeating unit at different weight fractions. The olefin block copolymer has a density of 0.85 to 0.92 g/cm 3 , and density X (g/cm 3 ) and TMA (Thermal Mechanical Analysis) value Y (°C) satisfy a defined relationship.

摘要翻译： 本发明涉及具有优异的弹性和耐热性的烯烃嵌段共聚物及其制备方法。 烯烃嵌段共聚物包括多个嵌段或链段，每个嵌段或链段各自包括乙烯或丙烯重复单元和不同重量分数的α-烯烃重复单元。 烯烃嵌段共聚物的密度为0.85〜0.92g / cm 3，密度X（g / cm 3）和TMA（热机械分析）值Y（℃）满足规定的关系。

公开(公告)号：EP1997834A1

公开(公告)日：2008-12-03

申请号：EP07252186.7

申请日：2007-05-29

申请人： Borealis Technology Oy

发明人： Bildstein, Benno ,  Kopacka, Holger ,  Enk, Barbara ,  Wurst, Klaus ,  Maaranen, Janne ,  Vanne, Tiina ,  Mansner, Erik ,  Kauhanen, Jurki

IPC分类号： C08F4/62 ,  C08F10/00 ,  C07F7/28 ,  C07F7/00 ,  C07F5/00 ,  C07F11/00 ,  C07F19/00

CPC分类号： C07C251/24 ,  C07C45/46 ,  C07C45/64 ,  C07C49/835 ,  C07C251/00 ,  C07C2601/10 ,  C07F11/005 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F2410/03 ,  C08F2420/04 ,  C07C49/798 ,  C08F4/52 ,  C08F4/6592 ,  C08F4/545 ,  C08F4/64013 ,  C08F4/64044 ,  C08F4/69112 ,  C08F4/64058 ,  C08F4/64048

摘要： An olefin polymerisation catalyst comprising:
(I) a complex comprising a ligand of formula (I)

coordinated (as shown) to a metal ion M; and
(II) a cocatalyst; or the reaction product thereof;

wherein each X which may be the same or different is NR 3 or O;
each Y which may be the same or different is C, S, P, S=O;
each R 1 which may be the same or different is hydrogen, an optionally substituted C 1-20 hydrocarbyl group, -CN, N(R 4 ) 2 , silyl, siloxy, -CF 3 , -SH, -C(=NR 4 )NR 4 R 4 , -NR 4 C(=O)R 4 , -NR 4 C(=NR 4 )R 4 , -NR 4 C(=NR 4 )NR 4 R 4 , -NR 4 C(=O)OR 4 , -NR 4 C(=O)NR 4 R 4 , -NR 4 S(O) 2 R 4 , -S(O) 2 NR 4 R 4 , -C(=S)NR 4 R 4 , -OC(=O)R 4 , -OC(=O)NR 4 R 4 , -OR 4 , optionally substituted heterocyclyl, or optionally substituted heteroaryl;
each R 2 which may be the same or different is an optionally substituted C 1-20 hydrocarbyl group, halo, silyl, siloxy, nitro, -CN, N(R 4 ) 2 , -CF 3 , -SH, C(=O)R 4 , OC(=O)R 4 , C(=O)OR 4 , -OC(=O)NR 4 R 4 , -OR 4 , optionally substituted heterocyclyl, or optionally substituted heteroaryl or two R 2 groups attached to adjacent ring atoms together form an optionally substituted 5- to 8-membered fused ring;
each R 3 which may be the same or different is hydrogen, or an optionally substituted C 1-20 hydrocarbyl group;
each R 4 which may be the same or different is a hydrogen, an optionally substituted C 1-20 hydrocarbyl group, or two R 4 groups taken together form an optionally substituted 5- to 8-membered fused ring;
a is 0 to 3;
b is 1 unless the atom Y to which R 1 is attached is P wherein b is 2.

摘要翻译： 一种烯烃聚合催化剂，其包含：（I）包含与金属离子M配位的（如图所示）的式（I）配位体的络合物; 和（II）助催化剂; 或其反应产物; 其中可以相同或不同的每个X是NR 3或O; C，S，P，S = O可以是相同或不同的Y。 每个R 1可以相同或不同，是氢，任选取代的C 1-20烃基，-CN，N（R 4）2，甲硅烷基，甲硅烷氧基，-CF 3，-SH，-C（= NR 4） ）NR 4 R 4，-NR 4 C（= O）R 4，-NR 4 C（= NR 4）R 4，-NR 4 C（= NR 4）NR 4 R 4，-NR 4 C（= O ）OR 4，-NR 4 C（= O）NR 4 R 4，-NR 4 S（O）2 R 4，-S（O）2 NR 4 R 4，-C（= S）NR 4 R 4， -OC（= O）R 4，-OC（= O）NR 4 R 4，-OR 4，任选取代的杂环基或任选取代的杂芳基; 每个R 2可以相同或不同，是任选取代的C 1-20烃基，卤素，甲硅烷基，甲硅烷氧基，硝基，-CN，N（R 4）2，-CF 3，-SH，C（= O ）R 4，OC（= O）R 4，C（= O）OR 4，-OC（= O）NR 4 R 4，-OR 4，任选取代的杂环基或任选取代的杂芳基或两个R 2基团 相邻的环原子一起形成任选取代的5至8元稠环; 每个R 3可以相同或不同，是氢或任选取代的C 1-20烃基; 每个可以相同或不同的R 4是氢，任选取代的C 1-20烃基，或两个R 4基团一起形成任选取代的5至8元稠环; a是0到3; b除非与R 1连接的原子Y是P，其中b是2，b是1。

公开(公告)号：EP1969022A1

公开(公告)日：2008-09-17

申请号：EP06839317.2

申请日：2006-12-12

申请人： DOW GLOBAL TECHNOLOGIES INC.

发明人： KARJALA, Teresa P. ,  YALVAC, Selim ,  RICKEY, Cynthia L. ,  DESJARDINS, Sylvie ,  SPRINGS, Marc A.

IPC分类号： C08F210/02

CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  C08L23/0815 ,  C08L51/06 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2308/00 ,  C08L2314/06 ,  C08F4/64 ,  C08L2666/24 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/01 ,  C08F4/64079 ,  C08F4/64013

摘要： The invention provides a comprising one or more ethylene interpolymers, and wherein the interpolymers, or the composition, has a melt viscosity from 1 to 30,000 cP at 177°C, and wherein at least one ethylene interpolymer has an Rv from 0.3 to 0.99. The invention further provides a composition comprising at least one low molecular weight (LMW) ethylene interpolymer, and at least one high molecular weight (HMW) ethylene interpolymer, and wherein the composition has a melt viscosity from 1 to 30,000 cP at 177°C, and wherein the sum of the Rv from the low molecular weight interpolymer and the high molecular weight interpolymer is from 0.3 to 2. The invention further provides for processes of making such compositions, processes for functionalizing the interpolymer(s) of such compositions, and articles comprising at least one component prepared from an inventive composition.