-
公开(公告)号:EP1776396B1
公开(公告)日:2008-11-05
申请号:EP05762803.4
申请日:2005-07-25
申请人: INEOS EUROPE LIMITED
IPC分类号: C08F10/00
CPC分类号: C08F10/02 , C08F10/00 , C08F110/02 , C08F4/022 , C08F4/69224 , C08F2500/01 , C08F4/64099 , C08F4/64089 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/69275 , C08F4/6925 , C08F4/69215 , C08F4/69034 , C08F4/69146
摘要: A polymerisation catalyst composition comprising (1) a transition metal compound of Formula (A), Z being 5-membered heterocyclic containing at least one carbon, at least one nitrogen and at least one of nitrogen, sulphur and oxygen, the others being nitrogen or carbon; M is a Group 3 to 11 metal or a lanthanide metal; E1 and E2 are divalent groups of aliphatic, alicyclic, aromatic or alkyl substituted aromatic hydrocarbon, or heterocyclic; D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integer such that X and L satisfy valency/oxidation state of M, (2) a catalyst-activating support which is a solid particulate substance, insoluble in hydrocarbons, comprising at least magnesium and aluminium atoms and hydrocarbyloxy groups containing 1 to 20 carbons atoms, the molar ratio of Mg/Al being in the range 1.0 to 300 and the molar ratio of hydrocarbyloxy groups to aluminium atoms being in the range 0.05 to 2.0, and optionally, (3) an additional activator selected from aluminium alkyl and boron compounds.
-
公开(公告)号:EP1789459A1
公开(公告)日:2007-05-30
申请号:EP05782880.8
申请日:2005-09-13
申请人: INEOS EUROPE LIMITED
IPC分类号: C08F210/18 , C08F4/622
CPC分类号: C08F210/18 , C08F10/00 , C08F4/69224 , C08F4/68224 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F4/6925 , C08F4/69275 , C08F4/6825 , C08F4/68215 , C08F4/69215 , C08F4/69146 , C08F4/69034 , C08F4/64013
摘要: Process for making copolymer (eg elastomeric copolymer) by copolymerising (1) ethylene with (2) at least one comonomer aliphatic C3-C20 alpha-olefins and (3) at least one C4 to C30 conjugated or non-conjugated dienes. The monomers are contacted with (a) a transition metal catalyst of Formula A, and (b) an activating quantity of a suitable activator, Z is five-membered heterocyclic group having at least one carbon atom, at least one nitrogen atom and at least one other hetero atom selected from nitrogen, sulphur and oxygen, the remaining atoms being nitrogen or carbon; M is a metal from Group 3 to 11 or lanthanide; E1 and E2 are divalent (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of said groups (i) to (v); D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are independently zero or integers such that the number of X and L groups satisfy the valency and oxidation state of the metal M.
-
公开(公告)号:EP1603957A1
公开(公告)日:2005-12-14
申请号:EP04721578.5
申请日:2004-03-18
IPC分类号: C08F10/02
CPC分类号: C08F136/06 , C08F4/63912 , C08F4/7006 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/639 , C08F4/69224 , C08F4/70 , C08F2500/04 , C08F2500/03 , C08F212/08 , C08F232/00 , C08F2500/25 , C08F220/00 , C08F210/14 , C08F4/69284 , C08F4/6925 , C08F4/69215 , C08F4/69146 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/68043 , C08F4/64089 , C08F4/64099 , C08F4/64093
摘要: A polymerisation catalyst comprising (1) a transition metal compound of Formula A, and optionally (2) an activating quantity of a Lewis acid activator, Formula (A), wherein Z is a five-membered heterocyclic group containing at least one carbon atom, at least one nitrogen atom and at least one other hetero atom selected from nitrogen, sulphur and oxygen, the remaining atoms in the ring being nitrogen or carbon; M is a metal from Group 3 to 11 of the Periodic Table or a lanthanide metal; E1 and E2 are divalent groups from (i) aliphatic hydrocarbon, (ii) alicyclic hydrocarbon, (iii) aromatic hydrocarbon, (iv) alkyl substituted aromatic hydrocarbon (v) heterocyclic groups and (vi) heterosubstituted derivatives of groups (i) to (v); D' and D2 are donor groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integers. The catalysts are useful for polymerising or oligomerising 1-olefins.
-
公开(公告)号:EP1789459B1
公开(公告)日:2014-04-30
申请号:EP05782880.8
申请日:2005-09-13
IPC分类号: C08F210/18 , C08F4/68
CPC分类号: C08F210/18 , C08F10/00 , C08F4/69224 , C08F4/68224 , C08F210/06 , C08F232/00 , C08F2500/25 , C08F4/6925 , C08F4/69275 , C08F4/6825 , C08F4/68215 , C08F4/69215 , C08F4/69146 , C08F4/69034 , C08F4/64013
-
公开(公告)号:EP1776396A1
公开(公告)日:2007-04-25
申请号:EP05762803.4
申请日:2005-07-25
申请人: INEOS EUROPE LIMITED
IPC分类号: C08F10/00
CPC分类号: C08F10/02 , C08F10/00 , C08F110/02 , C08F4/022 , C08F4/69224 , C08F2500/01 , C08F4/64099 , C08F4/64089 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/69275 , C08F4/6925 , C08F4/69215 , C08F4/69034 , C08F4/69146
摘要: A polymerisation catalyst composition comprising (1) a transition metal compound of Formula (A), Z being 5-membered heterocyclic containing at least one carbon, at least one nitrogen and at least one of nitrogen, sulphur and oxygen, the others being nitrogen or carbon; M is a Group 3 to 11 metal or a lanthanide metal; E1 and E2 are divalent groups of aliphatic, alicyclic, aromatic or alkyl substituted aromatic hydrocarbon, or heterocyclic; D1 and D2 are donor atoms or groups; X is an anionic group, L is a neutral donor group; n = m = zero or 1; y and z are zero or integer such that X and L satisfy valency/oxidation state of M, (2) a catalyst-activating support which is a solid particulate substance, insoluble in hydrocarbons, comprising at least magnesium and aluminium atoms and hydrocarbyloxy groups containing 1 to 20 carbons atoms, the molar ratio of Mg/Al being in the range 1.0 to 300 and the molar ratio of hydrocarbyloxy groups to aluminium atoms being in the range 0.05 to 2.0, and optionally, (3) an additional activator selected from aluminium alkyl and boron compounds.
-
公开(公告)号:EP1603957B1
公开(公告)日:2015-10-28
申请号:EP04721578.5
申请日:2004-03-18
CPC分类号: C08F136/06 , C08F4/63912 , C08F4/7006 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/639 , C08F4/69224 , C08F4/70 , C08F2500/04 , C08F2500/03 , C08F212/08 , C08F232/00 , C08F2500/25 , C08F220/00 , C08F210/14 , C08F4/69284 , C08F4/6925 , C08F4/69215 , C08F4/69146 , C08F4/68224 , C08F4/6825 , C08F4/68215 , C08F4/68043 , C08F4/64089 , C08F4/64099 , C08F4/64093
-
公开(公告)号:EP1918311A1
公开(公告)日:2008-05-07
申请号:EP06255605.5
申请日:2006-10-31
申请人: INEOS EUROPE LIMITED
CPC分类号: C08F36/04 , C08F10/00 , C08F2410/04 , C08F4/69224 , C08F4/7042 , C08F4/6925 , C08F4/68224 , C08F4/6825 , C08F4/69034 , C08F4/69146 , C08F4/69215 , C08F4/68215 , C08F4/64089
摘要: A process for producing homopolymers or copolymers of conjugated dienes comprising polymerising the diene monomer with a catalyst system comprising (A) two or more different transition metal compounds (B) a catalyst modifier (eg triphenyl phosphine) and optionally (C) one or more catalyst activators (eg MAO). The cis, trans and 1,2-vinyl microstructure of the produced diene polymer can be controlled.
摘要翻译: 一种生产共轭二烯均聚物或共聚物的方法,包括使二烯单体与催化剂体系聚合,所述催化剂体系包含(A)两种或更多种不同的过渡金属化合物(B)催化剂改性剂(例如三苯膦)和任选的(C)一种或多种催化剂 活化剂(如MAO)。 生产的二烯聚合物的顺式,反式和1,2-乙烯基微结构可以被控制。
-
-
-
-
-
-