EPOXY RESIN COMPOSITIONS
    2.
    发明授权

    公开(公告)号:EP3122734B1

    公开(公告)日:2018-01-31

    申请号:EP15709587.8

    申请日:2015-02-26

    申请人: Blue Cube IP LLC

    IPC分类号: C07D301/28 C08G59/02

    CPC分类号: C08G59/04 C07D301/28

    摘要: A process for preparing an aliphatic or cycloaliphatic epoxy resin composition including the steps of: (I) reacting a mixture of the following components: (a) an aliphatic or cycloaliphatic hydroxyl-containing material, (b) an epihalohydrin, (c) a stoichiometric excess of a base compound or basic acting substance, (d) a catalyst, and (e) optionally, a solvent; wherein the reacting step (I) is carried out under reaction conditions sufficient to form a crude aliphatic or cycloaliphatic epoxy resin composition product in the resultant reaction mixture; (II) neutralizing the resultant reaction mixture of step (I) containing the crude aliphatic or cycloaliphatic epoxy resin composition product with a phosphate neutralizing agent sufficient to partially neutralize the base or basic acting substance and to form a neutralized fluid medium containing aliphatic or cycloaliphatic epoxy resin composition product; (III) removing at least a portion of unreacted epihalohydrin from the reaction mixture of step (II); and (IV) subjecting the reaction mixture of step (III) above to a separation process to recover the aliphatic or cycloaliphatic epoxy resin composition product from the neutralized fluid medium; wherein the aliphatic or cycloaliphatic epoxy resin composition product yield is greater than about 70 percent.

    GLYCIDYLETHER VON LIMONEN-DERIVATEN UND DEREN OLIGOMERE ALS HÄRTBARE EPOXIDHARZE
    4.
    发明公开
    GLYCIDYLETHER VON LIMONEN-DERIVATEN UND DEREN OLIGOMERE ALS HÄRTBARE EPOXIDHARZE 审中-公开
    甘油三酯衍生物在低分子量低聚物环氧化物

    公开(公告)号:EP3033319A1

    公开(公告)日:2016-06-22

    申请号:EP14749745.7

    申请日:2014-07-30

    申请人: BASF SE

    摘要: Cured epoxy resins are widespread because of the excellent mechanical and chemical properties of cured epoxy resins. Epoxy resins based on bisphenol A diglycidyl ether or bisphenol F diglycidyl ether are usually used, but said epoxy resins are problematic for many fields because of the endocrine effect of said epoxy resins. The invention relates to glycidyl ethers of lime-based diols and/or polyols and curable epoxy resin compositions based on said glycidyl ethers as an alternative to bisphenol A diglycidyl ether or bisphenol F diglycidyl ether and the epoxy resin compositions based on bisphenol A diglycidyl ether or bisphenol F diglycidyl ether.

    摘要翻译: 固化环氧树脂由于其优异的机械和化学性质而广泛使用。 通常使用基于双酚A二缩水甘油醚或双酚F二缩水甘油醚的环氧树脂,但是由于它们对内分泌系统的影响,这些环氧树脂对许多部门是有问题的。 本发明涉及基于柠檬烯的二醇和/或多元醇的缩水甘油醚,以及基于其作为双酚A二缩水甘油醚或双酚F二缩水甘油醚的替代物的可固化环氧树脂组合物或其上的环氧树脂组合物。

    EPOXY COMPOUND HAVING ALKOXY SILYL GROUP, COMPOSITION COMPRISING SAME, CURED PRODUCT, USE THEREOF AND METHOD FOR PREPARING EPOXY COMPOUND HAVING ALKOXY SILYL GROUP
    6.
    发明公开
    EPOXY COMPOUND HAVING ALKOXY SILYL GROUP, COMPOSITION COMPRISING SAME, CURED PRODUCT, USE THEREOF AND METHOD FOR PREPARING EPOXY COMPOUND HAVING ALKOXY SILYL GROUP 审中-公开
    具有烷氧基甲硅烷基的环氧化合物,组合物含硬化产品,其用途和方法用于制备具有烷氧基甲硅烷A型环氧化合物

    公开(公告)号:EP2826777A4

    公开(公告)日:2015-11-25

    申请号:EP13760819

    申请日:2013-03-14

    摘要: The present invention relates to an alkoxy silyl-based epoxy compound exhibiting excellent heat resistant characteristics in a composite, and more particularly, exhibiting a low coefficient of thermal expansion (CTE) and the effect of significantly increasing the glass transition temperature in a composite and eliminating the necessity of a separate silane coupling agent. The present invention also relates to a composition comprising the compound, to a cured product thereof, to the use thereof and to a method for preparing an epoxy compound comprising an alkoxy silyl group. Thus, according to the present invention, provided are an epoxy compound comprising an epoxy group and an alkoxy silyl group, a composition comprising the epoxy compound and a curing agent, a filler and/or a reaction catalyst, a cured product thereof and the use thereof such as in an electronic component or the like. The epoxy composition comprising an epoxy compound having a novel alkoxy silyl group according to the present invention is obtained by a chemical bond resulting from a chemical reaction between the alkoxy silyl group and a filler (fiber and/or particle) and a chemical reaction between alkoxy silyl groups in a composite and/or a cured product, thus exhibiting effects of improved heat resistant characteristics, that is, a lower CTE and a higher glass transition temperature or no glass transition temperature (hereinafter, referred to as 'Tg-less') in an epoxy composite. Furthermore, the cured product comprising an epoxy compound having an alkoxy silyl group according to the present invention exhibits excellent flame resistance by introducing the alkoxy silyl group thereto.

    EPOXY RESIN COMPOSITIONS
    7.
    发明公开
    EPOXY RESIN COMPOSITIONS 审中-公开
    环氧树脂组合物

    公开(公告)号:EP2920224A1

    公开(公告)日:2015-09-23

    申请号:EP12888251.1

    申请日:2012-11-16

    IPC分类号: C08G59/32 C08G59/04 C08L63/00

    摘要: An epoxy resin composition including at least one epoxy resin having the Formula (I) where a is an integer from 0 to 5, x is an integer from 3 to 15, y is an integer from 5 to 30, is 0 or one, b is an integer from 3 to 10, c is an integer from one to 6, R
    1 is a C
    6 to C
    20 cycloalkylene group, and R
    2 is a saturated C
    2 to C
    20 aliphatic hydrocarbon group or a saturated C
    5 to C
    20 cycloaliphatic hydrocarbon group; a process for preparing the epoxy resin composition; and a curable coating composition comprising the epoxy resin composition.

    摘要翻译: 一种环氧树脂组合物,其包含至少一种具有式(I)的环氧树脂,其中a为0-5的整数,x为3-15的整数,y为5-30的整数,为0或1,b 是3至10的整数,c是1至6的整数,R 1是C 6至C 20亚环烷基,R 2是饱和C 2至C 20脂族烃基或饱和C 5至C 20脂环族烃基; 制备环氧树脂组合物的方法; 和包含环氧树脂组合物的可固化涂料组合物。

    EPOXY COMPOUND HAVING ALKOXY SILYL GROUP, COMPOSITION COMPRISING SAME, CURED PRODUCT, USE THEREOF AND METHOD FOR PREPARING EPOXY COMPOUND HAVING ALKOXY SILYL GROUP
    10.
    发明公开
    EPOXY COMPOUND HAVING ALKOXY SILYL GROUP, COMPOSITION COMPRISING SAME, CURED PRODUCT, USE THEREOF AND METHOD FOR PREPARING EPOXY COMPOUND HAVING ALKOXY SILYL GROUP 审中-公开
    具有烷氧基甲硅烷基的环氧化合物,组合物含硬化产品,其用途和方法用于制备具有烷氧基甲硅烷A型环氧化合物

    公开(公告)号:EP2826777A1

    公开(公告)日:2015-01-21

    申请号:EP13760819.6

    申请日:2013-03-14

    摘要: The present invention relates to an alkoxy silyl-based epoxy compound exhibiting excellent heat resistant characteristics in a composite, and more particularly, exhibiting a low coefficient of thermal expansion (CTE) and the effect of significantly increasing the glass transition temperature in a composite and eliminating the necessity of a separate silane coupling agent. The present invention also relates to a composition comprising the compound, to a cured product thereof, to the use thereof and to a method for preparing an epoxy compound comprising an alkoxy silyl group. Thus, according to the present invention, provided are an epoxy compound comprising an epoxy group and an alkoxy silyl group, a composition comprising the epoxy compound and a curing agent, a filler and/or a reaction catalyst, a cured product thereof and the use thereof such as in an electronic component or the like. The epoxy composition comprising an epoxy compound having a novel alkoxy silyl group according to the present invention is obtained by a chemical bond resulting from a chemical reaction between the alkoxy silyl group and a filler (fiber and/or particle) and a chemical reaction between alkoxy silyl groups in a composite and/or a cured product, thus exhibiting effects of improved heat resistant characteristics, that is, a lower CTE and a higher glass transition temperature or no glass transition temperature (hereinafter, referred to as 'Tg-less') in an epoxy composite. Furthermore, the cured product comprising an epoxy compound having an alkoxy silyl group according to the present invention exhibits excellent flame resistance by introducing the alkoxy silyl group thereto.

    摘要翻译: 本发明涉及一种在烷氧基的基于硅烷基的环氧化合物在复合表现出优异的耐热性的特性,并且更具体地,参展的热膨胀(CTE)系数低和在复合显着增加玻璃化转变温度和消除的效果 一个单独的硅烷偶联剂的必要性。 因此,本发明涉及一种组合物,其包含该化合物,涉及一种固化物,以使用和用于环氧化合物包括烷氧基甲硅烷基的的制备方法。 因此,雅丁到本发明中,提供的是在环氧化合物包括环氧基团,并在烷氧基甲硅烷基,组合物,包括环氧化合物和固化剂,填料和/或反应的催化剂,及其固化物以及使用 物:例如在电子元件或类似物。 的环氧组合物的环氧化合物,其包括具有新颖的烷氧基甲硅烷基雅丁到,本发明是通过化学键从烷氧基甲硅烷基和填料(纤维和/或颗粒)之间的化学反应产生的和烷氧基之间的化学反应而得到 甲硅烷基中的复合和/或固化产物,因此表现出的改善的耐热特性的影响,所做的是,较低的CTE和较高的玻璃化转变温度或没有玻璃化转变温度(在后,通过向称为“无Tg的”) 在环氧复合材料。 进一步,固化的产品,包括具有在烷氧基甲硅烷基雅鼎在本发明环氧化合物的通过引入烷氧基甲硅烷基于此表现出优异的阻燃性。