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    ADDITIVE COMPONENTS FOR LIQUID CRYSTALLINE MATERIALS
    3.
    发明公开
    ADDITIVE COMPONENTS FOR LIQUID CRYSTALLINE MATERIALS 有权
    添加剂成分液晶材料

    公开(公告)号：EP1689827A1

    公开(公告)日：2006-08-16

    申请号：EP04797266.6

    申请日：2004-11-25

    申请人： Rolic AG

    发明人： CHERKAOUI, Zoubair, Mohammed ,  LUKAC, Teodor ,  REICHARDT, Klaus ,  SCHMITT, Klaus

    IPC分类号： C09K19/58 ,  C09K19/20 ,  C09K19/12 ,  C09K19/18 ,  C09K19/34

    CPC分类号： C09K19/586 ,  C09K19/126 ,  C09K19/18 ,  C09K19/2007 ,  C09K19/2021 ,  C09K19/3405 ,  C09K19/3411 ,  C09K19/58 ,  C09K2019/0448 ,  Y10T428/10 ,  Y10T428/1036

    摘要： The present invention relates to mesogenic, cross-linkable mixtures comprising (i) a cross-linkable liquid crystalline host compound comprising at least one cross-linkable liquid crystalline compound, and (ii) at least one chiral or achiral rod shaped additive component, wherein said additive component has a rigid core and comprises at least two fused or linked, optionally substituted, non-aromatic, aromatic, carbocyclic or heterocyclic groups, and also comprises at least one optionally substituted alkyl residue, and at least one polymerizable group and wherein the additive component has a transition temperature to the isotropic state of 40°C or lower. The invention also relates to the novel chiral or achiral rod-shaped additive compounds used for the preparation of these mixtures, to mixtures according to the invention in form of an elastomer, polymer gel, polymer network or polymer film, to polymer networks and liquid crystalline polymer films prepared from these mixtures and to optical or electro­optical components comprising polymer networks and liquid crystalline polymer films prepared from such mixtures. Further, the invention relates to the use of the chiral or achiral rod shaped compounds as components of a cross-linkable liquid crystalline mixture in the production of orientated liquid crystalline polymers, to liquid crystalline mixtures comprising these compounds, to liquid crystalline polymers and liquid crystalline polymer networks prepared from such liquid crystalline mixtures, and to liquid crystalline devices comprising these compounds.

    Novel phenyl triester compound and anti-ferroelectric liquid crystal composition containing the same
    8.
    发明公开
    Novel phenyl triester compound and anti-ferroelectric liquid crystal composition containing the same 有权
    新型苯基三酯化合物和含有其的抗铁电液晶组合物

    公开(公告)号：EP0994097A3

    公开(公告)日：2000-09-06

    申请号：EP99119941.5

    申请日：1999-10-11

    申请人： MITSUBISHI GAS CHEMICAL COMPANY, INC.

    发明人： Motoyama, Yuki, Tokyo Fact.Mitsubishi Gas Chem.Co ,  Matsumoto,Takahiro, Tokyo Fact.Mitsubishi Gas Chem ,  Johno, Masahiro, Tokyo Fact.Mitsubishi Gas Chem.Co ,  Yui, Tomoyuki, Tokyo Fact.Mitsubishi Gas Chem.Co

    IPC分类号： C07C69/90 ,  C09K19/02 ,  C09K19/20

    CPC分类号： C09K19/0266 ,  C07C69/90 ,  C09K19/2021 ,  Y10T428/10

    摘要： An anti-ferroelectric liquid crystal composition comprising substantially a phenyl triester compound of the formula (1),    wherein R 1 is a linear alkyl group having 6 to 12 carbon atoms, m is an integer of 0 to 3, n is an integer of 1 to 3, and X 1 is a hydrogen atom or a fluorine atom, and an anti-ferroelectric liquid crystal compound of the formula (2),    wherein R 2 is a linear alkyl group having 6 to 12 carbon atoms, X 2 is a hydrogen atom or a fluorine atom, A is -CH 3 or -CF 3, r is 0 or 1 and C* is an asymmetric carbon, provided that when A is -CH 3 , r is 0 and p is an integer of 4 to 10, that when A is -CF 3 and when r is 0, p is an integer of 6 to 8, and further that when A is - CF 3 and when r is 1, q is an integer of 5 to 8 and p is 2 or 4. The present invention provides a novel phenyl triester compound, an anti-ferroelectric liquid crystal composition comprising the above phenyl triester compound is not only improved in response speed but also shows remarkably controlled layer rotation, and it can achieve a simple matrix liquid crystal display device which is free of a change in contrast and is highly reliable in use for a long period of time.

    摘要翻译： 一种反铁电液晶组合物，其基本上包含式（1）的苯基三酯化合物，其中R1是具有6-12个碳原子的直链烷基，m是0-3的整数，n是1至1的整数 3，X 1为氢原子或氟原子的化合物，以及式（2）的反铁电液晶化合物，其中R 2为具有6-12个碳原子的直链烷基，X 2为氢原子或氟 原子，A是-CH 3或-CF 3，r是0或1，且C *是不对称碳，条件是当A是-CH 3时，r是0且p是4至10的整数，当A是-CF 3 并且当r是0时，p是6到8的整数，而且当A是-CF 3并且当r是1时，q是5到8的整数并且p是2或4.本发明提供了一种新颖的 苯基三酯化合物，包含上述苯基三酯化合物的反铁电液晶组合物不仅响应速度提高，而且显示出明显的控制 可以实现简单的矩阵型液晶显示装置，该装置不会发生对比度变化，长期使用可靠性高。

    Ferrielectric liquid crystal compound
    9.
    发明公开
    Ferrielectric liquid crystal compound 有权
    Ferrielectric液晶化合物

    公开(公告)号：EP0994098A1

    公开(公告)日：2000-04-19

    申请号：EP99119047.1

    申请日：1999-09-29

    申请人： MITSUBISHI GAS CHEMICAL COMPANY, INC.

    发明人： Mine, Takakiyo ,  Johno, Masahiro ,  Yui, Tomoyuki

    IPC分类号： C07C69/94 ,  C09K19/20 ,  C09K19/02

    CPC分类号： C09K19/02 ,  C07C69/94 ,  C09K19/2021 ,  Y10T428/10

    摘要： A novel ferrielectric liquid crystal compound of the formula (1),
       wherein R is a linear alkyl group having 6 to 12 carbon atoms, X is a hydrogen atom or a fluorine atom, m is an integer of 1 to 3, n is an integer of 1 to 3, and C* is an asymmetric carbon atom. The ferrielectric liquid crystal compound of the invention characteristically has a ferrielectric phase in a broad temperature range and shows a high speed optical response in spite of a small spontaneous polarization.

    摘要翻译： 一种新的式（1）的铁电液晶化合物，其中R是具有6至12个碳原子的直链烷基，X是氢原子或氟原子，m是1至3的整数，n是整数 为1至3，且C *为不对称碳原子。 本发明的铁电液晶化合物的特征是在宽的温度范围内具有铁电相，尽管自发极化很小，但显示出高速的光学响应。

    Ferrielectric liquid crystal compound
    10.
    发明公开
    Ferrielectric liquid crystal compound 有权
    FerrielektrischeFlüssigkristallverbindung

    公开(公告)号：EP0974636A1

    公开(公告)日：2000-01-26

    申请号：EP99114143.3

    申请日：1999-07-20

    申请人： MITSUBISHI GAS CHEMICAL COMPANY, INC.

    发明人： Mine, Takakiyo, c/o Corporate Research Laboratory ,  Johno, Masahiro, c/o Corporate Research Laboratory ,  Yui, Tomoyuki, c/o Corporate Research Laboratory

    IPC分类号： C09K19/20 ,  C07C69/94

    CPC分类号： C09K19/2021 ,  C07C69/94 ,  Y10T428/10

    摘要： The present invention provides a ferrielectric liquid crystal compound represented by the following general formula (1),
    wherein R is a linear alkyl group having of 6 to 12 carbon atoms, X is a hydrogen atom or a fluorine atom, m is an integer of 1 to 3, n is an integer of 1 to 3, and C* is an asymmetric carbon atom.
    The ferrielectric liquid crystal compound of the present invention has a ferrielectric phase in a broad temperature range and shows a high speed response in spite of a small spontaneous polarization, and accordingly, it is very useful as a practical raw material for liquid crystal display device.

    摘要翻译： 本发明提供由以下通式（1）表示的电介质液晶化合物，其中R为碳原子数为6〜12的直链烷基，X为氢原子或氟原子，m为 1〜3的整数，n为1〜3的整数，C *为不对称碳原子。 本发明的电介质液晶化合物在宽温度范围内具有电介质相，尽管自发极化小，但显示出高速响应，因此作为液晶显示装置的实用原料是非常有用的。