摘要:
A process for the recovery of nickel and/or cobalt from a nickel and/or cobalt containing solution comprising: (i) contacting the nickel and/or cobalt containing solution with metallic particles of at least one metal that is more electronegative than nickel and/or cobalt thereby enabling a cementation process to occur between the nickel and/or cobalt in the solution and the metallic particles to produce a nickel and/or cobalt cementate; and (ii) separating the nickel and/or cobalt cementate from the metallic particles thereby producing a slurry including nickel and/or cobalt cementate.
摘要:
Une poudre de cobalt metallique de fines particules est preparee en traitant une solution aqueuse d'un halogenure d'amine cobaltique soluble avec une quantite suffisante d'un hydroxyde metallique soluble pour former un precipite contenant du cobalt. Le precipite est separe de la solution puis reduit dans une atmosphere reductrice pour produire du cobalt metallique.
摘要:
The invention relates to a method and apparatus for controlling a continuous metal removal in conjunction with a zinc preparation process, in which the metal removal is performed in one or more reactors (11a-c), in conjunction with the reactor, the redox potential (16a-c) and the acidity and/or basicity are measured, and based on the measurement results, the process variables (17a-c) of the metal removal are adjusted towards the desired direction. According to the invention, the redox potential measurements (16a-c) are performed from the sludge produced in the reactor in conjunction with the outlet pipe of the reactor outside the reactor, and the measuring instrument (16a-c) is purified at predetermined intervals.
摘要:
A process for recovering scandium economically with high efficiency by concentration and separation from an oxide ore containing nickel and a small amount of scandium as well as a large amount of iron and/or aluminum comprises the steps of acid leaching the oxide ore under a high-temperature, high-pressure oxidative atmosphere while restraining leaching of the iron and/or aluminum, thereby selectively leaching substantially all nickel and scandium from the ore, recovering the nickel from the resulting leaching solution as a precipitated sulfide while not precipitating the scandium as a sulfide but leaving the total amount thereof in the solution, and then adjusting the pH of the solution with a precipitant to recover the scandium from the solution as a high-concentration scandium hydroxide or carbonate by concentration and separation.
摘要:
Crystalline transition metal aluminates having to the formula where M is a transition metal having a valence of +2 selected from Cu, Zn, Mn, Fe, Co, and Ni, where AZ represents negative valence ions or radicals, v is a valence of -1, -2, or -3, n is a value to provide a mol ratio of Al/M of at least 1/1, and m is an integer of from zero to the maximum for waters of hydration, with (va)+(vb) equal to 2, are prepared in alkaline aqueous medium wherein transition metal compounds to form adducts with amorphous hydrous alumina, Al(OH) 3 , said adducts forming crystals when heated, said aluminates being useful as ion exchangers and as spinel precursors.
摘要:
A nickel recovery process capable of decreasing nickel remaining in a byproduct by recovering nickel from the byproduct of electrolytic nickel manufacturing process by chlorine-leaching, and also, capable of simplifying a cementation step simultaneously, is provided. In a nickel recovery step S60, a nickel recovery step S70 and a nickel recovery step S80, nickel is recovered in each step from S 0 slurry, residue flaker and chlorine-leached residue, which are byproducts of electrolytic nickel manufacturing process by chlorine-leaching, by using an aqueous solution containing 80 g/L to 390 g/L of chlorine and 30 g/L to 70 g/L of copper.