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    PROCESS FOR PRODUCING PERFLUOROALKYLSULFONIC ACID SALT
    1.
    发明公开
    PROCESS FOR PRODUCING PERFLUOROALKYLSULFONIC ACID SALT 审中-公开
    生产全氟烷基磺酸盐的方法

    公开(公告)号：EP2380873A1

    公开(公告)日：2011-10-26

    申请号：EP10726798.1

    申请日：2010-01-05

    申请人： Mitsubishi Materials Corporation ,  Mitsubishi Materials Electronic Chemicals Co., Ltd.

    发明人： HONDA, Tsunetoshi ,  YATSUYANAGI, Hiroyuki

    IPC分类号： C07C303/44 ,  C07C303/32 ,  C07C309/06 ,  C25B3/06

    CPC分类号： C07C303/44 ,  C25B3/08 ,  C07C309/06

    摘要： In this method for producing a perfluoroalkylsulfonic acid salt, there is provided a method for producing a perfluoroalkylsulfonic acid salt with a low fluorine content, which is a simple method to achieve a high yield,
    wherein a solution is formed by adding, to at least one compound selected from perfluoroalkylsulfonic acid salts represented by a general formula RfSO 3 •M (wherein Rf represents a perfluoroalkyl group of 1 to 4 carbon atoms, and M represents Li, Na or K), an organic solvent which is capable of dissolving the compound, and an adsorbent having a capacity to adsorb fluorine ions is added to the solution.

    摘要翻译： 在该全氟烷基磺酸盐的制造方法中，提供一种氟含量低的全氟烷基磺酸盐的制造方法，该方法是实现高收率的简便的方法，其中，通过将至少一种 选自由通式RfSO3·M（其中Rf表示1至4个碳原子的全氟烷基，M表示Li，Na或K）表示的全氟烷基磺酸盐的化合物，能够溶解该化合物的有机溶剂，以及 将具有吸附氟离子能力的吸附剂加入到溶液中。

    PROCESS FOR THE MANUFACTURE OF FLUOROOLEFINS
    2.
    发明授权
    PROCESS FOR THE MANUFACTURE OF FLUOROOLEFINS 有权
    氟树脂的生产工艺

    公开(公告)号：EP1183223B1

    公开(公告)日：2005-04-27

    申请号：EP00938098.1

    申请日：2000-06-02

    申请人： E.I. DU PONT DE NEMOURS AND COMPANY

    发明人： MANZER, Leo, E. ,  LUNDGREN, Cynthia, A.

    IPC分类号： C07C21/18 ,  C07C21/185 ,  C07C17/361 ,  C07C17/275 ,  C07C23/06 ,  C25B3/08

    CPC分类号： C25B3/08 ,  C07C17/275 ,  C07C17/361 ,  C07C21/18 ,  C07C21/185 ,  C07C23/06

    摘要： A process is disclosed for producing perfluoroolefins of the formula CF(R1f)=CF2, where R1f is F or CF3. The process involves (a) perfluorinating cyclobutanes of formula (I), where R2f is F or CF3, and where one R1 is H and the other R1 is H when R2f is F and is CH3 when R1f is CF3, by the Simons electrochemical fluorination process in an electrochemical cell in a solution of anhydrous liquid hydrogen fluoride under temperature and pressure conditions sufficient to replace all hydrogens in the cyclobutane of the above formula with fluorine; and (b) cracking the perfluorinated cyclobutane. A disclosed cracking involves contacting the perfluorinated cyclobutanes with carbon or a conductive metal, which is heated by induction heating to a temperature sufficient to crack the perfluorinated cyclobutanes.

    摘要翻译： 公开了一种制备式CF（R1f）= CF2的全氟烯烃的方法，其中R1f是F或CF3。 该方法包括：（a）通过Simons电化学氟化将式（I）的环丁烷全氟化，其中R 2f是F或CF 3，并且其中一个R 1是H，另一个R 1是H，当Rf是F时， 在电化学电池中在无水氟化氢溶液中在足以用氟取代上式的环丁烷中的所有氢的温度和压力条件下进行; 和（b）裂化全氟化环丁烷。 公开的裂化包括使全氟化环丁烷与碳或导电金属接触，所述导电金属通过感应加热加热至足以使全氟化环丁烷裂化的温度。

    ELECTROCHEMICAL FLUORINATION OF ALKANE SUBSTRATE
    3.
    发明公开
    ELECTROCHEMICAL FLUORINATION OF ALKANE SUBSTRATE 审中-公开
    的烷连接的电化学氟化

    公开(公告)号：EP1080251A1

    公开(公告)日：2001-03-07

    申请号：EP99914240.9

    申请日：1999-03-29

    申请人： MINNESOTA MINING AND MANUFACTURING COMPANY

    发明人： SMELTZER, John, C. ,  KOLPIN, Charles, F.

    IPC分类号： C25B3/08

    CPC分类号： C25B3/08

    摘要： Described is a process for the electrochemical fluorination of an alkane substrate, the process comprising the steps of: providing an alkane substrate comprising at least one carbon-bonded hydrogen; preparing a reaction solution comprising the alkane substrate and hydrogen fluoride; passing electric current through the reaction solution sufficient to cause replacement of one or more hydrogens of the alkane substrate with fluorine, the electric current being interrupted through a current cycle defined by current levels comprising an elevated current and a reduced current; wherein the current varies in such a manner that the resistance of the cell operated with interrupted current is lower than the resistance of the cell operated with non-interrupted current.

    PROCESS FOR PREPARING BRANCHED PERFLUOROCHEMICALS
    5.
    发明公开
    PROCESS FOR PREPARING BRANCHED PERFLUOROCHEMICALS 失效
    用于生产支化PERFLUOROVERBINDUNGEN

    公开(公告)号：EP0753085A1

    公开(公告)日：1997-01-15

    申请号：EP95912778.0

    申请日：1995-03-06

    申请人： MINNESOTA MINING AND MANUFACTURING COMPANY

    发明人： BEHR, Fredrick, E. ,  CHEBURKOV, Yuri ,  HANSEN, John, C. ,  ZHU, Dong-Wei

    IPC分类号： C25B3

    CPC分类号： C25B3/08

    摘要： A process for preparing inert or functional, tertiary carbon-containing perfluorochemicals comprises the step of electrochemically fluorinating, in the presence of anhydrous hydrogen fluoride, a composition comprising at least one starting compound selected from the group consisting of those fluoroalkanes, fluoroalkenes, fluoroalcohols, fluorocarboxylic acids, fluorocarboxylic acid halides, fluorocarboxylic acid esters, and combinations thereof which contain at least one (preferably, only one) -CX2-C(Rf)2- group, wherein each X is independently selected from the group consisting of hydrogen, fluorine, and CH2OH, with the proviso that only one X can be CH2OH, and each Rf group is independtly perfluoroalkyl. The process enables preservation of the highly-branched structure of the starting compounds resulting in high product yields.

    Process for preparing fluorochemicals
    6.
    发明公开
    Process for preparing fluorochemicals 失效
    制备氟化物的方法

    公开(公告)号：EP0643155A2

    公开(公告)日：1995-03-15

    申请号：EP94113544.4

    申请日：1994-08-30

    申请人： MINNESOTA MINING AND MANUFACTURING COMPANY

    发明人： Minday, Richard M., c/o Minnesota Mining and ,  Barrett, Thomas M., c/o Minnesota Mining and ,  Kolpin, Charles F., c/o Minnesota Mining and ,  Smeltzer, John C., c/o Minnesota Mining and

    IPC分类号： C25B3/08

    CPC分类号： C25B3/08

    摘要： A process for preparing fluorochemical compounds, e.g., perfluoroalkanes, perfluoroethers, and perfluoroalkyl tertiary amines, comprises

    (a) forming a mixture comprising at least one fluorinatable, non-functional organic starting compound, e.g., propane, and at least one other compound which is present in an amount sufficient to enable the formation of a fluorochemical phase and which is selected from the group consisting of

    (i) perfluorochemical compounds, e.g., perfluorohexane, which boil at a higher temperature than either the fluorinatable, non-functional organic starting compound or the fluorochemical compound resulting from the subsequent fluorination of the fluorinatable, non-functional organic starting compound; and
    (ii) precursor compounds, e.g., hexane, which can be fluorinated in situ to produce such perfluorochemical compounds; and

    (b) subjecting the mixture to electrochemical fluorination in the presence of anhydrous hydrogen fluoride.

    摘要翻译： 制备含氟化合物例如全氟烷烃，全氟醚和全氟烷基叔胺的方法包括（a）形成包含至少一种可氟化的非官能有机起始化合物例如丙烷和至少一种其它化合物的混合物，所述化合物是 其存在的量足以形成含氟化合物相并且选自（i）全氟化合物，例如全氟己烷，其在比可氟化的非官能有机起始化合物更高的温度下沸腾或 由可氟化的非官能有机起始化合物随后氟化得到的含氟化合物; 和（ii）前体化合物，例如己烷，其可就地氟化以产生此类全氟化合物; 和（b）使混合物在无水氟化氢存在下进行电化学氟化。

    Bipolar flow cell and process for electrochemical fluorination
    7.
    发明公开
    Bipolar flow cell and process for electrochemical fluorination 失效
    Bipolare Durchflusszelle und elektrochemisches Fluorierungsverfahren。

    公开(公告)号：EP0582192A1

    公开(公告)日：1994-02-09

    申请号：EP93112051.3

    申请日：1993-07-28

    申请人： MINNESOTA MINING AND MANUFACTURING COMPANY

    发明人： Childs, William V. ,  Klink, Frank W. ,  Smeltzer, John C. ,  Spangler, Jeffrey C.

    IPC分类号： C25B9/00 ,  C25B3/08

    CPC分类号： C25B9/063 ,  C25B3/08

    摘要： An electrochemical fluorination process comprises passing by forced convection a liquid mixture comprising anhydrous hydrogen fluoride and fluorinatable organic compound, e.g., tripropyl amine, at a temperature and pressure at which a substantially continuous liquid phase is maintained, between the electrodes (15) of a bipolar electrode stack (16). The bipolar electrode stack comprises a plurality of substantially parallel, spaced-apart electrodes (15) made of an electrically-conductive material, e.g., nickel, which is essentially inert to anhydrous hydrogen fluoride and which, when used as an anode, is active for electrochemical fluorination, and the electrodes of the stack are arranged in either a series or a series-parallel electrical configuration. The bipolar electrode stack has an applied voltage difference which produces a direct current which can cause the production of fluorinated organic compound, e.g., perfluoro(tripropyl amine). An electrochemical fluorination cell (11) which can be used for carrying out the process is also described.

    摘要翻译： 电化学氟化方法包括在两极的电极（15）之间，在保持基本上连续的液相的温度和压力下，通过强制对流使包含无水氟化氢和可氟化有机化合物（例如三丙胺）的液体混合物通过 电极堆叠（16）。 双极电极堆叠包括由导电材料（例如镍）制成的多个基本上平行的，间隔开的电极（15），其对于无水氟化氢基本上是惰性的，并且当用作阳极时，其用于 电化学氟化，并且堆叠的电极以串联或串联并联电构造布置。 双极电极堆叠具有施加的电压差，其产生可引起氟化有机化合物例如全氟（三丙胺）的直流电流。 还描述了可用于进行该方法的电化学氟化电池（11）。

    Perfluoroaminoethers
    9.
    发明公开
    Perfluoroaminoethers 失效

    公开(公告)号：EP0214852A2

    公开(公告)日：1987-03-18

    申请号：EP86306879.7

    申请日：1986-09-05

    申请人： MINNESOTA MINING AND MANUFACTURING COMPANY

    发明人： Moore, George G.I c/o MINNESOTA MINING AND ,  Hansen, John C. c/o MINNESOTA MINING AND

    IPC分类号： C07C217/00 ,  C07D211/38 ,  C07D265/30 ,  C25B3/08 ,  C09K5/00

    CPC分类号： C07D265/30 ,  C07D207/10 ,  C07D211/38 ,  C09K5/00 ,  C25B3/08

    摘要： Perfluoroaminoethers are provided. The per- fluoroaminoiethers have two or more tertiary amino nitrogen atoms each of which is connected to the other(s) adjacent thereto by (1) a catenary, ether oxygen-containing, perfluoroalkylene linking group the catenary carbon atoms of which are in the form of segments of vicinal carbon atoms that are 2 to 4 in number, said segments having up to 5 carbon atoms, a catenary ether oxygen-containing perfluorocyclohexylene linking group, or (3) a catenary ether oxygen-containing linking group having perfluoroalkylene and perfluorocyclohexylene moieties, the sum of the catenary ether oxygen atoms being 1 to 6.

    摘要翻译： 提供全氟氨基醚。 全氟氨基醚具有两个或更多个叔氨基氮原子，每个叔氨基氮原子通过（1）链，它们的链状碳原子以形式的含醚氧的全氟亚烷基连接基连接到与其相邻的其它邻位 的连接碳原子的数目为2至4的链段，所述链段具有至多5个碳原子，链状醚的含氧全氟环亚己基连接基团，或（3）具有全氟亚烷基和全氟亚环己基部分的链状醚的含氧连接基团 ，链状醚氧原子的总和为1至6。