摘要:
Even if ozone and hydrogen peroxide solution are simply mixed with water to be treated to perform oxidative destruction of harmful substances, such as dioxins, PCB and the like, it is difficult to decompose the harmful substances, with desired decomposing effects. It is an object of the present invention to provide an advanced water treatment process and system which are based on ozone treatment capable of providing more reliable treatment effects. To attain the above object, according to the present invention, ozone treatment is carried out in which minute bubbles of ozone having an average particle diameter of 0.5 to 3 mu m are brought into contact with water to be treated, which contains the harmful substances, such as dioxins and PCB. By carrying out a desired combination of the ozone treatment as an essential treatment, and a hydrogen peroxide treatment, an ultraviolet radiation treatment, an electrolysis treatment, and a carbonized filter medium treatment, it is possible to realize enhanced effectiveness of the water treatment.
摘要:
Die Erfindung betrifft ein Verfahren zur Aufarbeitung von alkalischen Abwässern, die bei der Wäsche von rohem Nitrobenzol entstehen, wobei das rohe Nitrobenzol
a) durch adiabate Nitrierung von Benzol mit Nitriersäure hergestellt, und anschließend b) in einer sauren Wäsche gewaschen, und anschließend c) in einer alkalischen Wäsche gewaschen wird, wobei ein alkalisches Abwasser enthaltend Benzol in Konzentrationen von 100 bis 3000 ppm und Nitrobenzol in Konzentrationen von 1000 bis 10000 ppm erhalten wird, dadurch gekennzeichnet, dass d) aus dem alkalischen Abwasser aus Schritt c) anschließend nicht gelöst vorliegendes Benzol und/oder Nitrobenzol abgeschieden wird, und e) optional aus dem alkalischen Abwasser aus Schritt d) anschließend restliches Benzol und/oder Nitrobenzol durch Strippen entfernt wird, und f) das alkalische Abwasser aus Schritt d) oder e) anschließend unter Ausschluss von Sauerstoff auf Temperaturen von 150 bis 500°C unter Überdruck erhitzt wird.
摘要:
In a method and an apparatus for cleaning tar-bearing waste water (17), a mixture of water and hydrocarbons, e.g. comprising polyaromatic hydrocarbons and phenols, the mixture is separated into a low-boiling-point part and a high-boiling-point part, bringing the low-boiling-point part on vapour form in a boiler (1), and the low-boiling-point part is cracked in vapour form at a high temperature in a reactor (2), providing light combustible gases, which can be utilised in e.g. gas engines, gas turbines or the like. Furthermore, the high-boiling-point part may be used for energy supply to the process or other processes or as an alternative be cracked for providing light combustible gases.
摘要:
Systems for treating water containing unwanted contaminants. Waste generated in toilet (1) and waste water generator (2) enters settling tank (3) and after a certain time enters distribution box (4) for distribution to leaching field (5). Apparatus (31) is used to add growing microbes, nutrients including carbon sources, and oxygen after the settling tank, but before the distribution box.
摘要:
In a method and an apparatus for cleaning tar-bearing waste water (17), a mixture of water and hydrocarbons, e.g. comprising polyaromatic hydrocarbons and phenols, the mixture is separated into a low-boiling-point part and a high-boiling-point part, bringing the low-boiling-point part on vapour form in a boiler (1), and the low-boiling-point part is cracked in vapour form at a high temperature in a reactor (2), providing light combustible gases, which can be utilised in e.g. gas engines, gas turbines or the like. Furthermore, the high-boiling-point part may be used for energy supply to the process or other processes or as an alternative be cracked for providing light combustible gases.
摘要:
A process for treating a solid-liquid mixture by cavitation has been developed to decompose at least some contaminant associated with the solid particles, the contaminant either being adsorbed into the pores of the solid or onto the surface of the solid particles. The process includes the step of subjecting the mixture to cavitation such that a portion of the contaminant is chemically decomposed. Typically the chemical decomposition occurs at the surface of the solid particles, although the process can also occur to some extent within the pores near the surface of the solid material being treated. Typically the cavitation process is an ultrasonic treatment step, although other cavitation processes are applicable, for example high shear mixing. The cavitation effect is capable of achieving physico-chemical changes at the particle surfaces. The localised high temperatures on bubble collapse (as high as 5000K) can decompose contaminant substances such as PCB and other hazardous materials including polybrominated biphenyl (PBB), organochloride and organophosphate compounds, pesticides and the like. One of the advantages of the treatment process is that the decomposition products are quenched quickly to the temperature of the bulk fluid (at, for example, 50oC) which avoids the reformation of the PCB or the formation of undesirable side reaction products such as dioxins.
摘要:
A process for extracting from aqueous solution the alkali metal or ammonium salt of a phenol, naphthol, anthrol or phenanthrol or the corresponding thiol, which comprises contacting an aqueous alkaline or neutral solution of the alkali metal or ammonium salt, in which is dissolved an alkali metal or ammonium fluoride, chloride, bromide, hydroxide, nitrate, nitrite, sulphate, sulphite, sulphide, thiosulphate, phosphate, hydrogen phosphate, carbonate, bicarbonate, cyanate, cyanide, thiocyanate, borate, chlorate, chlorite, hypochlorite, perchlorate, chromate, dichromate or permanganate, with a partially water-miscible organic solvent so as to transfer aqueous solution of the alkali metal or ammonium salt of the phenol, naphthol, anthrol or phenanthrol or corresponding thiol into the solvent while retaining separate aqueous and solvent phases, and thereafter separating the solvent phase containing the alkali metal or ammonium salt and water from the aqueous phase, the ratio of solvent to water in the separated solvent phase being from 0.5:1 to 10:1 w/w.