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    A reactor, a structures packing, and a method for improving oxidation of hydrogen sulfide or polysulfides in liquid sulfur
    1.
    发明公开
    A reactor, a structures packing, and a method for improving oxidation of hydrogen sulfide or polysulfides in liquid sulfur 有权
    电抗器，结构包装和一种用于改善硫化氢氧化或硫化物液体硫中

    公开(公告)号：EP2347995A1

    公开(公告)日：2011-07-27

    申请号：EP11000451.2

    申请日：2011-01-20

    申请人： Air Products and Chemicals, Inc.

    发明人： Diwakar, Garg ,  Xianming, Jimmy Li ,  Uday, Navin Parekh ,  Jung, Soo Chloe ,  Elmo, Nasato

    IPC分类号： C01B17/02 ,  C01B17/027

    CPC分类号： C01B17/027 ,  B01J19/32 ,  B01J2219/3221 ,  B01J2219/32227 ,  B01J2219/32408 ,  B01J2219/32425 ,  B01J2219/32466 ,  C01B17/0232

    摘要： Disclosed is a reactor, a structured packing, and a method for increasing the rate of decomposition of polysulfides and oxidation of polysulfides and hydrogen sulfide in liquid sulfur. The reactor, the structured packing, and the method involve a structured packing for contacting a first stream and a second stream in a reactor including a catalyst. The catalyst increases the rate of decomposition of polysulfides and oxidation of polysulfides and hydrogen sulfide in the liquid sulfur of the first stream with the second stream. The first stream includes liquid sulfur containing polysulfides and dissolved hydrogen sulfide. The second stream includes an oxygen-containing gas.

    摘要翻译： 本发明提供一种反应器，规整填料，以及用于在液体硫提高多硫化物的分解和多硫化物的氧化和硫化氢的速率的方法。 的反应器，规整填料，并且该方法包括用于接触第一物流和在反应器中包含催化剂的第二物流的规整填料。 催化剂增加多硫化物的分解和多硫化物的氧化和硫化氢与第二流的第一物流的液体硫的速率。 所述第一物流包括液体硫包含多硫化物和溶解的硫化氢。 所述第二物流包括含氧气体。

    Recovery of elemental sulphur from products containing contaminated elemental sulphur by froth flotation
    4.
    发明公开
    Recovery of elemental sulphur from products containing contaminated elemental sulphur by froth flotation 失效
    通过中硫污染产品的泡沫浮选elementärem硫的回收率。

    公开(公告)号：EP0240380A2

    公开(公告)日：1987-10-07

    申请号：EP87400368.4

    申请日：1987-02-19

    申请人： ION ADAMACHE

    发明人： ION ADAMACHE

    IPC分类号： C01B17/027 ,  B03B9/00

    CPC分类号： B03B9/00 ,  B03B9/061 ,  B03D1/002 ,  B03D1/006 ,  B03D1/008 ,  B03D1/012 ,  B03D1/02 ,  B03D2201/02 ,  B03D2201/04 ,  B03D2203/005 ,  B03D2203/006 ,  C01B17/027 ,  Y02W30/521

    摘要： A new 'cold' process for the recovery of elemental sulphur from contaminated elemental sulphur products is described. Elemental sulphur is recovered by froth flotation from: contaminated base pads of elemental sulphur blocks, stockpiles of contaminated elemental sulphur; contaminated elemental sulphur rejects from industrial handling and hauling; complex sulphur agglomerate, reject by-product from hot melting processes which is presently unprocessable and discarded (or as is otherwise referred to as 'sulphur crete melt residue'); contaminated products resulting from the exploitation processes using wells for the application of heat to reservoirs in order to recover elemental sulphur; and also from otl er sources of contaminated elemental sulphur in the oil and gas and other industries. This process comprises the steps of coarse screening, crushing, wet grinding, sizing, classifying. Then, the wet ground slurry at ambient temperature is treated by froth flotation, removing the elemental sulphur in the froth, and transporting undesirable contaminants to storage ponds or subsequent land reclamation. The initial elemental sulphur froth from the first stage of flotation is cleaned one or more times by reflotations. The cleaned elemental sulphur-bearing froth is then filtered to reinove excess water and to produce a filter cake.

    摘要翻译： 被描述为元素硫从单质硫污染的产品回收新的“冷”的过程。 元素硫是通过泡沫浮选回收从：元素硫的块，被污染的元素硫的储存污染基垫; 污染元素硫从工业装卸和牵引拒绝; 复杂的附聚物硫，从热熔融过程拒绝副产品所有这是目前无法处理和丢弃（或以其它方式通过向称为“硫克里特熔化残余”）; 污染的产品从开采所得工艺使用井的热施加到以回收元素硫贮存器; 因此，从在油污染元素硫和天然气等行业的其他来源。 该方法包括粗筛，粉碎，湿式粉碎，上浆，分级的步骤。 然后，在环境温度下将湿地面浆料通过泡沫浮选处理，除去在泡沫中的元素硫，并输送不希望的污染物，以存储池塘或随后的土地开垦。 从浮选的第一阶段的初始元素硫泡沫由reflotations清洗一次或多次。 然后将清洁的元素硫承载泡沫被过滤以除去过量的水并产生滤饼。

    A process for removing elemental sulfur from a gas stream
    5.
    发明公开
    A process for removing elemental sulfur from a gas stream 失效
    Verfahren zur Entfernung von elementarem Schwefel aus einem Gasstrom。

    公开(公告)号：EP0655414A1

    公开(公告)日：1995-05-31

    申请号：EP94203462.0

    申请日：1994-11-29

    申请人： COMPRIMO, B.V. ,  GASTEC N.V.

    发明人： Borsboom, Johannes ,  Lagas, Jan Adolf

    IPC分类号： C01B17/04 ,  C01B17/027

    CPC分类号： B01D53/002 ,  B01D53/52 ,  B01D53/8612 ,  B01D2257/30 ,  C01B17/021

    摘要： The invention relates to a process for removing elemental sulfur which is present in a gas in the form of vapor and/or entrained particles, in which process the gas to be treated is cooled. The gas to be treated is introduced into a heat exchanger at the lower end thereof and with the aid of the temperature and/or the flow velocity of the cooling medium it is ensured that the wall of the heat exchanger has a temperature below the solidification point of sulfur and above the dew point of water, if any, present in the gas. The deposited sulfur is removed under the influence of gravity countercurrent to the gas to be treated.

    摘要翻译： 本发明涉及一种去除以蒸汽和/或夹带颗粒形式存在于气体中的元素硫的方法，在该方法中，被处理气体被冷却。 待处理的气体在其下端被引入热交换器中，借助于冷却介质的温度和/或流速，确保热交换器的壁具有低于凝固点的温度 的硫和高于露出的水（如果有的话）存在于气体中。 沉积的硫在重力与待处理气体逆流的影响下被去除。

    Method of improving handling characteristics of froth of elemental sulfur particles
    6.
    发明公开
    Method of improving handling characteristics of froth of elemental sulfur particles 失效
    一种用于改善元素硫颗粒的泡沫的处理性能的方法。

    公开(公告)号：EP0402507A1

    公开(公告)日：1990-12-19

    申请号：EP89110866.4

    申请日：1989-06-15

    申请人： Linde Aktiengesellschaft

    发明人： de Haan, Robert, Dr. ,  Vermaire, Sonet ,  Hesse, Horst J.F.A. ,  Wootton, Sandra Rose

    IPC分类号： C01B17/027 ,  B01D53/34 ,  C01B17/05

    CPC分类号： B01D53/48 ,  B01D53/1418 ,  B01D53/1425 ,  C01B17/027 ,  C01B17/05

    摘要： To improve the handling characteristics and dispersibility of a sulfur containing froth, especially a froth obtained from the regeneration step in a process for scrubbing out and oxidizing H₂S, there is added to the scrubbing liquor an ionic or non-ionic surfactant, e.g., dioctyl or dodecyl sulfosucciniate in sufficient concentrations, e.g., 3-16 ppm, to substantially prevent the sulfur particles from becoming crusty and stiff, this technique being particularly applicable to the replacement of diethanolamine.

    摘要翻译： 为了改善处理特性和含泡沫硫的分散性，爱尤其是在一个过程中从再生步骤得到用于擦洗出和氧化H2S泡沫，有被添加到洗涤液到离子或非离子表面活性剂，例如，二辛基或 以足够的浓度，例如，3-16 PPM，以基本上防止变得易怒的，僵硬的硫颗粒十二烷基sulfosucciniate，该技术是特别适用于更换二乙醇胺。

    Recovery of elemental sulphur from products containing contaminated elemental sulphr by froth flotation
    7.
    发明公开
    Recovery of elemental sulphur from products containing contaminated elemental sulphr by froth flotation 失效
    通过快速浮选从含有污染元素硫的产品中回收元素硫

    公开(公告)号：EP0240380A3

    公开(公告)日：1988-08-24

    申请号：EP87400368

    申请日：1987-02-19

    申请人： ION ADAMACHE

    发明人： ION ADAMACHE

    IPC分类号： C01B17/027 ,  B03B09/00

    CPC分类号： B03B9/00 ,  B03B9/061 ,  B03D1/002 ,  B03D1/006 ,  B03D1/008 ,  B03D1/012 ,  B03D1/02 ,  B03D2201/02 ,  B03D2201/04 ,  B03D2203/005 ,  B03D2203/006 ,  C01B17/027 ,  Y02W30/521

    摘要： A new 'cold' process for the recovery of elemental sulphur from contaminated elemental sulphur products is described. Elemental sulphur is recovered by froth flotation from: contaminated base pads of elemental sulphur blocks, stockpiles of contaminated elemental sulphur; contaminated elemental sulphur rejects from industrial handling and hauling; complex sulphur agglomerate, reject by-product from hot melting processes which is presently unprocessable and discarded (or as is otherwise referred to as 'sulphur crete melt residue'); contaminated products resulting from the exploitation processes using wells for the application of heat to reservoirs in order to recover elemental sulphur; and also from otl er sources of contaminated elemental sulphur in the oil and gas and other industries. This process comprises the steps of coarse screening, crushing, wet grinding, sizing, classifying. Then, the wet ground slurry at ambient temperature is treated by froth flotation, removing the elemental sulphur in the froth, and transporting undesirable contaminants to storage ponds or subsequent land reclamation. The initial elemental sulphur froth from the first stage of flotation is cleaned one or more times by reflotations. The cleaned elemental sulphur-bearing froth is then filtered to reinove excess water and to produce a filter cake.

    Method and apparatus for melting sulfur in aqueous slurries
    8.
    发明公开
    Method and apparatus for melting sulfur in aqueous slurries 失效
    Verfahren zum Schmelzen von Schwefel在wässerigenAufschlämmungen。

    公开(公告)号：EP0249671A2

    公开(公告)日：1987-12-23

    申请号：EP86402685.1

    申请日：1986-12-03

    申请人： ARI TECHNOLOGIES, INC. (a corporation of Illinois)

    发明人： Nagl, Gary J. ,  Hardison, Leslie C.

    IPC分类号： C01B17/027

    CPC分类号： C01B17/0205 ,  B01J6/005

    摘要： Method and apparatus for recovering sulfur from an aqueous slurry. The slurry is passed downwardly through a shell-and-tube heat exchanger having verti­cally arranged tubes, wherein it is heated sufficiently to melt the sulfur. The liquid mixture leaving the heat exchanger is discharged into a first separation zone, in which a phase separation between the lighter aqueous phase and the denser liquid sulfur occurs. The upper aqueous phase is then transported to an intermediate point in the height of a vertically elongated second separation zone, while the molten sulfur is transported from the lower end of the first separation zone to a point adjacent the lower end of said second separation zone, in which an interface between the phases is main­tained at a point below the entry point of the aqueous liquid phase into the second separation zone. The aqueous liquid is discharged from the top of the second separation zone, while molten sulfur is discharged from the bottom of said zone.

    摘要翻译： 从含水浆料中回收硫的方法和装置。 将浆料向下通过具有垂直排列的管的管壳式热交换器，其中其被充分加热以熔化硫。 离开热交换器的液体混合物被排放到第一分离区域中，在第一分离区域中发生较轻的水相和较稠的液体硫之间的相分离。 然后将上部水相输送到垂直细长的第二分离区的高度的中间点，同时熔融的硫从第一分离区的下端输送到邻近所述第二分离区的下端的点， 其中相之间的界面保持在低于水性液相进入第二分离区的入口点。 水性液体从第二分离区的顶部排出，而熔融硫从所述区域的底部排出。