摘要:
A process for the production of an alkaline earth metal, aluminum-containing spinel/clay composition comprises: (a) combining (1) an acidic, aluminum-containing composition in which the aluminum is present in a positively charged species, and (2) a basic, alkaline earth metal-containing composition to form a gel mixture; (b) mixing the gel with kaolin clay to form a co-gel; and (c) calcining the co-gel mixture to form the alkaline earth metal, aluminum-containing spinel composition in a clay matrix. Alkaline earth metal, aluminum-containing spinel/clays having both high surface areas and very high attrition resistance, and processes for using spinel/clay compositions, e.g., as sulfur oxide and nitrogen oxide removal agent, are also disclosed.
摘要:
The invention relates to a catalyst for converting SO2 with molecular oxygen into SO3. The catalyst is suited for continuous operation at temperatures of 700 °C and higher when said catalyst is comprised of a porous supporting material and an active component which is joined to the supporting material. The active component is made up of 10 to 80 wt. % iron. The supporting material is a BET-surface ranging from 100 to 2000 m2/g and comprises a SiO¿2? content of at least 90 wt. %. The weight ratio supporting material:active component ranges from 1:1 to 100:1.
摘要:
Die vorliengende Erfindung betrifft ein Verfahren zur Entfernung von Schwefeldioxid aus Abgasen durch katalytische Umsetzung des Schwefeldioxides mit Sauerstoff und Wasser an Aktivkohle, wobei Aktivkohle einer Korn-größe von 0,3 bis 3,5 mm verwendet wird.
摘要:
Methods and devices for transforming less desirable chemical species into more desirable or useful chemical forms are disclosed. The specifications can be used to treat pollutants into more benign compositions and to produce useful chemicals from raw materials and wastes. The methods and devices (400) disclosed utilize continuous or temporary pulse of electrical current induced by electromagnetic field and high surface area formulations. The invention can also be applied to improve the performance of existing catalysts and to prepare novel devices.
摘要:
The invention is a method and a sulfuric acid plant design for reduction of start-up SO2, SO3 and H2SO4 emissions in sulfuric acid production, in which SO2 is converted to SO3 in n successive catalyst beds, where n is an integer >1. The final catalytic beds are used as absorbents for SO2 to SO3 during the start-up procedure, and one or more of the m beds downstream the first bed are purged, either separately or simultaneously, with hot gas, where m is an integer > 1 and m
摘要:
The present disclosure relates to a process and a process plant for desulfurizing a process gas comprising elemental sulfur, H 2 and water, comprising the steps of a. directing the process gas to contact a material catalytically active in hydrogenation to provide a hydrogenated process gas under effective hydrogenation conditions, b. cooling and phase separating the hydrogenated process gas, to provide a water condensate and a moisture reduced hydrogenated process gas, c. oxidizing the moisture reduced hydrogenated process gas after addition of a source of O 2 , to form an SO 2 rich process gas, d. catalytically oxidizing the SO 2 rich process gas to provide an SO 3 rich process gas e. hydrating the SO 3 in said SO 3 rich process gas to form H 2 SO 4 and condensing sulfuric acid and providing a desulfurized process gas substantially free of H 2 SO 4 and a liquid stream of concentrated sulfuric acid. This has the associated benefit of providing an SO 2 rich process gas of lower volume, compared to a process without intermediate withdrawal of water. If the process gas does not contain a sufficient amount of hydrogen, this may be added.
摘要:
A process where a gas, containing SO2 and O2 is brought in contact with a mixture of from 95% vol. to 50% vol. of activated carbon catalyst and from 5% vol. to 50% vol. of an inert filler material, where the SO2 is converted to H2SO4 on the activated carbon catalyst and is then washed from the activated carbon catalyst to obtain a H2SO4 solution.