Alkaline earth metal spinel/kaolin clays and processes for making and using same
    1.
    发明公开
    Alkaline earth metal spinel/kaolin clays and processes for making and using same 失效
    Erdalkalimetallspinell和Kaolintonmineralien组成以及其制备方法及其用途。

    公开(公告)号:EP0281993A1

    公开(公告)日:1988-09-14

    申请号:EP88103565.3

    申请日:1988-03-08

    申请人: UOP

    摘要: A process for the production of an alkaline earth metal, aluminum-containing spinel/clay composition comprises: (a) combining (1) an acidic, aluminum-containing composition in which the aluminum is present in a positively charged species, and (2) a basic, alkaline earth metal-containing composition to form a gel mixture; (b) mixing the gel with kaolin clay to form a co-gel; and (c) calcining the co-gel mixture to form the alkaline earth metal, aluminum-containing spinel composition in a clay matrix. Alkaline earth metal, aluminum-containing spinel/clays having both high surface areas and very high attrition resistance, and processes for using spinel/clay compositions, e.g., as sulfur oxide and nitrogen oxide removal agent, are also disclosed.

    摘要翻译: 一种用于生产一种碱土金属的过程中,含有铝的尖晶石/粘土组合物包含:(a)将(1),其中所述铝是存在于带正电的物质的酸性,含有铝的组合物,和(2) 一个基本的,碱土组合物以形成凝胶混合物含金属的; (B)混合的高岭土的凝胶以形成共凝胶; 和(c)煅烧该共凝胶混合物以形成在粘土基质中的碱土金属,含有铝的尖晶石组合物中。 碱土金属,含有铝的尖晶石/具有高表面积和两个非常高的耐磨耗性,和方法来应用尖晶石/粘土组合物,E. G.,如硫氧化物和氮氧化物去除剂粘土,是游离缺失盘。

    PROCESS FOR DESULFURIZATION OF A PROCESS GAS

    公开(公告)号:EP4000716A1

    公开(公告)日:2022-05-25

    申请号:EP20209046.0

    申请日:2020-11-20

    发明人: LYKKE, Mads

    IPC分类号: B01D53/48 C01B17/78

    摘要: The present disclosure relates to a process and a process plant for desulfurizing a process gas comprising elemental sulfur, H 2 and water, comprising the steps of
    a. directing the process gas to contact a material catalytically active in hydrogenation to provide a hydrogenated process gas under effective hydrogenation conditions,
    b. cooling and phase separating the hydrogenated process gas, to provide a water condensate and a moisture reduced hydrogenated process gas,
    c. oxidizing the moisture reduced hydrogenated process gas after addition of a source of O 2 , to form an SO 2 rich process gas,
    d. catalytically oxidizing the SO 2 rich process gas to provide an SO 3 rich process gas
    e. hydrating the SO 3 in said SO 3 rich process gas to form H 2 SO 4 and condensing sulfuric acid and providing a desulfurized process gas substantially free of H 2 SO 4 and a liquid stream of concentrated sulfuric acid.
    This has the associated benefit of providing an SO 2 rich process gas of lower volume, compared to a process without intermediate withdrawal of water. If the process gas does not contain a sufficient amount of hydrogen, this may be added.

    SULFUR DIOXIDE REMOVAL FROM WASTE GAS
    10.
    发明公开

    公开(公告)号:EP3439767A1

    公开(公告)日:2019-02-13

    申请号:EP17715128.9

    申请日:2017-03-31

    发明人: STRICKROTH, Alain

    IPC分类号: B01D53/86 C01B17/78

    摘要: A process where a gas, containing SO2 and O2 is brought in contact with a mixture of from 95% vol. to 50% vol. of activated carbon catalyst and from 5% vol. to 50% vol. of an inert filler material, where the SO2 is converted to H2SO4 on the activated carbon catalyst and is then washed from the activated carbon catalyst to obtain a H2SO4 solution.