摘要:
Process for the manufacture of sodium carbonate crystals comprising: the addition of solid sodium carbonate (1) to an aqueous solution coniprising sodium bicarbonate and sodium carbonate; the crystallization and the separation of sodium sesquicarbonate crystals; (B, C) the crystallization of sodium carbonate crystals, (E) the amount of sodium carbonate added being adjusted so that the crystallization of sesquicarbonate crystals can be carried out without preliminary evaporation of the aqueous suspension.
摘要:
Sodium bicarbonate is produced by introducing solid sodium sesquicarbonate and/or Wegscheider's salt into a reversion slurry, saturated with respect to bicarbonate and containing at least 10 wt. % solids, to effect rapid and complete conversion of the feed solids to crystalline sodium bicarbonate which is recovered from the slurry. Carbon dioxide is introduced into the reversion liquor to maintain its composition at a relatively constant value, preferably in a region of the Na 2 C0 3 -NaHC0 3- H 2 0 phase diagram that minimizes the equilibrium partial pressure of CO 2 vapor above such liquor.
摘要:
A process for the dry carbonation of an alkali metal or ammonium carbonate (19), utilizing a low carbon dioxide-containing carbonating gas stream (10), and more particularly, a process for the production of a bicarbonate sorbent (21) useful in the desulfurization of flue gases from the low carbon dioxide-content flue gases themselves.