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1.发明公开Selective photochlorination of 1,1-dichloroethane with iodine catalyst 失效Segektive Photochlorierung von 1,1-Dichloroäthanin Gegenwart eines Jodkatalysators。
公开(公告)号：EP0096403A1
公开(公告)日：1983-12-21
申请号：EP83105542.1
申请日：1983-06-06
摘要： The invention is a selective process for preparing 1,1,1-trichloroethane comprising irradiating a vaporous mixture comprising 1,1-dichloroethane, chlorine and a photocatalytic amount of iodine or a compound which liberates iodine in the presence of chlorine with radiation from a light source capable of providing radiation at a wavelength at which a binary intermediate formed from iodine and chlorine absorbs and at which chlorine does not absorb appreciably or has very low absorption, wherein the radiation is capable of inducing the selective formation of 1,1,1-trichloroethane. This process results in a reaction with surprisingly higher selectivity for 1,1,1-trichloroethane.
摘要翻译： 本发明是一种制备1,1,1-三氯乙烷的选择性方法，包括照射包含1,1-二氯乙烷，氯和光催化量的碘的蒸气混合物或在氯存在下释放碘的化合物与来自光的辐射 能够提供由碘和氯形成的二元中间体吸收并且氯不被明显吸收或具有非常低的吸收的波长的辐射源，其中辐射能够诱导选择性形成1,1,1- 三氯乙烷。 该过程导致对1,1,1-三氯乙烷令人惊奇的更高选择性的反应。
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公开(公告)号：EP0062952A1
公开(公告)日：1982-10-20
申请号：EP82200418.0
申请日：1982-04-02
发明人： Servais, Michel , Crochet, Roger
摘要： Compositions de 1,1,1-trichloréthane stabilisées contenant un composé époxydé tel que l'époxybutane, un composé nitré tel que le nitrométhane et un composé furannique tel que le 2-méthylfuranne.
Ces compositions conveniennent bien pour dégraisser les métaux et en nettoyage à sec des textiles.摘要翻译： 含有环氧化合物如环氧丁烷，硝基化合物如硝基甲烷和呋喃化合物如2-甲基呋喃的稳定化1,1,1-三氯乙烷组合物。 这些组合物非常适用于金属和干洗纺织品的脱脂。
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3.发明公开Solvent composition, method of inhibiting the decomposition of 1,1,1-trichloroethane and method of degreasing articles 失效溶剂组合物，抑制1,1,1-三氯乙烷的分解和方法，用于对象的脱脂的方法。
公开(公告)号：EP0023794A1
公开(公告)日：1981-02-11
申请号：EP80302497.5
申请日：1980-07-23
CPC分类号： C23G5/0288 , C07C17/42 , C07C19/05
摘要： A solvent composition comprising 1,1,1-trichloroethane and a stabilizing amount of an epoxide of formula
wherein R 1 and R 2 are hydrogen, alkyl of 1 to 4 carbon atoms, phenyl or benzyl,
R 3 is hydrogen or alkyl of 1 to 4 carbon atoms,
R 4 is alkyl of 1 to 4 carbon atoms and
n is 0 or 1.
Preferably the or each alkyl group contains 1 or 2 carbon atoms; examples of useful epoxides are ethyl trans-2,3-epoxybutyrate, ethyl 3,4-epoxy-3-methylvalerate and ethyl beta-methyl-beta-phenylglycidate.
The composition can be used for degreasing.-
公开(公告)号：EP3950651A1
公开(公告)日：2022-02-09
申请号：EP20778829.0
申请日：2020-03-27
发明人： TAKAHASHI, Kazuhiro
IPC分类号： C07C19/05 , C07C21/073 , C07C17/383
摘要： An object of the present invention is to provide a novel azeoropic or azeotrope-like composition that is effective for the separation of HF from 1,1,2-trichloroethane (HCC-140), trans-1,2-dichloroethylene (HCO-1130(E)), or cis-1,2-dichloroethylene (HCO-1130(Z)). The object can be achieved by an azeotropic or azeotrope-like composition comprising HCC-140, HCO-1130(E), or HCO-1130(Z), and hydrogen fluoride.
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公开(公告)号：EP3353139A1
公开(公告)日：2018-08-01
申请号：EP16777853.9
申请日：2016-09-22
申请人： Blue Cube IP LLC
IPC分类号： C07C17/10 , C07C17/395 , C07C19/03 , C07C19/04 , C07C19/041 , C07C19/043 , C07C19/045 , C07C19/05 , C07C19/055
CPC分类号： C07C17/013 , C07C17/04 , C07C17/10 , C07C17/25 , C07C17/383 , C07C17/395 , C07C19/03 , C07C19/04 , C07C19/041 , C07C19/043 , C07C19/045 , C07C21/10 , C07C19/05 , C07C19/055
摘要： The present invention provides processes for the production of chlorinated methanes via the direct chlorination of methane. The processes include a dehydrochlorination and/or chlorination step that converts up to 100% of the higher chlorinated alkanes in a process stream from the methane chlorination reaction into more highly chlorinated alkanes. These more highly chlorinated alkanes can be easily removed from the process stream. The use of a cost effective feedstream of crude methane is thus rendered possible, without additional capital expenditure for the sophisticated separation equipment required to separate ethane and other hydrocarbon components from the methane feed.
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公开(公告)号：EP0062952B1
公开(公告)日：1985-08-07
申请号：EP82200418.0
申请日：1982-04-02
发明人： Servais, Michel , Crochet, Roger
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公开(公告)号：EP0024113A1
公开(公告)日：1981-02-25
申请号：EP80302376.1
申请日：1980-07-15
CPC分类号： C11D7/261 , C07C17/42 , C11D7/28 , C11D7/32 , C11D7/5018 , C23G5/02887 , C07C19/05
摘要： A solvent composition for cleaning metal and other arti- ctes which comprises 1,1,1-trichloroethane having dissolved therein a stabilising amount of a mixture of stabilising components comprising (i) tertiary butanol (ii) nitromethane and (iii) 1-or 2-nitropropane or nitroethane, in which mixture the specified stabilising components are present in the mole fraction per cent ranges encompassed by Contour K in Figure 1 of the drawings in the case where component (iii) is 1-or 2-nitropropane or by Contour A in Figure 2 of the drawing in the case where component (iii) is nitroethane.
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公开(公告)号：EP3807236A1
公开(公告)日：2021-04-21
申请号：EP19744762.6
申请日：2019-06-12
申请人： ARKEMA FRANCE
发明人： BONNET, Anthony , DUBOIS, Jean-Luc
IPC分类号： C07C17/04 , C07C17/20 , C07C17/25 , C07C21/18 , C07C17/087 , C07C19/045 , C07C17/06 , C07C19/05 , C07C19/12
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公开(公告)号：EP0091708B1
公开(公告)日：1987-07-29
申请号：EP83200456.8
申请日：1983-03-31
发明人： Gregor, Reinhard , Ruzha, Wolfgang , Hönig, Werner
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10.发明公开Selective catalytic photochlorination of 1,1-dichloroethane 失效Selektive katalytische Photochlorierung von 1,1-Dichloroäthan。
公开(公告)号：EP0096404A1
公开(公告)日：1983-12-21
申请号：EP83105543.9
申请日：1983-06-06
摘要： The invention is a selective process for preparing 1,1,1-trichloroethane comprising irradiating a vaporous mixture comprising 1,1-dichloroethane, chlorine and an effective amount of a photocatalyst wherein the photocatalyst is bromine, a compound which liberates bromine in the presence of chlorine, carbon monoxide, nitric oxide or oxygen, with radiation capable of inducing the selective formation of 1,1,1-trichloroethane. Radiation in the wavelength of between about 250 and 550 nanometers is capable of inducing the selective formation of 1,1,1-trichloroethane.
摘要翻译： 本发明是用于制备1,1,1-三氯乙烷的选择性方法，其包括：照射包含1,1-二氯乙烷，氯和有效量的光催化剂的蒸气混合物，其中光催化剂是溴，在存在下释放溴的化合物 氯，一氧化碳，一氧化氮或氧气，具有能够诱导1,1,1-三氯乙烷选择性形成的辐射。 在约250和550纳米之间的波长的辐射能够诱导1,1,1-三氯乙烷的选择性形成。
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