EP0927717A4 -
    8.
    发明公开
    EP0927717A4 - 失效
    EP0927717A4 - Google专利

    公开(公告)号:EP0927717A4

    公开(公告)日:1999-07-07

    申请号:EP98929761

    申请日:1998-06-30

    CPC分类号: C07C407/00 C07C409/10

    摘要: A process for producing hydroperoxides by oxidizing a hydrocarbon with an oxygen-containing gas in the presence of a specified compound to selectively convert the hydrocarbon into a corresponding hydroperoxide. The specified compounds are those capable of trapping free radicals, and preferred examples thereof include oxygen, nitrogen, phosphorus, sulfur, carbon and silicon radicals, and compounds capable of forming such radicals in a reaction system. This process is applicable to the oxidation of hydrocarbons including arylalkylhydrocarbons such as cumene, cymene, m-diisopropylbenzene, p-diisopropylbenzene, 1,3,5-triisopropylbenzene, isopropylnaphthalene, diisopropylnaphthalene, isopropylbiphenyl and diisopropylbiphenyl.

    摘要翻译: 一种通过在特定化合物存在下用含氧气体氧化烃以选择性地将烃转化为相应的氢过氧化物来生产氢过氧化物的方法。 指定的化合物是能够捕获自由基的化合物,其优选实例包括氧,氮,磷,硫,碳和硅自由基,以及能够在反应体系中形成这种自由基的化合物。 该方法适用于包括芳基烷基烃如异丙基苯,伞花烃,间二异丙基苯,对二异丙基苯,1,3,5-三异丙基苯,异丙基萘,二异丙基萘,异丙基联苯和二异丙基联苯的烃的氧化。