摘要:
A method for forming ionic copolymer salts from low molecular weight copolymer acids formed from ethylene and an alpha, beta-ethylenically unsaturated carboxylic acid having at least one carboxylic acid group and oxides of Group II metals. The copolymer acid and the metal are fed to a reaction vessel. The copolymer acid and the metal oxide are mixed at a temperature between the melting point of the copolymer acid and 20°C above the melting point of the copolymer acid. The reaction is conducted at a reaction temperature which is from 30°C greater than the melting point of the copolymer acid to 300°C.
摘要:
A modified block copolymer comprising a base block copolymer of at least two monovinyl substituted aromatic hydrocarbon polymer blocks and of at least one olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20 %, said base block copolymer having at least one molecular unit grafted thereonto, said molecular unit containing at least one member selected from a dicarboxylic acid group and groups derived therefrom, said base block copolymer having a monovinyl substituted aromatic hydrocarbon content of 5 to 95 % by weight.
摘要:
Dispersants containing amine groups are borated by reaction with a polyborate ester followed by removal of the alcohol which is produced by the reaction.
摘要:
A bulk sulphonation process for sulphonating an elastomeric polymer wherein the polymer and sulphuric acid, chlorosulphonic acid or S0 3 as sulphonating agent are mechanically mixed whereby the polymer is in a state of flux in the substantial absence of solvent at a temperature below 250°C and above the glass transition temperature or crystalline melting point. Either the free sulphonic acid is recovered or the sulphonic acid is neutnlitad before recovery.
摘要:
@ A photographic element and its use in diffusion transfer photography are described which contain a novel polymeric mordant comprising recurring units having the formula wherein A represents recurring units derived from one or more an α,β-ethylenically unsaturated monomer; B represents recurring units derived from a monomer containing at least two ethylenically unsaturated groups; QN + represents a moiety containing a quaternized nitrogen group; R' represents an alkoxy group having from 1 to 8 carbon atoms or an alkylenedioxy group having from 1 to 4 carbon atoms, the group being appended to an aromatic group of A; R 2 represents an alkoxy group having from 1 to 8 carbon atoms or an alkylenedioxy group having from 1 to 4 carbon atoms, the group being appended to an aromatic group of QN + ; each n and m independently represents an integer from 0 to 5, with the proviso that the polymer contains recurring units having at leasttwo alkoxy groups or one alkylenedioxy group; each R 3 independently represents hydrogen or an alkyl group having from 1 to 6 carbon atoms; X 6 represents an anion; x is from 0 to 80 mole percent; y is from 20 to 100 mole percent; and z is from 0 to 10 mole percent.
摘要:
Improved low temperature flex-crack resistant ionic copolymers of ethylene, unsaturated carboxylic acid and at least one softening comonomer that is capable of forming a homopolymer having a glass transition temperature of less than -40°C, such as alkyl acrylates and/or alkyl vinyl ethers and from about 0.5 to about 6.0 mole % of chain branches arising from the polymerization of ethylene, are obtained by direct or graft copolymerization, followed by neutralization of the carboxylic acid groups with metal ions, such ionic copolymers of ethylene being characterized by having from about 5 to about 20 chain branches arising from the polymerization of ethylene/1000 CH 2 units of the polymer backbone, said ethylene chain branches being composed of butyl or longer branches, the copolymer being further characterized by satisfying the equation A + 2.05 B = C, wherein A is the mole percent of softening comonomer, B is the mole percent of butyl or longer chain branches derived from the polymerization of ethylene, and C is from about 1.5 to about 24.3.
摘要:
lonic direct and graft copolymers of a-olefins and α,β-ethylenically unsaturated carboxylic acid are provided using from above 1 to about 3 times the amount of lead salt necessary to neutralize all of the copolymerized acid. The resulting ionomers contain high levels of lead and are tough, clear and melt-processible. Accordingly, they are useful in radiation shields.
摘要:
A fluorocarbon polymer comprising a perfluorocarbon main chain and a pendant chain attached to the main chain, characterized in that the pendant chain has a quaternary ammonium type terminal group.