Process for preparing methacrylimide-containing polymers
    9.
    发明公开
    Process for preparing methacrylimide-containing polymers 失效
    制备含有甲基丙烯酰亚胺的聚合物的方法

    公开(公告)号:EP0200530A3

    公开(公告)日:1987-01-07

    申请号:EP86303249

    申请日:1986-04-29

    IPC分类号: C08F08/32 C08F20/52

    CPC分类号: C08F8/32 C08F8/48 C08F120/14

    摘要: Methacrylimide-containing polymers are continuously produced by introducing 10 to 60 wt.% of an inert solvent, 90 to 40 wt.% of methacrylic acid, a methacrylic acid ester or a monomer mixture comprising at least 50 wt.% of methacrylic acid or a methacrylic acid ester, and a radical polymerization initiator and a molecular weight modifier into a polymerization reaction zone, converting at least 80 wt.% of the charged monomer to a polymer at 60 - 170°C, adding a compound represented by the formula:
    wherein R represents a hydrogen atom, an alkyl group having 1 - 12 carbon atoms, a cycloalkyl group having 7 - 11 carbon atoms or an aryl group having 6 - 10 carbon atoms, to the polymerization reaction liquid, carrying out reaction of the resulting mixture at 150 to 300°C in an imidization reaction zone, and finally separating volatile substances from the reaction liquid.