摘要:
The present invention relates to a diene-based rubber latex including a polymer aggregate and having an extra large diameter, a method for preparing same and a graft copolymer with a core-shell structure, including same and having excellent impact strength and surface properties. A diene-based rubber latex of which 14 wt% to 26 wt% has diameter of 100 nm to less than 300 nm, 62 wt% to 81 wt% has a diameter of 300 nm to less than 800 nm, and 5 wt% to 14 wt% has a diameter of 800 nm to less than 1000 nm, based on 100 wt% of total rubber particles.
摘要:
The present invention relates to a method of preparing a graft copolymer and a thermoplastic resin composition including the graft copolymer. More specifically, the present invention relates to a method of preparing a graft copolymer, the method including a step of performing coagulation by adding an acid coagulant to 100 parts by weight (based on solids) of graft copolymer latex prepared by graft-polymerizing an aromatic vinyl compound and a vinyl cyanide compound onto conjugated diene rubber latex; and a step of performing coagulation once more by adding a salt coagulant thereto. According to the present invention, when the method is used to prepare a graft copolymer, coagulation efficiency may be improved and the gloss of the prepared graft copolymer may be increased. In addition, since a b-value measured using a Hunter lab colorimeter and a b-value measured after being left at 250 °C for 15 minutes are low, the graft copolymer may have excellent color characteristics. In addition, since heating loss is low and scorch time is long, the graft copolymer may have excellent processing characteristics.
摘要:
A grain aggregate is formed by bonding a plurality of cross-linking polymeric grains via a substance (binder) having a reactive functional group, and alternatively, the grain aggregate is formed by bonding at least two different types of a plurality of grains, thus providing the grain aggregate having the improved heat resistance, solvent resistance, strength and light-diffusing properties. Further, a light-diffusing agent made up of the grain aggregate has the improved light-diffusing properties. Therefore, when applying a light-diffusing mold article including the light-diffusing agent to, for example, a backlight of a liquid crystal display device, high brightness and a wide angle of visibility can be attained. Further, by spray drying of a dispersion liquid containing the grain aggregate, the grain aggregate can be produced with ease.
摘要:
A grain aggregate is formed by bonding a plurality of cross-linking polymeric grains via a substance (binder) having a reactive functional group, and alternatively, the grain aggregate is formed by bonding at least two different types of a plurality of grains, thus providing the grain aggregate having the improved heat resistance, solvent resistance, strength and light-diffusing properties. Further, a light-diffusing agent made up of the grain aggregate has the improved light-diffusing properties. Therefore, when applying a light-diffusing mold article including the light-diffusing agent to, for example, a backlight of a liquid crystal display device, high brightness and a wide angle of visibility can be attained. Further, by spray drying of a dispersion liquid containing the grain aggregate, the grain aggregate can be produced with ease.
摘要:
Disclosed is a process for isolating copolymers comprising repeating units from 2-vinylpyridine and styrene by drowning the reaction emulsion into an acetic acid solution or by adding an acetic acid/water solution to the reaction emulsion. The copolymer isolated by this technique filters and washes much more rapidly than the copolymer isolated using sodium chloride, and the wet cake has a high solids content.