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公开(公告)号：EP3738948B1
公开(公告)日：2022-12-14
申请号：EP19738460.5
申请日：2019-01-08
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公开(公告)号：EP4011857A1
公开(公告)日：2022-06-15
申请号：EP21212795.5
申请日：2021-12-07
发明人： ARAYA BRENES, MARIO
IPC分类号： C07C29/151 , C07C31/04 , C07C68/04 , C07C69/96
摘要： The present application relates to an apparatus and process for producing dimethyl carbonate, in particular a system (apparatus or process) for DMC synthesis without the need of using a dehydrating agent. More particularly, the feed mixture for the process can be selected from the following options: a) carbon monoxide, methanol and flue gas from the process, b) synthesis gas without CO 2 and flue gas from the process, c) synthesis gas with CO 2 and added synthesis gas from purified flue gas from the process. The process uses a catalyst cluster comprising a specific combination of different groups of heterogeneous catalysts wherein each group has a different function. Also the invention relates to an apparatus comprising a specific combination of heterogeneous catalysts for applying different routes to produce dimethyl carbonate from each feed mixture option, on continuous basis.
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3.发明公开
公开(公告)号：EP3822251A1
公开(公告)日：2021-05-19
申请号：EP19833012.8
申请日：2019-07-08
申请人： NIPPON STEEL CORPORATION , MITSUBISHI GAS CHEMICAL COMPANY, INC. , Nippon Steel Engineering Co., Ltd.
发明人： SUZUKI, Kimihito , SHINKAI, Yousuke , LIU, Hongyu , HARADA, Hidefumi , KATO, Yuzuru , MORITA, Kentaro , OHASHI, Asuka
摘要： Provided are a method for producing carbonate esters, and a catalytic structure for producing carbonate esters, whereby solid catalyst powder formation and detachment are suppressed and superior carbonate ester reaction efficiency is yielded when a catalytic structure constituted by a sufficient quantity of a cerium-oxide-containing solid catalyst supported on a substrate is used. The method for producing carbonate esters according to the present invention comprises a step for reacting a monohydric alcohol and carbon dioxide in the presence of a catalytic structure and a hydrating agent. The catalytic structure comprises a substrate and a catalytic layer that is formed on at least a portion of the surface of the substrate and contains a solid catalyst and an inorganic binder. The solid catalyst contains cerium oxide. The supported quantity of the solid catalyst is 15 g/m 2 to 200 g/m 2 , inclusive. The inorganic binder contains silica and/or alumina.
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公开(公告)号：EP3142787A4
公开(公告)日：2018-01-24
申请号：EP14891721
申请日：2014-05-14
发明人： HOU ZHENSHAN , SONG BAONING
CPC分类号： C07D317/36 , B01J31/0239 , B01J31/0254 , B01J31/08 , B01J31/26 , B01J31/4007 , B01J31/4084 , B01J37/0036 , B01J37/04 , B01J38/00 , B01J38/48 , B01J2231/341 , C07D303/04 , C07D303/08 , C07D317/12
摘要： Catalysts and methods for making cyclic carbonates are disclosed. The catalyst may include at least one polymer quaternary ammonium salt, at least one metal halide and silica gel. The method of making the cyclic carbonates may include forming a mixture that includes the catalyst and an epoxide, and contacting the mixture with carbon dioxide in a reactor under conditions to form the propylene carbonate.
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5.发明公开
公开(公告)号：EP2619168A4
公开(公告)日：2016-04-06
申请号：EP11827563
申请日：2011-09-22
发明人： ZHAI YUMEI , GUAN SHAN , SRIDHAR NARASI , AGARWAL ARUN
IPC分类号： C07C68/04 , C07C51/15 , C07C53/02 , C07C69/04 , C25B3/04 , C25B9/08 , C25B11/03 , C25B11/04 , C25B15/08
CPC分类号： C25B3/04 , C25B9/08 , C25B11/035 , C25B11/0405 , C25B11/0447 , C25B11/0478 , C25B11/0484 , C25B15/02 , C25B15/08 , Y02P20/142
摘要： A method and apparatus is provided for the electrochemical reduction of carbon dioxide to formate and formic acid. One embodiment features a three-compartment reactor which houses: a gas compartment; a catholyte compartment, which contains a porous cathode having a tin-based catalyst; and an anolyte compartment, which contains an anode having a mixed metal oxide catalyst. Further embodiments include a method for depositing tin onto a porous cathode, tin-zinc cathodes, a reaction method using an acidic anolyte, and pulsed polarization to extend reactor runtimes.
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6.发明公开PROCESS FOR PRODUCTION OF ALKYL TIN ALKOXIDE COMPOUND, AND PROCESS FOR PRODUCTION OF CARBONATE ESTER USING THE COMPOUND 有权制造方法ALKYLZINNOXIDVERBINDUNG和方法，用于生产碳酸酯的使用连接
公开(公告)号：EP2226328A4
公开(公告)日：2012-02-22
申请号：EP09804784
申请日：2009-03-31
发明人： SHINOHATA MASAAKI , MIYAKE NOBUHISA
CPC分类号： C07F7/2232 , C07C68/04 , C07C69/96
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公开(公告)号：EP1460056B1
公开(公告)日：2011-10-05
申请号：EP02793446.2
申请日：2002-12-27
发明人： MIYAKE, Nobuhisa , NAGAHARA, Hajime
摘要： A process for producing a carbonic ester which comprises the steps of: (1) reacting an organometallic compound having a metal-oxygen-carbon bond with carbon dioxide to obtain a reaction mixture containing a carbonic ester formed by the reaction; (2) separating the carbonic ester from the reaction mixture to obtain a liquid residue; and (3) reacting the liquid residue with an alcohol to form an organometallic compound having a metal-oxygen-carbon bond and water, removing the water from the organometallic compound, and recovering the organometallic compound obtained in the step (3) in order to recycle it to the step (1).
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8.发明公开PROCESS FOR PRODUCTION OF ALKYL TIN ALKOXIDE COMPOUND, AND PROCESS FOR PRODUCTION OF CARBONATE ESTER USING THE COMPOUND 有权制造方法ALKYLZINNOXIDVERBINDUNG和方法，用于生产碳酸酯的使用连接
公开(公告)号：EP2226328A1
公开(公告)日：2010-09-08
申请号：EP09804784.8
申请日：2009-03-31
CPC分类号： C07F7/2232 , C07C68/04 , C07C69/96
摘要： The present invention provides a process for producing : a compound represented by XOR 2 ; a dialkyl tin dialkoxide compound having one tin atom, two Sn-R 1 bonds and two Sn-OR 2 bonds; and/or a tetraalkyl dialkoxy distannoxane compound having one Sn-O-Sn bond, in which each tin atom of the tetraalkyl dialkoxy distannoxane compound has two Sn-R 1 bonds and one Sn-OR 2 bond, the process comprising reacting in the absence of a catalyst at least one alkyl tin compound selected from the group consisting of i) and ii) below:
i) a dialkyl tin compound having one tin atom, two Sn-R 1 (wherein R 1 represents an alkyl group) bonds, and two Sn-OX bonds (wherein OX is a group in which HOX that is a conjugate acid of OX is a Bronsted acid having a pKa of from 0 to 6.8); and
ii) a tetraalkyl distannoxane compound having one Sn-O-Sn bond, in which each tin atom of the tetraalkyl distannoxane compound has two Sn-R 1 bonds and one Sn-OX bond (wherein OX is a group in which HOX that is a conjugate acid of OX is a Bronsted acid having a pKa of from 0 to 6.8); and
a carbonic acid ester represented by R 2 OCOOR 2 (wherein R 2 represents a linear or branched, saturated or unsaturated hydrocarbon group, a hydrocarbon group having a saturated or unsaturated cyclic hydrocarbon substituent, or a Y-CH 2 - group (wherein Y represents an alkyl polyalkylene group, an aromatic group or a cyclic saturated or unsaturated alkylene ether group)), and/or
an alcohol represented by R 2 OH (wherein R 2 is the same as defined above).摘要翻译： 本发明提供了生产的方法：通过XOR 2所示的化合物; 具有一个锡原子，2个Sn-R 1个键和2个Sn-OR 2键的二烷基锡二醇盐化合物; 和/或具有一个的Sn-O-斯恩·邦德四烷基二烷氧基distannoxanes化合物，其中，所述四烷基二烷氧基distannoxanes化合物的各锡原子具有2个Sn-R 1个键和一个的Sn-OR 2键，该方法包括在不存在起反应 催化剂选自I的）和选择的至少一种烷基锡化合物II）所示：i）具有一个锡原子的二烷基锡化合物，2个Sn-R 1（worin，R 1个darstellt到的烷基）键和 2个Sn-OX键（worin OX是其中HOX的基团确实是OX的共轭酸是具有pKa在0〜6.8的布朗斯台德酸）; 和ii）具有一个的Sn-O-斯恩·邦德四烷基distannoxanes化合物，其中所述四烷基distannoxanes化合物的各锡原子具有2个Sn-R 1个键和一个的Sn-OX键（worin OX是其中HOX的基团即 OX的共轭酸是具有pKa在0〜6.8）布朗斯台德酸; 并且由R表示的碳酸酯2 OCOOR 2（worin R 2表示直链或支链的，饱和或不饱和烃基，具有的烃基的饱和或不饱和环状烃取代基，或者Y-CH 2 - 基（worinÿ 烷基聚亚烷基的darstellt，芳族基或环状饱和或不饱和亚烷基醚基）），和/或醇的R 2 OH（worin R2至表示的与上述相同的定义）。
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公开(公告)号：EP1623758A4
公开(公告)日：2007-08-22
申请号：EP04728019
申请日：2004-04-16
发明人： OSORA HIROYUKI , KOBAYASHI KAZUTO , SEIKI YOSHIO , YASUTAKE TOSHINOBU , IIJIMA MASAKI , OGUCHI AKIRA
CPC分类号： B01J27/053 , B01J27/16 , C07C68/04 , Y02P20/544 , C07C69/96
摘要： An economical catalyst for dimethyl carbonate synthesis is disclosed which has a high conversion rate under supercritical conditions of CO2 and can be handled easily. The catalyst for dimethyl carbonate synthesis is obtained by loading SO42- or PO43- on a carrier composed of a compound having a solid acid site, and used for producing dimethyl carbonate from acetone dimethyl acetal and CO2 in supercritical state. The compound having a solid acid site is preferably one or more of ZrO2, Al2O3 and TiO2.
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公开(公告)号：EP1640357A1
公开(公告)日：2006-03-29
申请号：EP04746852.5
申请日：2004-06-25
摘要： A method for producing an aromatic carbonate, comprising:
(1) performing a reaction between an organometal compound and carbon dioxide to obtain a reaction mixture containing a dialkyl carbonate formed by the reaction,
(2) separating the dialkyl carbonate from the reaction mixture to obtain a residual liquid,
(3) reacting the residual liquid with an alcohol to form at least one organometal compound and form water and removing the water from the organometal compound, and
(4) reacting the dialkyl carbonate separated in step (2) with an aromatic hydroxy compound to obtain an aromatic carbonate.摘要翻译： 1。一种芳香族碳酸酯的制造方法，其特征在于，包括：（1）使有机金属化合物与二氧化碳反应，得到含有通过该反应生成的碳酸二烷基酯的反应混合物，（2）从反应混合物中分离碳酸二烷基酯，得到 （3）使残余液体与醇反应以形成至少一种有机金属化合物并形成水并从有机金属化合物中除去水，以及（4）使步骤（2）中分离出的碳酸二烷基酯与芳族化合物 得到芳香族碳酸酯。
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