PHOTOELECTRIC CONVERSION ELEMENT AND DYE-SENSITIZED SOLAR CELL

    公开(公告)号:EP3306633A4

    公开(公告)日:2018-06-13

    申请号:EP16799898

    申请日:2016-05-18

    IPC分类号: H01G9/20 C09B57/10

    摘要: Provided are a photoelectric conversion element and a dye sensitized solar cell having a supporting substrate, a conductive layer, a power generating layer having a porous semiconductor layer onto which a metal complex dye represented by Formula (1) is adsorbed, a porous insulating layer, and a counter electrode conductive layer, in which the layers are laminated in this order on the supporting substrate, and voids that each of the power generating layer, the porous insulating layer, and the counter electrode conductive layer has are filled with an electrolyte. R represents a hydrogen atom, an alkyl group, or an aryl group. G represents a group represented by any one of Formulae (G-1) to (G-4). A 1 to A 3 each represent a hydrogen atom, a carboxyl group, or a salt thereof. At least one of A 1 to A 3 is a carboxyl group or a salt thereof. X 1 and X 2 each represent -O-, -S-, and others. R a represents an alkyl group and the like. R b to R e each represent a hydrogen atom or a substituent. na represents I to 3. (G-1) to (G-4) are bonded to a pyridine ring in the portion of *.

    PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION AND OXIDE SEMICONDUCTOR ELECTRODE
    8.
    发明公开
    PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION AND OXIDE SEMICONDUCTOR ELECTRODE 审中-公开
    光电转换元件,染料敏化太阳能电池,金属络合物染料,染料溶液和氧化物半导体电极

    公开(公告)号:EP3309804A1

    公开(公告)日:2018-04-18

    申请号:EP16807292.4

    申请日:2016-05-26

    IPC分类号: H01G9/20 C09B57/10 C09B67/44

    摘要: Provided are a photoelectric conversion element and a dye-sensitized solar cell, each including a photoconductor layer having semiconductor fine particles carrying a metal complex dye represented by Formula (1); and a metal complex dye, a dye solution, and an oxide semiconductor electrode.

    In the formula, M represents a metal ion. Ar 11 to Ar 14 each represent a phenyl group, or a phenyl group having an alkyl group or the like, and Ar 11 and Ar 12 each represent different phenyl groups. R 11 to R 14 each represent an alkyl group or the like. n 11 and n 12 each represent an integer of 0 to 3. n 13 and n 14 each represent an integer of 0 to 4. M 1 and M 2 each represent a proton or a cation, and L 3 and L 4 each represent a monodentate ligand.

    摘要翻译: 提供一种光电转换元件和染料敏化太阳能电池,每个所述光电转换元件和染料敏化太阳能电池包括:具有承载由式(1)表示的金属络合物染料的半导体微粒的光电导体层; 和金属络合物染料,染料溶液和氧化物半导体电极。 在该式中,M表示金属离子。 Ar11〜Ar14分别表示苯基或具有烷基等的苯基,Ar11和Ar12分别表示不同的苯基。 R11至R14各自表示烷基等。 n11和n12各自表示0至3的整数.n13和n14各自表示0至4的整数.M1和M2各自表示质子或阳离子,并且L3和L4各自表示单齿配体。

    PHOTOELECTRIC CONVERSION ELEMENT AND DYE-SENSITIZED SOLAR CELL
    9.
    发明公开
    PHOTOELECTRIC CONVERSION ELEMENT AND DYE-SENSITIZED SOLAR CELL 审中-公开
    光电转换元件和染料敏化太阳能电池

    公开(公告)号:EP3306633A1

    公开(公告)日:2018-04-11

    申请号:EP16799898.8

    申请日:2016-05-18

    IPC分类号: H01G9/20 C09B57/10

    摘要: Provided are a photoelectric conversion element and a dye sensitized solar cell having a supporting substrate, a conductive layer, a power generating layer having a porous semiconductor layer onto which a metal complex dye represented by Formula (1) is adsorbed, a porous insulating layer, and a counter electrode conductive layer, in which the layers are laminated in this order on the supporting substrate, and voids that each of the power generating layer, the porous insulating layer, and the counter electrode conductive layer has are filled with an electrolyte.

    R represents a hydrogen atom, an alkyl group, or an aryl group. G represents a group represented by any one of Formulae (G-1) to (G-4). A 1 to A 3 each represent a hydrogen atom, a carboxyl group, or a salt thereof. At least one of A 1 to A 3 is a carboxyl group or a salt thereof. X 1 and X 2 each represent -O-, -S-, and others. R a represents an alkyl group and the like. R b to R e each represent a hydrogen atom or a substituent. na represents I to 3. (G-1) to (G-4) are bonded to a pyridine ring in the portion of *.

    摘要翻译: 本发明提供一种光电转换元件和染料敏化太阳能电池,其具有支撑基板,导电层,具有多孔半导体层的发电层,多孔半导体层上吸附有由式(1)表示的金属络合物染料,多孔绝缘层, 以及对电极导电层,其中在支撑基板上依次层压这些层,并且发电层,多孔绝缘层和对电极导电层中的每一个均填充有电解质。 R表示氢原子,烷基或芳基。 G表示由式(G-1)至(G-4)中的任一个表示的基团。 A1〜A3分别表示氢原子,羧基或其盐。 A1至A3中的至少一个是羧基或其盐。 X1和X2各自表示-O - , - S-等。 Ra表示烷基等。 Rb至Re各自表示氢原子或取代基。 na表示I至3.(G-1)至(G-4)键合至*部分中的吡啶环。