Polymerization method using surfactant-containing particle
    40.
    发明专利
    Polymerization method using surfactant-containing particle 有权
    使用含表面活性剂颗粒的聚合方法

    公开(公告)号:JP2013139553A

    公开(公告)日:2013-07-18

    申请号:JP2012259422

    申请日:2012-11-28

    IPC分类号: C08F4/6592 C08F2/44

    摘要: PROBLEM TO BE SOLVED: To provide a method which can simply suppress fouling in a reactor.SOLUTION: There is provided a method of polymerizing addition polymerizable monomers using a catalyst formed by bringing (A) a transition metal compound represented by the following general formula [3]: LMXor a μ-oxo type transition metal compound dimer thereof, and (B) an activating agent into contact with one another, the method comprising polymerizing addition polymerizable monomers in a solvent to which a surfactant-containing particle obtained by mixing a particle composed of an inorganic compound or an organic polymer, and at least one surfactant selected from the group consisting of a compound represented by general formula [1]: R-O-(-R-O-)-Qand a compound represented by general formula [2]: RC(=O)NRhas been added.

    摘要翻译: 要解决的问题:提供一种能够简单地抑制反应器中的结垢的方法。解决方案:提供使用以下通式(A)表示的过渡金属化合物(以下通式[ 3]:LMX或其μ-氧代型过渡金属化合物二聚物,和(B)活化剂彼此接触,所述方法包括在溶剂中聚合加成聚合单体,所述溶剂中含有通过混合颗粒获得的含表面活性剂的颗粒 由无机化合物或有机聚合物组成的至少一种表面活性剂和选自通式[1]表示的化合物中的至少一种表面活性剂:RO - ( - RO - ) - Q和由通式[2]表示的化合物: 已经添加了RC(= O)NR。