公开(公告)号：JP2000192059A

公开(公告)日：2000-07-11

申请号：JP36379499

申请日：1999-12-22

申请人： CHEVRON CHEM CO LLC

发明人： MORRIS JACK E ,  AHMADI MAJID R

IPC分类号： C10L1/18 ,  C10L1/14 ,  C10L1/19 ,  C10L1/22 ,  C10L1/23 ,  C10L1/2383 ,  C10L10/00

摘要： PROBLEM TO BE SOLVED: To obtain a fuel additive composition which effectively prevents and reduces the formation of deposits in an engine by combining an aromatic ester compound of a polyalkylphenoxyalkanol with an aliphatic hydrocarbon- substituted amine which has a basic nitrogen atom and in which the hydrocarbon group has a specified number-average molecular weight. SOLUTION: This composition comprises an aromatic ester compound represented by formula I or a fuel-soluble salt thereof and an aliphatic hydrocarbon-substituted amine, desirably a branched-hydrocarbon-substituted amine, more desirably, polyisobutyl- or polyisobutenyl-amine which has at least one basic nitrogen atom and in which the hydrocarbon group has a number- average molecular weight of about 400 to about 1,000. In the formula, R is OH, NO2, -(CH2)xNR5R6; R5 and R6 are each H or a 1-6C alkyl; x is 0 or 1; R1 is H, OH, NO2, or-NR7R8; R7 and R8 are each R5; R2 and R3 are each R5; and R4 is a polyalkyl having an average molecular weight of about 450 to 5,000. It is desirable that the composition is used in a concentration of about 25 to 5,000 ppm based on a hydrocarbon fuel.

公开(公告)号：JP2000119344A

公开(公告)日：2000-04-25

申请号：JP25432299

申请日：1999-09-08

申请人： CHEVRON CHEM CO LLC

发明人： HARRISON JAMES J ,  RUHE WILLIAM R JR

IPC分类号： C10L1/224 ,  C08F8/32 ,  C08F210/00 ,  C08F222/04 ,  C08G81/02 ,  C10L1/236 ,  C10L1/2383 ,  C10L1/30 ,  C10L10/00 ,  C10L10/18 ,  C10M149/06 ,  C10M149/10 ,  C10N40/25 ,  C10L1/22

摘要： PROBLEM TO BE SOLVED: To obtain a polyalkylene polysuccinimide excellent in dispersant characteristic, and improved in hydrolysis stability, shear stress stability and fluorocarbon elastomer compatibility, and to obtain its post-treated derivative. SOLUTION: This polysuccinimide composition is obtained by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer and a polyamine under reactive conditions. An alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has an Mn of 140 to 3,000. The unsaturated acidic reagent copolymer has an average degree of polymerization of 2 to 20 and comprises the unsaturated acidic reagent and an olefin having an Mn of at least 1,000. The polyamine has at least 3 nitrogen atoms and 4 to 20 carbon atoms.

公开(公告)号：JPH11158216A

公开(公告)日：1999-06-15

申请号：JP27558598

申请日：1998-09-29

申请人： CHEVRON CHEM CO LLC

发明人： CHERPECK RICHARD E

IPC分类号： C10L1/234 ,  C08F8/00 ,  C08F10/00 ,  C08K5/13 ,  C08K5/17 ,  C08K5/29 ,  C08K5/32 ,  C10L1/198 ,  C10L1/238 ,  C10L1/2387 ,  C10L10/00 ,  C10L1/22

摘要： PROBLEM TO BE SOLVED: To decrease engine deposits, particularly intake valve deposits, by using the subject compd. as a fuel additive to a fuel compsn. SOLUTION: The substd. biphenyl polyalkylether is expressed by the formula. In the formula, R1 is H or hydroxy; R2 is hydroxyl, cyano, nitro, amino, aminomethyl, an N-alkylamino or an N-alkylaminomethyl each having a 1 to about 6C alkyl, or an N, N-dialkylamino or an N,N-dialkylaminomethyl each having independently 1 to about 6C alkyl groups; R1 and R2 are located at the ortho positions each other and are located at the meta or para positions to an adjacent phenyl substituent group; and R3 is a polyalkyl group having an average mol.wt. ranging from about 450 to about 5,000. The substd. biphenyl polyalkylether in a hydrocarbon fuel has a concn. ranging from about 50 to about 2,500 ppm by wt.

公开(公告)号：JP2001019981A

公开(公告)日：2001-01-23

申请号：JP2000166790

申请日：2000-06-02

申请人： CHEVRON CHEM CO LLC

发明人： CHERPECK RICHARD E

IPC分类号： C10L1/232 ,  C08G65/28 ,  C08G65/333 ,  C10L1/06 ,  C10L1/08 ,  C10L1/238 ,  C10L10/00 ,  C10L10/04 ,  C10L1/22

摘要： PROBLEM TO BE SOLVED: To obtain the subject new compound capable of effectively preventing and suppressing production of engine deposits, in particular inlet valve deposits, therefore useful in automotive engines and the like. SOLUTION: This new compound is a compound of formula I (A is a nitrogen-contg. ring such as 3-pyridyl, 4-pyridyl or 3-piperidyl; R1 and R2 are each H or a 1-6C alkyl, being selected independently in the case of a plurality of O-CHR1-CHR2 groups; R3 is H, a 1-100C alkyl, phenyl, a 7-100C aralkyl or the like; x is 0-4; n is about 5 to about 100) or a fuel-soluble salt thereof, e.g. a compound of formula II. This compound of formula I is obtained by deprotonation of a pyridyl compound of formula III through such a process as to catalyze the compound of formula III in a solvent such as toluene under an anhydrous condition in the presence of an appropriate base such as sodium hydride at-10 to about 120 deg.C for about 0.25 to about 3 h to form the corresponding metal salt, which, in turn is reacted with a compound of formula IV.

公开(公告)号：JP2001011118A

公开(公告)日：2001-01-16

申请号：JP2000166791

申请日：2000-06-02

申请人： CHEVRON CHEM CO LLC

发明人： CHERPECK RICHARD E ,  KRAMER JAMES D

IPC分类号： C10L1/06 ,  C08F8/30 ,  C10L1/08 ,  C10L1/22 ,  C10L1/232 ,  C10L1/238 ,  C10L1/2383 ,  C10L10/00 ,  C10L10/04

摘要： PROBLEM TO BE SOLVED: To obtain a new compound which can have an excellent preventing effect on deposits on engines, especially on inlet valves, when used as a fuel additive in fuel compositions. SOLUTION: A compound of formula I [R1 is a polyalkyl having an average mol.wt. of about 500 to 5,000; R2 is an about 2 to 6C alkylene; R3 is H or CH3; (x) is about 0 to 4], for example, a compound of formula II. The compound of formula I can be produced, for example, by a method comprising reacting (A) a polyalkenylsuccinic acid anhydride of formula III R4 is a polyalkenyl [derived from a polyolefin which is the (co)polymer of a mono-olefin, especially a 1-mono-olefin, such as ethylene, propylene or butylene]} with (B) (i) ammonia, (ii) ammonium hydroxide, (iii) methylamine or (iv) a polyamine, preferably ethylene diamine, at about 80 to 200 deg.C, and then reducing the obtained polyalkenylsuccinimde of formula IV.

公开(公告)号：JP2000160173A

公开(公告)日：2000-06-13

申请号：JP33246199

申请日：1999-11-24

申请人： CHEVRON CHEM CO LLC

发明人： HOUSER KEITH R

IPC分类号： C10L1/182 ,  C10L1/14 ,  C10L1/18 ,  C10L1/185 ,  C10L1/22 ,  C10L1/224 ,  C10L1/23 ,  C10L1/234 ,  C10L1/2383 ,  C10L10/00

摘要： PROBLEM TO BE SOLVED: To obtain the subject composition capable of effectively preventing and suppressing an engine deposit by including a hydrocarbon having a boiling point within a specific range and a fuel additive composition comprising a specified combination. SOLUTION: This composition is obtained by including (A) a major amount of a hydrocarbon having a boiling point within the range of a gasoline or a diesel fuel and (B) a fuel additive composition containing (i) 15-2,000 ppm of an aromatic ester compound represented by formula I (R is hydroxy, nitro or the like; R1 is H, hydroxy or the like; R2 and R3 are each H or a 1-6C lower alkyl; and R4 is a polyalkyl having 450-5,000 average molecular weight) or its fuel-soluble salt, (ii) 30-2,000 ppm of a poly(oxyalkylene)amine and (iii) 30-2,000 ppm of an aromatic di- or tri-carboxylic acid ester represented by formula II [R9 is a 4-20C alkyl; and (y) is 2 or 3] in which the total amount of the components (i) and (ii) is at least 70 ppm and the weight ratio of the component (iii) to the total amount of the components (i) and (ii) is 0.25:1.

公开(公告)号：JP2000143612A

公开(公告)日：2000-05-26

申请号：JP31493899

申请日：1999-11-05

申请人： CHEVRON CHEM CO LLC

发明人： MCDONALD JOHN

IPC分类号： C07C309/30 ,  C07C303/32 ,  C10M125/24 ,  C10M135/10 ,  C10M141/10 ,  C10M159/24 ,  C10M163/00 ,  C10N10/04 ,  C10N30/02 ,  C10N30/04 ,  C10N30/12 ,  C10N40/25 ,  C10N70/00

摘要： PROBLEM TO BE SOLVED: To produce the subject compound useful as a detergent-dispersant for lubricant in a new way e.g. by neutralizing sulfonic acid with a metal salt of an alkylhydroxyl aromatic hydrocarbon having a high TBN. SOLUTION: The objective compound (e.g. a low over based alkyl sulfonate or the like) is produced by one of the following three methods: (A) neutralizing sulfonic acid with a metal salt of an alkylhydroxyl aromatic hydrocarbon having a high TBN (e.g. a sulfurized carbonized alkaline earth metal alkylphenate or the like); (B) partially neutralizing sulfonic acid with lime, followed by neutralizing sulfonic acid with a metal salt of an alkylhydroxyl aromatic hydrocarbon having high a TBN; (C) neutralizing sulfonic acid with lime, followed by treating the neutralized sulfonic acid with a metal salt of an alkylhydroxyl aromatic hydrocarbon having a high TBN. The above neutralizing processes are preferably carried out in the absence of a chloride without adding a carboxylic acid.

公开(公告)号：JP2000087053A

公开(公告)日：2000-03-28

申请号：JP24410299

申请日：1999-08-30

申请人： CHEVRON CHEM CO LLC

发明人： CHERPECK RICHARD E

IPC分类号： C07D207/40 ,  C07D207/412 ,  C07D401/12 ,  C08F8/30 ,  C10L1/04 ,  C10L1/224 ,  C10L1/232 ,  C10L1/238 ,  C10L10/00 ,  C10L10/18 ,  C10L1/22

摘要： PROBLEM TO BE SOLVED: To inhibit the formation of engine deposit by blending a specific compound (a fuel-soluble salt) with a hydrocarbon having a boiling point in the range of that of a gasoline or a diesel fuel. SOLUTION: A compound of formula I or its fuel-soluble salt of 50-2,500 ppm is added to a hydrocarbon having a boiling point in the range of that of a gasoline or a diesel fuel. In formula I, R is a polyalkyl or a polyalkenyl of an average molecular weight of 450-5,000; (n) is 2-5; Z is pyridyl, piperidyl, or the like; R1 is hydroxy, nitro, cyano or (CH2)x-NR3R4; R3 and R4 are each H or a 1-6C lower alkyl; (x) is 0 or 1; R2 is H, hydroxy, nitro, cyano or (CH2)y- NR5R6; R5 and R6 are each H or a 1-6C lower alkyl; and (y) is 0 or 1. 10-70 wt.%, preferably 10-60 wt.%, of the compound of formula I is added to an inert and stable lipophilic organic solvent having a boiling point of 65-205 deg.C optionally together with an oxygenation agent, an antiknock agent, other additives such as a dispersant, a cleaning agent or the like.

公开(公告)号：JP2000080384A

公开(公告)日：2000-03-21

申请号：JP24410199

申请日：1999-08-30

申请人： CHEVRON CHEM CO LLC

发明人： CHERPECK RICHARD E ,  NELSON KENNETH D

IPC分类号： C07D405/12 ,  C07D207/40 ,  C07D207/412 ,  C08F8/30 ,  C10L1/224 ,  C10L1/232 ,  C10L1/238 ,  C10L1/2387 ,  C10L10/00 ,  C10L10/12 ,  C10L1/22

摘要： PROBLEM TO BE SOLVED: To obtain a compound effective in prohibiting formation of engine deposit by employing a specific succinimide-based compound and a fuel-soluble salt thereof. SOLUTION: A compound represented by formula I and a fuel soluble salt thereof are selected. In the formula, R is polyalkyl or polyalkenyl, having an average mol.wt. of 450-5,000; (n) is 2-5; Z is a group represented by formulae II-IV; R1 is OH, NO2, CN or -(CH2)X-NR3R4; R3-4 are each H or 1-6C alkyl;(x) is 0 or 1; and R2 is H or R1. R is preferably a polypropylene, a polybutene or a polyalkyl or polyalkenyl derived from a poly-α-olefin oligomer from 1- octene or 1-decene, or derived from a polyisobutene. A fuel composition can be constituted of a main amount of hydrocarbons in the boiling temperature range of gasoline or a diesel fuel and a deposit formation-prohibiting amount of a compound of formula I or its fuel soluble salt.

公开(公告)号：JP2000073075A

公开(公告)日：2000-03-07

申请号：JP19550799

申请日：1999-07-09

申请人： CHEVRON CHEM CO LLC

发明人： NELSON KENNETH D

IPC分类号： C07D211/64 ,  C07D211/60 ,  C07D211/62 ,  C07D213/79 ,  C07D213/80 ,  C10L1/232 ,  C10L1/238 ,  C10L10/00 ,  C10L1/22

摘要： PROBLEM TO BE SOLVED: To obtain pyridyl and piperidyl esters of polyalkylphenoxyalkanol capable of effectively inhibiting engine deposit (esp. inlet valve deposit) by utilizing it as a fuel additive to a fuel composition. SOLUTION: The pyridtyl and piperidyl esters of polyalkylphenoxyalkanol are compounds expressed by formula I (A is 3-pyridyl, 4-pyridyl, 3-piperidyl or 4-piperidyl and is pref. 4-pyridyl or 4-piperidyl; R1 is a polyalkyl group having ca. 450-5,000 average molecular weight; and R2 and R3 are each H or a 1-6C lower alkyl) or their salts soluble in fuel. The compound pref. has ca. 700-3,500 molecular weight so as to become nonvolatile at the ordinary engine inlet valve operating temperature (ca. 200-250 deg.C). The compound of formula I is obtained e.g. by subjecting a polyalkylphenol of formula II to hydroxyalkylation with an alkylenecabonate of formula III in the presence of an alkali metal hydride or the like as a catalyst and then by reacting the reaction product with pyridylcarboxylic acid.