Method of producing polar group-containing olefin copolymers
    5.
    发明专利
    Method of producing polar group-containing olefin copolymers 有权
    生产含极性烯烃烯烃共聚物的方法

    公开(公告)号:JP2014159540A

    公开(公告)日:2014-09-04

    申请号:JP2013099944

    申请日:2013-05-10

    IPC分类号: C08F4/80 C08F10/00

    摘要: PROBLEM TO BE SOLVED: To provide a method of producing high molecular mass polymers of polar group-containing monomers such as a polar group-containing allyl compound.SOLUTION: Provided is a method for producing a homopolymer of an olefin of the general formula (1): CH=CHR(Ris a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms) or a copolymer of two or more of such olefins, or a method for producing a copolymer of an olefin of the general formula (1) with an olefin having a polar group represented by the general formula (2): CH=CHRR(Ris a hydrogen atom or a methyl group, and Ris -COOR, -CN, -OCOR, -OR, -CH-OCOR, -CHOH, -CH-N(R)or -CH-Hal, where R, Rand Hal are as described in the specifications), using as a catalyst a complex of group 10 metals in the periodic table having a structure represented by the specified formula 1 (Men represents a menthyl group).

    摘要翻译: 要解决的问题:提供一种制备含极性基团的烯丙基化合物的极性基团单体的高分子量聚合物的方法。提供一种制备通式(1)的烯烃均聚物的方法, ):CH = CHR(R为氢原子或碳原子数1〜20的烃基)或这些烯烃中的2种以上的共聚物,或者将通式(1)的烯烃与 具有由通式(2)表示的极性基团的烯烃:CH = CHRR(R是氢原子或甲基,Ris -COOR,-CN,-OCOR,-OR,-CH-OCOR,-CHOH, -CH-N(R)或-CH-Hal,其中R,Rand Hal如说明书所述),使用具有由规定式1表示的结构的周期表中的第10族金属的络合物作为催化剂 男士代表薄荷基)。