Method of decomposition treating polymethylene polyphenylene polyisocyanate-based polyurea compound
    4.
    发明专利
    Method of decomposition treating polymethylene polyphenylene polyisocyanate-based polyurea compound 审中-公开
    聚乙烯聚苯乙烯聚异氰酸酯基聚氨酯复合物的分解处理方法

    公开(公告)号:JP2010254924A

    公开(公告)日:2010-11-11

    申请号:JP2009109835

    申请日:2009-04-28

    Abstract: PROBLEM TO BE SOLVED: To provide a method of decomposition treating a polymeric MDI-based polyurea compound by which a reusable polymethylene polyphenyl polyamine (PMDA) is recovered without adding any hydrolysis accelerator such as an alkali to a polyurea residue, produced as a by-product in the manufacture of polymethylene polyphenylene polyisocyanate (polymeric MDI), for which there has been no other choice but to be disposed of, and which does not bring about any corrosion problem of a reactor. SOLUTION: In the method of decomposition treating the polymeric MDI-based polyurea compound, the polymeric MDI-based polyurea compound is hydrolyzed in carbon dioxide in a supercritical or subcritical state. COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 待解决的问题:提供一种分解处理聚合MDI基聚脲化合物的方法,通过该方法可回收可重复使用的聚亚甲基多苯基多胺(PMDA),而不向聚脲残留物中加入任何水解加速剂如碱,生成为 在聚亚甲基聚亚苯基多异氰酸酯(聚合MDI)的制造中的副产物,其没有其他选择而不能被处理,并且不会引起反应器的任何腐蚀问题。 解决方案:在聚合MDI基聚脲化合物的分解处理方法中,聚合MDI基聚脲化合物在二氧化碳中以超临界或亚临界状态水解。 版权所有(C)2011,JPO&INPIT

    Polyurea electrolyte and production method therefor
    9.
    发明专利
    Polyurea electrolyte and production method therefor 有权
    聚氨酯电解液及其生产方法

    公开(公告)号:JP2011021176A

    公开(公告)日:2011-02-03

    申请号:JP2010126776

    申请日:2010-06-02

    Abstract: PROBLEM TO BE SOLVED: To provide a polyurea electrolyte suitable for an electrolyte membrane for a fuel cell and excellent in mechanical strength and acid resistance.
    SOLUTION: The polyurea electrolyte includes a polyurea resin formed by polymerizing a first compound having two or more isocyanate groups and a second compound having two or more amino groups. The polyurea electrolyte is characterized in that the first compound or the second compound contains ten or more carbon chains, and in that the first compound or the second compound contains a sulfonic acid group or a carboxylic acid group. Further, the production method for the polyurea electrolyte is characterized by including a step of neutralizing the sulfonic acid group or the carboxylic acid group in the first compound or the second compound using a neutralizer, a step of polymerizing the first compound and the second compound following the neutralization step, and a step of removing the neutralizer from the polymer of the first compound and the second compound following the polymerization step.
    COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 要解决的问题:提供一种适用于燃料电池用电解质膜的聚脲电解质,其机械强度和耐酸性优异。 解决方案:聚脲电解质包括通过聚合具有两个或更多个异氰酸酯基团的第一化合物和具有两个或更多个氨基的第二化合物形成的聚脲树脂。 聚脲电解质的特征在于,第一化合物或第二化合物含有十个以上的碳链,第一化合物或第二化合物含有磺酸基或羧酸基。 此外,聚脲电解质的制造方法的特征在于包括使用中和剂中和第一化合物或第二化合物中的磺酸基或羧酸基的工序,使第一化合物和第二化合物聚合的工序如下 中和步骤,以及在聚合步骤之后从第一化合物和第二化合物的聚合物中除去中和剂的步骤。 版权所有(C)2011,JPO&INPIT

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