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    NOVEL CALIXARENE DERIVATIVE AND CURABLE RESIN COMPOSITION CONTAINING THE SAME
    3.
    发明专利
    NOVEL CALIXARENE DERIVATIVE AND CURABLE RESIN COMPOSITION CONTAINING THE SAME 失效

    公开(公告)号：JP2000256362A

    公开(公告)日：2000-09-19

    申请号：JP6108799

    申请日：1999-03-09

    申请人： KURARAY CO ,  UNIV KANAGAWA

    发明人： NISHIKUBO TATATOMI ,  KAMEYAMA ATSUSHI ,  ANDO YOSHINORI

    IPC分类号： C07D493/10 ,  C08G4/00 ,  C08G8/36 ,  C08G65/16 ,  C08G85/00

    摘要： PROBLEM TO BE SOLVED: To obtain a novel calixarene derivative that can provide a curable resin composition which causes no volumetric shrinkage on the polymerization and is not adversely affected by oxygen on curing and is useful as a coating material, or the like. SOLUTION: This is a calixarene derivative represented by formula I (R1 is H, an alkyl; R2 is H, a lower alkyl; (n) is 4-10; one of X1 and X2 is a spiro ortho ester derivative of formula II, and the other is H). The derivative of formula I is prepared, for example, by stirring a p-alkylcalixarene as a starting material together with cesium carbonate in a solvent, adding a halogenated acetic ester thereto in the presence of a phase transfer catalyst and heating to form an ether, then adding a basic substance thereto, stirring them in a solvent, further admixing a phase transfer catalyst and water and stirring them under heating to obtain a carboxylic acid, adding a solvent to the mixture of the resultant carboxylic acid and 1,8-azabicyclo[5.4.0]-7-undecene, finally dripping 2-bromomethy-1,4,6-trioxaspiro[4.4]nonane to the mixture under stirring with heat.

    4.
    发明专利
    失效

    公开(公告)号：JP3031492B2

    公开(公告)日：2000-04-10

    申请号：JP12323791

    申请日：1991-03-05

    IPC分类号： B05D7/02 ,  B32B1/02 ,  B32B27/00 ,  B32B27/08 ,  B32B27/28 ,  B32B27/30 ,  B65D1/00 ,  B65D65/40 ,  B65D81/34 ,  C08G4/00 ,  C08G6/00 ,  C08J7/04 ,  B65D1/09

    摘要： Containers made from polymeric material comprising: a shaped first material layer formed from a linear alternating polyketone polymer having repeating units of the formula -CO &lparstr& A &rparstr& wherein A represents a moiety derived from the same or different ethylenically unsaturated hydrocarbons polymerized through the ethylenic linkage, a cooperatively shaped second material layer formed by coating a copolymer of vinylidene chloride on at least one side of said first material layer, have good oxygen and water barrier properties, and are suitable for retorting or heating in both convection and microwave ovens without mechanical deterioration. n

    PRODUCTION OF ACETONE-FORMALDEHYDE CONDENATE
    7.
    发明专利
    PRODUCTION OF ACETONE-FORMALDEHYDE CONDENATE 失效

    公开(公告)号：JPH06220149A

    公开(公告)日：1994-08-09

    申请号：JP3274493

    申请日：1993-01-27

    申请人： TAOKA CHEMICAL CO LTD

    发明人： TAKAHASHI KATSUHIRO ,  HANNO KEIKO ,  OHASHI KOICHI

    IPC分类号： C08G6/02 ,  C08G4/00

    摘要： PURPOSE:To obtain the subject condensate, capable of mildly advancing reaction, excellent in safety, compatibility, mixability and adhesion and useful as adhesives, etc., by condensing acetone with formaldehyde in a specific proportion in the presence of an alkaline catalyst in the coexistence of a phenolic compound. CONSTITUTION:One mol acetone is condensed with 1.4-3mol formaldehyde in the presence of an alkaline catalyst such as sodium hydroxide in the coexistence of a phenolic compound such as phenol in an amount of preferably 30-150% (based on the equiv. of the alkaline catalyst) to afford the objective condensate.