탄소나노튜브섬유의 제조장치 및 이를 이용한 탄소나노튜브섬유 제조방법
    53.
    发明公开
    탄소나노튜브섬유의 제조장치 및 이를 이용한 탄소나노튜브섬유 제조방법 有权
    用于制备碳纳米管纤维的装置和使用其制备碳纳米管的方法

    公开(公告)号:KR1020160049998A

    公开(公告)日:2016-05-10

    申请号:KR1020150150087

    申请日:2015-10-28

    Abstract: 본발명은탄소나노튜브섬유제조장치에관한것으로서, 반응영역을구비한수직형반응기본체; 방사용액및 제1가스를포함하는방사원료를상기반응영역으로주입하는내부관및 상기내부관을둘러싼동심축환형부를형성하고이를통해제2가스를상기반응영역으로주입하는외부관을구비한동심축이중관형유입관; 상기반응영역을가열하기위한가열수단; 및상기반응영역하단에설치되는탄소나노튜브섬유배출부;를포함하고, 상기유입관의내부관을통해반응영역상단으로유입된방사원료는반응영역상단으로부터하단을향해유동하면서탄화및 흑연화됨으로써탄소나노튜브의연속집합체로이루어진탄소나노유브섬유를형성하고, 상기유입관의외부관을통해반응영역상단으로유입된제2가스는반응영역상단으로부터하단을향해유동하면서상기탄소나노튜브연속집합체의둘레를감싸는형태로가스커튼을형성하는것을특징으로하는탄소나노튜브섬유제조장치를제공한다. 본발명에따른장치는내벽의오염으로인한오염을최소화하고. 제조된탄소나노튜브섬유의배출을원활하게하여연속공정에바람직하다.

    Abstract translation: 本发明涉及碳纳米管纤维的制造装置,其特征在于,包括:具有反应面积的立式反应器主体; 具有内管和外管的同心轴双管型流入管,内管将包含纺丝溶液和第一气体的纺丝原料注入反应区域,并且外管形成同心轴环形 围绕内管的部分,并且通过同心轴环形部分将第二气体注入反应区域; 加热装置加热反应区域; 以及安装在反应区域的下端的碳纳米管纤维排出部,其中通过流入管的内管流入反应区域的上端的纺丝原料从反应区域的上端朝向 碳化和石墨化,由此形成由碳纳米管的连续聚集体形成的碳纳米管纤维,并且通过流入管的外管流入反应区域的上端的第二气体从上游端 反应区域朝向其下端,并形成围绕碳纳米管的连续聚集体的圆周的气幕。 根据本发明的装置将由污染的内壁引起的污染减到最小,并且能够使生成的碳纳米管纤维平滑地排放,因此对于连续方法是优选的。

    탄소나노튜브섬유 제조장치 및 이를 이용한 탄소나노튜브섬유 제조방법
    55.
    发明公开
    탄소나노튜브섬유 제조장치 및 이를 이용한 탄소나노튜브섬유 제조방법 有权
    用于制备碳纳米管纤维的装置和使用其制备碳纳米管的方法

    公开(公告)号:KR1020140147004A

    公开(公告)日:2014-12-29

    申请号:KR1020140065029

    申请日:2014-05-29

    Abstract: The present invention relates to an apparatus for manufacturing carbon nanotube fiber, comprising: a vertical reactor body having a reaction area; a spinning solution inlet for injecting spinning solution into the lower part of the reaction zone of the body; a transferred gas inlet for introducing transferred gas into the lower part of the reaction zone of the body; a heating means for heating the reaction zone; and a carbon nanotube fiber outlet installed at the upper end of the reaction zone. The present invention provides an apparatus for manufacturing carbon nanotube fiber and a method for manufacturing carbon nanotube fiber using the same, wherein the spinning solution introduced into the reaction zone from the spinning solution inlet forms carbon nanotube fiber consisting of continuous aggregate of carbon nanotubes by being carbonized and graphitized while flowing upward from the lower end of the reaction zone owing to the transferred gas introduced through the transferred gas inlet. The carbon nanotube fiber using the apparatus according to the present invention can be applied to various fields such as multifunctional composite materials, deformation/damage sensors, power transmission lines and electrochemical devices, e.g., micro-electrode materials for detecting biological materials, supercapacitors and actuators as the carbon nanotube fiber is long and has excellent electrical conductivity, tensile strength and elasticity.

    Abstract translation: 碳纳米管纤维制造装置技术领域本发明涉及一种碳纳米管纤维的制造装置,其特征在于: 用于将纺丝溶液注入到身体的反应区的下部的纺丝溶液入口; 用于将转移的气体引入到身体的反应区的下部的转移气体入口; 用于加热反应区的加热装置; 和安装在反应区上端的碳纳米管纤维出口。 本发明提供一种碳纳米管纤维的制造装置及使用该装置的碳纳米管纤维的制造方法,其中从纺丝溶液入口引入反应区的纺丝溶液由碳纳米管的连续聚集体构成的碳纳米管纤维 碳酸化和石墨化,同时由于通过转移的气体入口引入的转移气体从反应区的下端向上流动。 使用根据本发明的装置的碳纳米管纤维可以应用于多功能复合材料,变形/损伤传感器,输电线路和电化学装置等各种领域,例如用于检测生物材料的微电极材料,超级电容器和致动器 由于碳纳米管纤维长且具有优异的导电性,拉伸强度和弹性。

    메탈 멤브레인을 이용한 연속식 카본나노튜브 제조장치 및 제조방법
    58.
    发明公开
    메탈 멤브레인을 이용한 연속식 카본나노튜브 제조장치 및 제조방법 有权
    连续制造碳纳米管制造装置与金属膜方法

    公开(公告)号:KR1020140007195A

    公开(公告)日:2014-01-17

    申请号:KR1020120074599

    申请日:2012-07-09

    CPC classification number: C01B32/164 B01D71/022 B01J31/12 B82B3/0004

    Abstract: The present invention relates to a continuous carbon nanotube manufacturing apparatus using a metallic membrane and a continuous carbon nanotube manufacturing method using a metallic membrane and, more specifically, to a continuous carbon nanotube manufacturing apparatus using a metallic membrane comprising: a reaction unit in which carbon nanotubes are synthesized; a separation unit which separates mixture gas from the carbon nanotubes transferred from the reaction unit; a gas separation unit of a metallic membrane type which removes a part or the whole of at least one gas component from the separated mixture gas; and a recirculation pipe which recirculates filtered mixture gas to the carbon nanotube reaction unit, and a continuous carbon nanotube manufacturing method using a metallic membrane. The present invention facilitates a high speed process, exhibits excellent productivity and the conversion rate of a carbon source, does not need the installation of a heat exchanger since temperature does not have to be lowered in gas separation, dramatically reduces production costs by recirculating gas after being emitted from the reaction unit without passing a cooling process and reducing calorie required for a preheater, reduces energy consumption by reducing the size of the reaction unit in comparison to a capacity, and scarcely generates waste gas.

    Abstract translation: 本发明涉及使用金属膜的连续碳纳米管制造装置和使用金属膜的连续碳纳米管制造方法,更具体地,涉及使用金属膜的连续碳纳米管制造装置,其包括:反应单元,其中碳 合成纳米管; 分离单元,其从与所述反应单元转移的碳纳米管分离混合气体; 从分离的混合气体中除去至少一种气体成分的一部分或全部的金属膜型气体分离单元; 以及将过滤的混合气体再循环到碳纳米管反应单元的再循环管,以及使用金属膜的连续碳纳米管制造方法。 本发明有利于高速工艺,显示出优异的生产率和碳源的转化率,不需要安装热交换器,因为在气体分离中不必降低温度,因此通过再循环气体显着降低生产成本 从反应单元排出而不通过冷却过程并降低预热器所需的热量,通过与容量相比减小反应单元的尺寸并且几乎不产生废气来降低能量消耗。

    연속식 카본나노튜브 제조장치 및 제조방법
    60.
    发明公开
    연속식 카본나노튜브 제조장치 및 제조방법 有权
    连续碳纳米管制造设备和方法

    公开(公告)号:KR1020120114453A

    公开(公告)日:2012-10-17

    申请号:KR1020110031471

    申请日:2011-04-06

    CPC classification number: C01B32/164 B01J8/1827 B01J19/24 B82B3/0004

    Abstract: PURPOSE: A continuous carbon nano-tube manufacturing apparatus and a method for the same are provided to improve environmentally-friendly characteristic by suppressing the generation of waste gas. CONSTITUTION: A continuous carbon nano-tube manufacturing method includes the following: reaction gas containing carbon sources, reductive gas, and inert gas is reacted with a catalyst to generate carbon nano-tubes; the generated carbon nano-tube is separated from mixed gas; the separated mixed gas is filtered through a gas separating unit(600) in the shape of a metal membrane to separate whole or a part of reductive gas; and the filtered mixed gas is re-circulated to the carbon nano-tube generating process. [Reference numerals] (AA) Hydrogen storage; (BB) Exhaust gas treatment

    Abstract translation: 目的:提供连续的碳纳米管制造装置及其制造方法,通过抑制废气的产生来提高环保特性。 构成:连续的碳纳米管制造方法包括:将含碳源,还原气体和惰性气体的反应气与催化剂反应生成碳纳米管; 将生成的碳纳米管与混合气体分离; 分离的混合气体通过金属膜形式的气体分离单元(600)过滤以分离全部或一部分还原气体; 将过滤后的混合气体再循环至碳纳米管生成工序。 (附图标记)(AA)储氢; (BB)废气处理

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