公开(公告)号：KR1020070101815A

公开(公告)日：2007-10-17

申请号：KR1020070036471

申请日：2007-04-13

Applicant: 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드

Inventor： 마차도레이날도마리오 ,  하르츠크리스토퍼엘. ,  홀렌제임스이. ,  모흐레베카제이. ,  리알스조지엘.

IPC: C25B1/02

CPC classification number: C25B1/00 ,  C23C16/4488 ,  C25B15/08

Abstract: A method and an apparatus for achieving maximum yield in the electrolytic preparation of group IV and V hydrides are provided to generate a gas of high purity and to supply a gas producing stream by choosing the concentration of M3OH less than the maximum concentration of M3OH to be the initial concentration of M3OH. A method for achieving maximum yield in the electrolytic preparation of group IV and V hydrides comprises the steps of: determining solubility profile curves of the metal salt when the M3OH is exhausted and the metal oxide is formed by the oxidation reaction at diverse concentrations of M3OH; determining the maximum concentration of M3OH in which the concentration of metal salt deposited from the electrolytic solution is not produced when the M3OH is exhausted; and selecting the concentration of M3OH which is in the range of at and within 5% less than the maximum concentration of M3OH to be the initial concentration of M3OH.

Abstract translation: 提供了用于在IV族和V型氢化物的电解制备中获得最大产率的方法和装置，以产生高纯度的气体，并且通过选择小于M3OH的最大浓度的M3OH浓度来提供气体产生流 初始浓度为M3OH。 在IV族和V型氢化物的电解制备中获得最大产率的方法包括以下步骤：当M3OH排出时确定金属盐的溶解度曲线曲线，并且在不同浓度的M3OH下通过氧化反应形成金属氧化物; 确定在M3OH排出时不产生从电解液沉积的金属盐浓度的M3OH的最大浓度; 并选择M3OH的浓度在M3OH的最大浓度以下的5％以内的范围内，作为M3OH的初始浓度。

公开(公告)号：KR100457284B1

公开(公告)日：2004-11-16

申请号：KR1020020051376

申请日：2002-08-29

Applicant: 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드

Inventor： 웰프키스앨런 ,  카톨라노앤소니로코 ,  파릴로데이비드조지프 ,  보엠리차드피터 ,  마차도레이날도마리오 ,  카람실비아

IPC: B01J8/04

CPC classification number: B01F5/0643 ,  B01J19/0053 ,  B01J19/2485 ,  B01J35/04 ,  C07C209/36 ,  Y02P20/582

Abstract: The invention pertains to an improved apparatus comprised of a monolith catalytic reactor having an inlet and an outlet and a static mixer having an inlet and an outlet thereto with the outlet of said static mixer in communication with the inlet of said monolith catalytic reactor. The invention also pertains to an improvement in a process for effecting a reaction in the monolith catalytic reactor wherein a reactant gas and reactant liquid are introduced to the inlet to the monolith catalytic reactor, reacted and, then, the reaction product passed through the outlet of the monolith catalytic reactor.

Abstract translation: 本发明涉及一种改进的设备，该设备包括具有入口和出口的整体式催化反应器和具有入口和出口的静态混合器，所述静态混合器的出口与所述整体式催化反应器的入口连通。 本发明还涉及在整体式催化反应器中进行反应的方法的改进，其中反应物气体和反应物液体被引入到整体式催化反应器的入口，反应，然后反应产物通过 整体式催化反应器。 ＆lt;图像＆GT;

公开(公告)号：KR100870161B1

公开(公告)日：2008-11-24

申请号：KR1020070036471

申请日：2007-04-13

Applicant: 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드

Inventor： 마차도레이날도마리오 ,  하르츠크리스토퍼엘. ,  홀렌제임스이. ,  모흐레베카제이. ,  리알스조지엘.

IPC: C25B1/02

CPC classification number: C25B1/00 ,  C23C16/4488 ,  C25B15/08

Abstract: 본 발명은 금속 M
1 을 포함하는 캐소드, 금속 M
2 를 포함하는 희생 애노드(sacrificial anode), 및 금속 수산화물, M
3 OH를 포함하는 초기 농도(initial concentration)의 전해질 수용액을 포함하는 전기화학적 전지에서 금속 M
1 의 수소화 물 가스를 생성하는 방법으로서, 여기서 희생용 금속 애노드는 M
3 OH를 포함하는 전해질 수용액의 존재 하에 전기화학적으로 산화되어 금속 염을 형성하고, 금속 M
1 의 수소화물 가스는 캐소드의 금속 M
1 을 환원시킴으로써 형성되는 것인 방법을 제공한다. 본 방법은 M
3 OH가 소모되고 금속 산화물이 M
3 OH의 다양한 농도에서 산화 반응에 의해 형성될 때의 금속 염의 용해도 프로필 곡선을 결정하는 단계; M
3 OH가 소모될 때 전해질 용액으로부터 침전되는 금속 염의 농도를 생성하지 않는 M
3 OH의 최대 농도를 결정하는 단계; 및 M
3 OH의 최대 농도보다 5% 및 5% 이내 더 작은 범위에 있는 M
3 OH의 농도를 M
3 OH의 초기 농도로 선택하는 단계를 포함한다.
전기화학적 전지, 캐소드, 희생 애노드

公开(公告)号：KR1020030019191A

公开(公告)日：2003-03-06

申请号：KR1020020051376

申请日：2002-08-29

Applicant: 에어 프로덕츠 앤드 케미칼스, 인코오포레이티드

Inventor： 웰프키스앨런 ,  카톨라노앤소니로코 ,  파릴로데이비드조지프 ,  보엠리차드피터 ,  마차도레이날도마리오 ,  카람실비아

IPC: B01J8/04

CPC classification number: B01F5/0643 ,  B01J19/0053 ,  B01J19/2485 ,  B01J35/04 ,  C07C209/36 ,  Y02P20/582

Abstract: PURPOSE: An apparatus comprising a monolith catalytic reactor having an inlet and an outlet and a static mixer having an inlet and an outlet with the outlet of the static mixer in communication with the inlet of the monolith catalytic reactor, and an improved process for effecting reaction between a reactant gas and reactant liquid in a monolith catalytic reactor are provided. CONSTITUTION: In a process for the heterogeneous catalytic reaction of a mixture of a reactant gas and reactant liquid in a monolith catalytic reactor under conditions of reaction, the process comprises the steps of initially mixing the reactant gas with the reactant liquid in a static mixer thereby forming a frothy mixture, introducing the resultant frothy mixture into the monolith catalytic reactor for reaction, and, then, recovering reaction product from the monolith catalytic reactor. The apparatus is comprised of in combination a monolith catalytic reactor(4) having an inlet and an outlet and a static mixer(1) having an inlet and an outlet with the outlet of the static mixer in communication with the inlet of the monolith catalytic reactor, wherein the monolith catalytic reactor has from 100 to 1200 cells(15) per square inch, wherein the static mixer is comprised of a plurality of parallel channels defining alternating flow paths which extend angularly to the longitudinal axis, wherein the static mixers is comprised of a plurality of mixing sections(3) with each mixing section rotated about the longitudinal axis in the direction of flow from the preceding section, wherein the parallel channels interact at angles of 45 to about 90 degrees, wherein the sections in the static mixer are rotated from about 45 to 90 degrees about the longitudinal axis from the preceding section in the direction of flow, and wherein the catalytic metal deposited on the surface of the monolith is a Group VIb, Group VIIb, or Group VIII or Group Ib metal.

Abstract translation: 目的：一种包括具有入口和出口的整体式催化反应器的装置和具有静态混合器的出口与整体式催化反应器的入口连通的入口和出口的静态混合器，以及用于进行反应的改进方法 提供了在整体催化反应器中的反应气体和反应物液体之间。 构成：在反应条件下在整体式催化反应器中反应气体和反应物液体的混合物的非均相催化反应的方法中，该方法包括以下步骤：首先将反应物气体与反应物液体在静态混合器中混合，由此 形成泡沫混合物，将所得的泡沫混合物引入用于反应的整体式催化反应器中，然后从整体式催化反应器回收反应产物。 该装置组合有具有入口和出口的整体式催化反应器（4）和静态混合器（1），静态混合器（1）具有入口和出口，静态混合器的出口与整体式催化反应器的入口连通 ，其中所述整体催化反应器具有每平方英寸100至1200个电池（15），其中所述静态混合器由限定与所述纵向轴线成角度延伸的交替流动路径的多个平行通道组成，其中所述静态混合器由 多个混合部分（3），其中每个混合部分沿着来自前一部分的流动方向围绕纵向轴线旋转，其中平行通道以45至约90度的角度相互作用，其中静态混合器中的部分旋转 围绕来自前一部分的沿着流动方向的纵向轴线约45至90度，并且其中沉积在单体表面上的催化金属 锂是VIb族，VIIb族，VIII族或Ib族金属。