公开(公告)号：US08697829B2

公开(公告)日：2014-04-15

申请号：US13343178

申请日：2012-01-04

申请人： Anubhav Saxena ,  Alok Sarkar

发明人： Anubhav Saxena ,  Alok Sarkar

IPC分类号： C08G77/10 ,  C08G77/28 ,  C08G77/392 ,  C08F283/12 ,  H01B1/12 ,  H01M6/18

CPC分类号： C08G77/392 ,  C08G77/10

摘要： A process for the manufacture of polyorganosiloxanes having ionic groups and reactive functional groups includes (a) conversion of a low molecular weight aralkylene modified polysiloxane to a corresponding sulfonic acid functional material by treating the low molecular weight aralkylene modified polysiloxane with a sulfonating agent; (b) subjecting the reaction product obtained in step (a) to an equilibration reaction with an acid catalyzed ring opening polymerization-effective polyorganosiloxane; and (c) subjecting the reaction product obtained in step (b) to a hydrosilylation reaction with an unsaturated hydrocarbon containing at least one epoxy group, an unsaturated hydrocarbon containing at least two unsaturation moieties, an unsaturated hydrocarbon containing at least one sulfur heteroatom, an unsaturated hydrocarbon containing a monovalent organosilane group, an unsaturated hydrocarbon containing one hydroxyl containing group, an unsaturated hydrocarbon containing one or more of a halogen, carboxylate, imine, isocyanate, amide, nitrile or tertiary amine with other than alkyl groups moiety.

摘要翻译： 制备具有离子基团和反应性官能团的聚有机硅氧烷的方法包括（a）通过用磺化剂处理低分子量亚烷基改性聚硅氧烷将低分子量亚芳基改性聚硅氧烷转化为相应的磺酸官能材料; （b）使步骤（a）中获得的反应产物与酸催化的开环聚合有效的聚有机硅氧烷进行平衡反应; 和（c）使步骤（b）中获得的反应产物与含有至少一个环氧基的不饱和烃，含有至少两个不饱和部分的不饱和烃，含有至少一个硫杂原子的不饱和烃进行氢化硅烷化反应， 含有一价有机硅烷基的不饱和烃，含有一个含羟基的不饱和烃，含烷基部分以外的卤素，羧酸酯，亚胺，异氰酸酯，酰胺，腈或叔胺中的一种或多种的不饱和烃。

公开(公告)号：US20130172510A1

公开(公告)日：2013-07-04

申请号：US13343178

申请日：2012-01-04

申请人： Anubhav Saxena ,  Alok Sarkar

发明人： Anubhav Saxena ,  Alok Sarkar

IPC分类号： C08G77/14

CPC分类号： C08G77/392 ,  C08G77/10

摘要： A process for the manufacture of polyorganosiloxanes having ionic groups and reactive functional groups includes (a) conversion of a low molecular weight aralkylene modified polysiloxane to a corresponding sulfonic acid functional material by treating the low molecular weight aralkylene modified polysiloxane with a sulfonating agent; (b) subjecting the reaction product obtained in step (a) to an equilibration reaction with an acid catalyzed ring opening polymerization-effective polyorganosiloxane; and (c) subjecting the reaction product obtained in step (b) to a hydrosilylation reaction with an unsaturated hydrocarbon containing at least one epoxy group, an unsaturated hydrocarbon containing at least two unsaturation moieties, an unsaturated hydrocarbon containing at least one sulfur heteroatom, an unsaturated hydrocarbon containing a monovalent organosilane group, an unsaturated hydrocarbon containing one hydroxyl containing group, an unsaturated hydrocarbon containing one or more of a halogen, carboxylate, imine, isocyanate, amide, nitrile or tertiary amine with other than alkyl groups moiety.

摘要翻译： 制备具有离子基团和反应性官能团的聚有机硅氧烷的方法包括（a）通过用磺化剂处理低分子量亚烷基改性聚硅氧烷将低分子量亚芳基改性聚硅氧烷转化为相应的磺酸官能材料; （b）使步骤（a）中获得的反应产物与酸催化的开环聚合有效的聚有机硅氧烷进行平衡反应; 和（c）使步骤（b）中获得的反应产物与含有至少一个环氧基的不饱和烃，含有至少两个不饱和部分的不饱和烃，含有至少一个硫杂原子的不饱和烃进行氢化硅烷化反应， 含有一价有机硅烷基的不饱和烃，含有一个含羟基的不饱和烃，含烷基部分以外的卤素，羧酸酯，亚胺，异氰酸酯，酰胺，腈或叔胺中的一种或多种的不饱和烃。

公开(公告)号：US08974775B2

公开(公告)日：2015-03-10

申请号：US13343188

申请日：2012-01-04

申请人： Anubhav Saxena ,  Alok Sarkar ,  Sandip Tiwari

发明人： Anubhav Saxena ,  Alok Sarkar ,  Sandip Tiwari

IPC分类号： C09D5/16 ,  A61K8/89

CPC分类号： C08G77/26 ,  A01N25/10 ,  A01N25/24 ,  A01N25/30 ,  A61K8/894 ,  A61K8/895 ,  A61K8/898 ,  A61K8/899 ,  A61K2800/10 ,  A61Q19/00 ,  C08G77/12 ,  C08G77/14 ,  C08G77/20 ,  C08G77/24 ,  C08G77/28 ,  C08G77/46 ,  C09D5/14 ,  C09D5/1675 ,  C09D183/06 ,  C09D183/08 ,  C09D183/12

摘要： There is provided herein a functionalized ionic silicone composition comprising a silicone of the formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj  (I) which contains a monovalent radical bearing ion-pairs and having the formula (II): -A-Ix−Mny+; where A is a spacing group having at least 2 spacing atoms selected from a divalent hydrocarbon or hydrocarbonoxy group, where I is an ionic group such as sulfonate —SO3−, carboxylate —COO−, phosphonate —PO32− group and phosphate —OPO32−, where M is hydrogen or a cation independently selected from alkali metals, alkali earth metals, transition metals, metals, quaternary ammonium and phosphonium groups; or, zwitterions having the formula (III): —R′—NR″2+—R′″—I  (III) where I is defined as above, and where the subscript a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2≦a+b+c+d+e+f+g+h+i+j≦6000, b+e+h>0 and c+f+i>0.

摘要翻译： 本文提供了包含式（I）的硅氧烷：M1aM2bM3cD1dD2eD3fT1gT2hT3iQj（I）的官能化离子硅氧烷组合物，其含有带有离子对的一价基团并具有式（II）：-A-Ix-Mny +; 其中A是具有选自二价烃或烃氧基的至少2个间隔原子的间隔基团，其中I是离子基团，例如磺酸酯-SO 3 - ，羧酸酯-COO-，膦酸酯-PO 32 - 基团和磷酸酯-OPO 32 - 其中M是氢或独立地选自碱金属，碱土金属，过渡金属，金属，季铵和鏻基的阳离子; 或者具有式（III）的两性离子：-R'-NR“2 + -R'” - I（III）其中I如上定义，并且其中下标a，b，c，d，e，f， 受限于以下限制：2＆nlE; a + b + c + d + e + f + g + h + i + j＆nlE; 6000，b + e + h> 0和c + f + i> 0。

公开(公告)号：US20140017188A1

公开(公告)日：2014-01-16

申请号：US13734308

申请日：2013-01-04

申请人： Alok Sarkar ,  Anubhav Saxena ,  Sandip Tiwari ,  Benjamin Falk ,  Anne Dussaud

发明人： Alok Sarkar ,  Anubhav Saxena ,  Sandip Tiwari ,  Benjamin Falk ,  Anne Dussaud

IPC分类号： A61K8/899 ,  A61Q1/04 ,  A61Q5/12 ,  A61K8/896

CPC分类号： A61K8/899 ,  A61K8/896 ,  A61K2800/10 ,  A61Q1/04 ,  A61Q5/06 ,  A61Q5/12 ,  A61Q17/04 ,  A61Q19/00

摘要： A personal care composition includes at least one end-functionalized ionic silicone and at least one film-forming agent.

摘要翻译： 个人护理组合物包括至少一种末端官能化的离子硅氧烷和至少一种成膜剂。

公开(公告)号：US20130172193A1

公开(公告)日：2013-07-04

申请号：US13343188

申请日：2012-01-04

申请人： Anubhav Saxena ,  Alok Sarkar ,  Sandip Tiwari

发明人： Anubhav Saxena ,  Alok Sarkar ,  Sandip Tiwari

IPC分类号： C08G77/28

CPC分类号： C08G77/26 ,  A01N25/10 ,  A01N25/24 ,  A01N25/30 ,  A61K8/894 ,  A61K8/895 ,  A61K8/898 ,  A61K8/899 ,  A61K2800/10 ,  A61Q19/00 ,  C08G77/12 ,  C08G77/14 ,  C08G77/20 ,  C08G77/24 ,  C08G77/28 ,  C08G77/46 ,  C09D5/14 ,  C09D5/1675 ,  C09D183/06 ,  C09D183/08 ,  C09D183/12

摘要： There is provided herein a functionalized ionic silicone composition comprising a silicone of the formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj  (I) which contains a monovalent radical bearing ion-pairs and having the formula (II): -A-Ix-Mny+; where A is a spacing group having at least 2 spacing atoms selected from a divalent hydrocarbon or hydrocarbonoxy group, where I is an ionic group such as sulfonate —SO3−, carboxylate —COO−, phosphonate —PO32− group and phosphate —OPO32−, where M is hydrogen or a cation independently selected from alkali metals, alkali earth metals, transition metals, metals, quaternary ammonium and phosphonium groups; or, zwitterions having the formula (III): —R′—NR″2+—R′″—I  (III) where I is defined as above, and where the subscript a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2≦a+b+c+d+e+f+g+h+i+j≦6000, b+e+h>0 and c+f+i>0.

摘要翻译： 本文提供了包含式（I）的硅氧烷：M1aM2bM3cD1dD2eD3fT1gT2hT3iQj（I）的官能化离子硅氧烷组合物，其含有带有离子对的一价基团并具有式（II）：-A-Ix-Mny +; 其中A是具有选自二价烃或烃氧基的至少2个间隔原子的间隔基团，其中I是离子基团，例如磺酸酯-SO 3 - ，羧酸酯-COO-，膦酸酯-PO 32 - 基团和磷酸酯-OPO 32 - 其中M是氢或独立地选自碱金属，碱土金属，过渡金属，金属，季铵和鏻基的阳离子; 或者具有式（III）的两性离子：-R'-NR''2 + -R“'-I（III）其中I如上所定义，其中下标a，b，c，d，e， 受限于以下限制，f，g，h，i，j为零或正数：2 @ a + b + c + d + e + f + g + h + i + j @ 6000，b + e + h> 0 和c + f + i> 0。

公开(公告)号：US20130172192A1

公开(公告)日：2013-07-04

申请号：US13343184

申请日：2012-01-04

申请人： Anubhav Saxena ,  Alok Sarkar ,  M Srividhya

发明人： Anubhav Saxena ,  Alok Sarkar ,  M Srividhya

IPC分类号： C08G77/28

CPC分类号： C08G77/14 ,  C08G77/28 ,  C08G77/30 ,  C08G77/392 ,  C08G77/398 ,  C08L83/08

摘要： An ionically cross-linked silicone elastomeric composition including a polyorganosiloxane of the general formula MaMsbDcDsdTeTsfQ and optionally reinforcing or non-reinforcing fillers, and can include wound care agents, personal care ingredients, seed coating agents, agricultural agents, antimicrobial agents and/or antifouling agents.

摘要翻译： 包含通式为MaMsbDcDsdTeTsfQ的聚有机硅氧烷和任选的增强或非增强填料的离子交联的硅氧烷弹性体组合物，并且可以包括伤口护理剂，个人护理成分，种子包衣剂，农药，抗微生物剂和/或防污剂 。