Low TVOC release silicone composite sheet

    公开(公告)号:US12083783B2

    公开(公告)日:2024-09-10

    申请号:US16957999

    申请日:2018-12-26

    Abstract: The disclosure relates to a low TVOC release silicone composite sheet, comprising: 1) a substrate layer selected from a fabric or a polymeric film. 2) a silicone adhesive layer coated onto the substrate layer and containing volatile organic compound (VOC) releasing additives, and 3) a reinforcing layer adjacent to the silicone adhesive layer; wherein the coating amount of the silicone adhesive layer is less than 45 wt %, preferably less than 35 wt %, more preferably less than 20 wt %, based on the total coating amount of the silicone adhesive layer and the reinforcing layer. and wherein both silicone adhesive layer and reinforcing layer contain or consist essentially of liquid silicone rubber (LSR) or room temperature vulcanized silicone rubber (RTV), and said reinforcing layer contains one or more coatings comprising A). organopolysiloxane having one or more silicon atom-bonded alkenyl groups on average in one molecule; B). an organohydrogenpolysiloxane; and C). a hydrosilylation reaction catalyst present in any amount effective to cure the composition. Furthermore, it relates also to a method for coating and for reducing TVOC release.

    CURABLE COMPOSITION FOR SILICONE PRESSURE SENSITIVE ADHESIVES

    公开(公告)号:US20240270965A1

    公开(公告)日:2024-08-15

    申请号:US18555908

    申请日:2022-03-30

    Abstract: A curable composition contains: (A) a polydiorganosiloxane component including: (A1) greater than 3.1 wt % to 20 wt % of an aliphatically unsaturated polydiorganosiloxane polymer and (A3) a hydroxyl-terminated polydiorganosiloxane gum of unit formula (A-III); (B) a polyorganosilicate resin component including (B1) a capped resin, (B2) >18.53 wt % to 54.3 wt % of an uncapped resin; where the weight ratio of the uncapped resin (B2) to the capped resin (B1) is greater than 0.51 to 58.82; where component (A) and component (B) are present in amounts to provide a weight ratio of (B):(A) of 1.2:1 to less than 1.62:1; (C) a polyorganohydrogensiloxane that is present in an amount to provide a molar ratio of silicon bonded hydrogen atoms to alkenyl groups for the curable composition of 5 to 50; (D) a hydrosilylation reaction catalyst in an amount sufficient to provide 1 to 1000 ppm of platinum group metal; and (E) a condensation reaction catalyst; where the content of alkenyl groups in the curable composition is 0.017 wt % to 0.089 wt %; and where wt % values are relative to the total weight of components (A), (B), (C), (D) and (E) unless otherwise stated.

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