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1.发明授权Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion 有权在高苯转化率下通过苯烷基化制备苯酚含量降低的高辛烷值汽油的方法公开(公告)号：US08395006B2
公开(公告)日：2013-03-12
申请号：US12720345
申请日：2010-03-09
申请人： Michael C. Clark , Benjamin S. Umansky , Elizabeth A. Nye , Mark J. Reichensperger , William C. Lewis
发明人： Michael C. Clark , Benjamin S. Umansky , Elizabeth A. Nye , Mark J. Reichensperger , William C. Lewis
IPC分类号： C07C2/64
CPC分类号： C10G35/065 , B01J29/7038 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G2300/1092 , C10G2300/1096 , C10G2300/301 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , Y02P20/52 , C07C15/085
摘要： A process for the alkylation of a benzene-containing refinery stream such as reformate with light refinery olefins which is capable of achieving high benzene conversion levels operates in a fixed bed of an MWW zeolite catalyst, preferably MCM-22, in single pass mode in the liquid phase at a relatively low to moderate temperatures with pressure maintained at a value adequate to ensure subcritical operation. High levels of benzene conversion with conversions of at least 90% and higher, e.g. 92% or 95% or even higher are achievable. A high octane product is produced, comprising mono-, di- and tri-alkylbenzenes with lesser levels of the tetra-substituted products. By operating with staged olefin injection, the end point of the alkylation product can be maintained at a low value while, at the same time, achieving high levels of benzene and olefin conversion.
摘要翻译： 使用能够获得高苯转化水平的轻炼油烯烃的含苯精炼料流如重整油的烷基化方法在MWW沸石催化剂（优选MCM-22）的固定床中以单程模式在 液相在相对低至中等温度下，压力保持在足以确保亚临界操作的值。 高转化率的苯转化率至少为90％以上，例如。 可达到92％或95％甚至更高。 产生高辛烷值的产物，包括具有较低含量的四取代产物的单烷基苯，二烷基苯和三烷基苯。 通过使用分段烯烃注入操作，烷基化产物的终点可以保持在低值，同时实现高水平的苯和烯烃转化。
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2.发明申请PROCESS FOR MAKING HIGH OCTANE GASOLINE WITH REDUCED BENZENE CONTENT BY BENZENE ALKYLATION AT HIGH BENZENE CONVERSION 有权通过苯甲醛在高浓度苯甲醛转化中制备具有降低苯并噻吩含量的高辛烷值的方法公开(公告)号：US20100300930A1
公开(公告)日：2010-12-02
申请号：US12720345
申请日：2010-03-09
申请人： Michael C. CLARK , Benjamin S. UMANSKY , Elizabeth A. NYE , Mark J. REICHENSPERGER , William C. LEWIS
发明人： Michael C. CLARK , Benjamin S. UMANSKY , Elizabeth A. NYE , Mark J. REICHENSPERGER , William C. LEWIS
CPC分类号： C10G35/065 , B01J29/7038 , C07C2/66 , C07C2529/70 , C10G29/205 , C10G2300/1092 , C10G2300/1096 , C10G2300/301 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , Y02P20/52 , C07C15/085
摘要： A process for the alkylation of a benzene-containing refinery stream such as reformate with light refinery olefins which is capable of achieving high benzene conversion levels operates in a fixed bed of an MWW zeolite catalyst, preferably MCM-22, in single pass mode in the liquid phase at a relatively low to moderate temperatures with pressure maintained at a value adequate to ensure subcritical operation. High levels of benzene conversion with conversions of at least 90% and higher, e.g. 92% or 95% or even higher are achievable. A high octane product is produced, comprising mono-, di- and tri-alkylbenzenes with lesser levels of the tetra-substituted products. By operating with staged olefin injection, the end point of the alkylation product can be maintained at a low value while, at the same time, achieving high levels of benzene and olefin conversion.
摘要翻译： 使用能够获得高苯转化水平的轻炼油烯烃的含苯精炼料流如重整油的烷基化方法在MWW沸石催化剂（优选MCM-22）的固定床中以单程模式在 液相在相对低至中等温度下，压力保持在足以确保亚临界操作的值。 高转化率的苯转化率至少为90％以上，例如。 可达到92％或95％甚至更高。 产生高辛烷值的产物，包括具有较低含量的四取代产物的单烷基苯，二烷基苯和三烷基苯。 通过使用分段烯烃注入操作，烷基化产物的终点可以保持在低值，同时实现高水平的苯和烯烃转化。
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公开(公告)号：US20110118522A1
公开(公告)日：2011-05-19
申请号：US12899049
申请日：2010-10-06
IPC分类号： C07C15/073 , C07C2/12 , C07C7/10 , C07C15/067
CPC分类号： C10G53/04 , C07C7/10 , C10G2300/1092 , C10G2300/1096 , C10G2300/202 , C10G2300/805 , C10G2400/02 , C07C11/02
摘要： A light olefin feed for an olefin conversion process is subjected to a water wash to remove water-soluble contaminants after which the water is separated from the olefin prior to the conversion reaction. The water used for the wash is free of boiler feedwater additives, especially basic nitrogenous additives, which adversely affect catalytic function.
摘要翻译： 将用于烯烃转化方法的轻质烯烃进料进行水洗以除去水溶性污染物，之后在转化反应之前将水与烯烃分离。 用于洗涤的水不含锅炉给水添加剂，特别是碱性含氮添加剂，对催化功能产生不利影响。
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