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    Phosphine-based catalysts useful for the telomerization of butadiene
    2.
    发明授权
    Phosphine-based catalysts useful for the telomerization of butadiene 失效
    用于丁二烯调聚的膦基催化剂

    公开(公告)号：US08779164B2

    公开(公告)日：2014-07-15

    申请号：US13518040

    申请日：2010-02-17

    Applicant: Petrus Van Leeuwen ,  Mathieu Tschan ,  Zoraida Freixa ,  Henk Hagen

    Inventor： Petrus Van Leeuwen ,  Mathieu Tschan ,  Zoraida Freixa ,  Henk Hagen

    IPC: C07F19/00 ,  C07C1/22

    CPC classification number: C07F19/005 ,  B01J31/2452 ,  B01J31/249 ,  B01J2231/20 ,  B01J2531/824 ,  C07C1/20 ,  C07C1/22 ,  C07C41/06 ,  C07C41/20 ,  C07C11/02 ,  C07C43/15 ,  C07C43/04

    Abstract: A phosphine-based catalyst composition suitable for the telomerization of butadiene to produce 1-octene includes palladium and one of a class of novel phosphine ligands characterized by two potentially functionalized phenyl rings and cyclized 5- or 6-member alkoxy groups that, together, bridge the two potentially functionalized phenyl rings. In these groups the alkoxy moiety of each is located ortho to at least one functionalizing moiety, if any, on the phenyl rings. The catalysts including this class of phosphine ligands may exhibit higher catalytic activity and selectivity, and may be used at lower temperatures, than many other phosphine ligand catalysts, reducing costs. Palladium precipitation may also be reduced.

    Abstract translation: 适用于丁二烯调聚以生产1-辛烯的磷化氢基催化剂组合物包括钯和一类新型膦配体之一，其特征在于两个潜在官能化的苯环和环化的5-或6-烷氧基，其一起桥接 两个潜在的官能化苯环。 在这些基团中，每个烷氧基部分位于苯环上至少一个官能化部分（如果有的话）的邻位。 包括这类膦配体的催化剂可以表现出更高的催化活性和选择性，并且可以在比许多其它膦配体催化剂更低的温度下使用，降低成本。 钯沉淀也可能降低。

    NOVEL PHOSPHINE-BASED CATALYSTS USEFUL FOR THE TELOMERIZATION OF BUTADIENE
    4.
    发明申请
    NOVEL PHOSPHINE-BASED CATALYSTS USEFUL FOR THE TELOMERIZATION OF BUTADIENE 失效
    新型基于磷酸盐的催化剂有助于二苯乙烯的酯化

    公开(公告)号：US20130123516A1

    公开(公告)日：2013-05-16

    申请号：US13518040

    申请日：2010-02-17

    Applicant: Petrus Van Leeuwen ,  Mathieu Tschan ,  Zoraida Freixa ,  Henk Hagen

    Inventor： Petrus Van Leeuwen ,  Mathieu Tschan ,  Zoraida Freixa ,  Henk Hagen

    IPC: C07F19/00 ,  C07C1/22

    CPC classification number: C07F19/005 ,  B01J31/2452 ,  B01J31/249 ,  B01J2231/20 ,  B01J2531/824 ,  C07C1/20 ,  C07C1/22 ,  C07C41/06 ,  C07C41/20 ,  C07C11/02 ,  C07C43/15 ,  C07C43/04

    Abstract: A phosphine-based catalyst composition suitable for the telomerization of butadiene to produce 1-octene includes palladium and one of a class of novel phosphine ligands characterized by two potentially functionalized phenyl rings and a third phenyl group having an alkoxy functionality on one of the ortho-positions, which is part of a 5- or 6-membered ring between this ortho position and the adjacent meta position, this ring not being part of a second aryl group. The catalysts including this class of phosphine ligands may exhibit higher catalytic activity and selectivity, and may be used at lower temperatures, than many other phosphine ligand catalysts, reducing costs. Palladium precipitation may also be reduced.

    Abstract translation: 适用于丁二烯调聚以生产1-辛烯的膦基催化剂组合物包括钯和一类新型膦配体之一，其特征在于两个潜在官能化的苯环和在其中一个邻位上具有烷氧基官能团的第三苯基， 位置，其是该邻位和相邻间位之间的5-或6-元环的一部分，该环不是第二芳基的一部分。 包括这类膦配体的催化剂可以表现出更高的催化活性和选择性，并且可以在比许多其它膦配体催化剂更低的温度下使用，降低成本。 钯沉淀也可能降低。

    Method for determining susceptibility to heart disease by screening polymorphisms in the vitamin D receptor gene
    5.
    发明申请
    Method for determining susceptibility to heart disease by screening polymorphisms in the vitamin D receptor gene 审中-公开
    通过筛选维生素D受体基因多态性来确定心脏病易感性的方法

    公开(公告)号：US20050074786A1

    公开(公告)日：2005-04-07

    申请号：US10703715

    申请日：2003-11-07

    Applicant: Andreas Uitterlinden ,  Johannes Petrus Van Leeuwen ,  Huibert Pieter Pols

    Inventor： Andreas Uitterlinden ,  Johannes Petrus Van Leeuwen ,  Huibert Pieter Pols

    IPC: G01N33/50 ,  C12N15/09 ,  C12Q1/68 ,  C12Q1/6883

    CPC classification number: C12Q1/6883 ,  C12Q2600/156 ,  C12Q2600/172

    Abstract: The present invention relates to prognostic method and means for determining susceptibility to heart disease in a subject by screening for polymorphisms in the Vitamin D receptor gene. In particular, the present invention provides a method for determining susceptibility to heart disease, the method comprising analysing the genetic material of a subject to determine which of the B/b, A/a or T/t alleles of the restriction enzyme sites BsmI, ApaI and TaqI respectively are present. Specific combinations of alleles represent a haplotype which is associated with susceptibility to heart disease.

    Abstract translation: 本发明涉及通过筛选维生素D受体基因的多态性来确定受试者对心脏病易感性的预后方法和手段。 特别地，本发明提供了一种确定心脏病易感性的方法，所述方法包括分析受试者的遗传物质以确定限制酶位点BsmI的B / b，A / a或T / t等位基因中的哪一个， ApaI和TaqI分别存在。 等位基因的特定组合表示与心脏病易感性相关的单倍型。

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