ORGANO SULFUR-BASED ELECTRODE ACTIVE MATERIAL

    公开(公告)号:US20200350587A1

    公开(公告)日:2020-11-05

    申请号:US16960782

    申请日:2019-02-25

    Abstract: Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.

    PRODUCTION METHOD OF SULFUR-MODIFIED POLYACRYLONITRILE

    公开(公告)号:US20220340693A1

    公开(公告)日:2022-10-27

    申请号:US17763839

    申请日:2020-09-14

    Abstract: The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).

    METHOD FOR PRODUCING ORGANO-SULFUR ELECTRODE ACTIVE MATERIAL

    公开(公告)号:US20200243860A1

    公开(公告)日:2020-07-30

    申请号:US16756580

    申请日:2018-10-30

    Abstract: Disclosed is a sulfur-based electrode active material with which a nonaqueous electrolyte secondary battery that has a large capacity and exhibits less deterioration of the cycle characteristics can be obtained even when an electrode is employed in which the sulfur-based electrode active material is used as an electrode active material and an aluminum foil is used as a current collector. Also disclosed is a method for producing an organosulfur electrode active material, including a step of obtaining an organosulfur compound by heat-treating an organic compound and sulfur and a step of treating the organosulfur compound with a basic compound. The organosulfur compound is preferably sulfur-modified polyacrylonitrile, and the basic compound is preferably ammonia. The organosulfur compound may be treated with the basic compound after the organosulfur compound is ground, or may be ground in a medium that contains the basic compound.

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