Abstract:
An aqueous dispersion of polyurethane resin obtained by a chain elongation reaction in water, by adding (C) at least one chain extender selected from water-soluble polyamines, hydrazine and derivatives thereof to a dispersion liquid obtained by emulsifying and dispersing a mixture in water. The mixture comprises “(B) at least one compound selected from the phosphorous compounds represented by formula (1), and (A) an urethane prepolymer and/or a neutralized urethane prepolymer material which has an isocyanate group at the terminal, wherein an urethane prepolymer of said component (A) is an urethane prepolymer obtained by (a1) an organic polyisocyanate and (a2) a polymeric polyol, and said neutralized urethane prepolymer material is a neutralized material obtained by neutralizing an urethane prepolymer which is obtained by further using (a3) a compound having an anionic hydrophilic group and at least two active hydrogens in a molecule together with said components (a1) and (a2);
Abstract:
An aqueous dispersion of polyurethane resin is obtained by a chain elongation reaction in water wherein (C) at least one chain extender selected from a group consisting of water-soluble polyamines, hydrazine and derivatives thereof is added to a dispersion liquid obtained by emulsifying and dispersing a mixture in water. The mixture comprises: (B) at least one compound selected from the phosphorous compounds represented by the following formula (1) and (A) an urethane prepolymer and/or a neutralized urethane prepolymer material which has an isocyanate group at the terminal. The urethane prepolymer of component (A) is an urethane prepolymer obtained from (a1) an organic polyisocyanate and (a2) a polymeric polyol. The neutralized urethane prepolymer material of component (A) is a neutralized material obtained by neutralizing an urethane prepolymer which is obtained by further using (a3) a compound having an anionic hydrophilic group and at least two active hydrogens in a molecule together with the components (a1) and (a2).
Abstract:
Provided are: a photostabilizer masterbatch in which the problems of the occurrence of blocking over time due to the effect of temperature fluctuations in the environment and the difficulty in handling due to the resulting solidification in aggregates are overcome; and a method of producing the same.The photostabilizer masterbatch is obtained by adding and mixing 80 to 300 parts by mass of (B) a hindered amine compound represented by the following Formula (1) with respect to 100 parts by mass of (A) a silica produced by a wet process and subsequently further adding and mixing 5 to 50 parts by mass of (C) a silica produced by a dry process: (wherein, R1 represents a hydrogen atom, a hydroxy group, an alkyl, hydroxyalkyl, alkoxy or hydroxyalkoxy group having 1 to 30 carbon atoms, or an oxy radical; and R2 represents an alkyl group having 1 to 30 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, or a group represented by the following Formula (2)) (wherein, R3 represents the same as R1 in the Formula (1)).