Abstract:
An aqueous dispersion of polyurethane resin is obtained by a chain elongation reaction in water wherein (C) at least one chain extender selected from a group consisting of water-soluble polyamines, hydrazine and derivatives thereof is added to a dispersion liquid obtained by emulsifying and dispersing a mixture in water. The mixture comprises: (B) at least one compound selected from the phosphorous compounds represented by the following formula (1) and (A) an urethane prepolymer and/or a neutralized urethane prepolymer material which has an isocyanate group at the terminal. The urethane prepolymer of component (A) is an urethane prepolymer obtained from (a1) an organic polyisocyanate and (a2) a polymeric polyol. The neutralized urethane prepolymer material of component (A) is a neutralized material obtained by neutralizing an urethane prepolymer which is obtained by further using (a3) a compound having an anionic hydrophilic group and at least two active hydrogens in a molecule together with the components (a1) and (a2).
Abstract:
An aqueous dispersion of polyurethane resin obtained by a chain elongation reaction in water, by adding (C) at least one chain extender selected from water-soluble polyamines, hydrazine and derivatives thereof to a dispersion liquid obtained by emulsifying and dispersing a mixture in water. The mixture comprises “(B) at least one compound selected from the phosphorous compounds represented by formula (1), and (A) an urethane prepolymer and/or a neutralized urethane prepolymer material which has an isocyanate group at the terminal, wherein an urethane prepolymer of said component (A) is an urethane prepolymer obtained by (a1) an organic polyisocyanate and (a2) a polymeric polyol, and said neutralized urethane prepolymer material is a neutralized material obtained by neutralizing an urethane prepolymer which is obtained by further using (a3) a compound having an anionic hydrophilic group and at least two active hydrogens in a molecule together with said components (a1) and (a2);