公开(公告)号：US20140148614A1

公开(公告)日：2014-05-29

申请号：US14088874

申请日：2013-11-25

Applicant: BASF SE

Inventor： Daniel Schneider ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Jürgen Paschold ,  Joaquim Henrique Teles ,  Stefan Rittinger

IPC: C07C67/36

CPC classification number: C07C67/36 ,  C07C69/06

Abstract: Process for preparing methyl formate by carbonylation of methanol by means of carbon monoxide in a carbonylation reactor in the presence of a catalyst system comprising alkali metal formate and alkali metal alkoxide to give a reaction mixture (RM) which comprises methyl formate, alkali metal formate, alkali metal alkoxide and possibly unreacted methanol and unreacted carbon monoxide and is taken from the carbonylation reactor, wherein the reaction mixture (RM) comprises at least 0.5% by weight of alkali metal alkoxide based on the total weight of the reaction mixture (RM) and the molar ratio of alkali metal formate to alkali metal alkoxide in the reaction mixture (RM) is greater than 1.

Abstract translation: 在含有碱金属甲酸盐和碱金属醇盐的催化剂体系的存在下，在羰基化反应器中，通过一氧化碳羰基化甲醇制备甲酸甲酯的方法，得到包含甲酸甲酯，碱金属甲酸盐的反应混合物（RM） 碱金属醇盐和可能未反应的甲醇和未反应的一氧化碳，并从羰基化反应器中取出，其中反应混合物（RM）包含至少0.5重量％的碱金属醇盐，基于反应混合物（RM）的总重量和 反应混合物（RM）中碱金属甲酸盐与碱金属醇盐的摩尔比大于1。

公开(公告)号：US20140018456A1

公开(公告)日：2014-01-16

申请号：US13721392

申请日：2012-12-20

Applicant: BASF SE

Inventor： Peter Bassler ,  Stefan Rittinger ,  Daniel Schneider ,  Donata Maria Fries ,  Klaus-Dieter Mohl ,  Joaquim Henrique Teles ,  Martin Schäfer ,  Jürgen Paschold

IPC: C07C51/44

CPC classification number: C07C51/44 ,  C07C53/02

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.

Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸和叔胺（I）的液体流通过将叔胺（I）和甲酸源 ，其中包含的次要组分被分离出来，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中蒸馏装置的底部输出分离成两个液相，上部液相再循环到甲酸 酸源和下液相再循环至次级组分和/或蒸馏装置的分离，其中通过蒸馏从上液相除去低锅炉并再循环至贫化物流。

公开(公告)号：US08957244B2

公开(公告)日：2015-02-17

申请号：US14088874

申请日：2013-11-25

Applicant: BASF SE

Inventor： Daniel Schneider ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Jürgen Paschold ,  Joaquim Henrique Teles ,  Stefan Rittinger

IPC: C07C67/36

CPC classification number: C07C67/36 ,  C07C69/06

Abstract: Process for preparing methyl formate by carbonylation of methanol by means of carbon monoxide in a carbonylation reactor in the presence of a catalyst system comprising alkali metal formate and alkali metal alkoxide to give a reaction mixture (RM) which comprises methyl formate, alkali metal formate, alkali metal alkoxide and possibly unreacted methanol and unreacted carbon monoxide and is taken from the carbonylation reactor, wherein the reaction mixture (RM) comprises at least 0.5% by weight of alkali metal alkoxide based on the total weight of the reaction mixture (RM) and the molar ratio of alkali metal formate to alkali metal alkoxide in the reaction mixture (RM) is greater than 1.

Abstract translation: 在含有碱金属甲酸盐和碱金属醇盐的催化剂体系的存在下，在羰基化反应器中，通过一氧化碳羰基化甲醇制备甲酸甲酯的方法，得到包含甲酸甲酯，碱金属甲酸盐的反应混合物（RM） 碱金属醇盐和可能未反应的甲醇和未反应的一氧化碳，并从羰基化反应器中取出，其中反应混合物（RM）包含至少0.5重量％的碱金属醇盐，基于反应混合物（RM）的总重量和 反应混合物（RM）中碱金属甲酸盐与碱金属醇盐的摩尔比大于1。

公开(公告)号：US08889905B2

公开(公告)日：2014-11-18

申请号：US13721392

申请日：2012-12-20

Applicant: BASF SE

Inventor： Peter Bassler ,  Stefan Rittinger ,  Daniel Schneider ,  Donata Maria Fries ,  Klaus-Dieter Mohl ,  Joaquim Henrique Teles ,  Martin Schäfer ,  Jürgen Paschold

IPC: C07C53/00 ,  C07C51/44

CPC classification number: C07C51/44 ,  C07C53/02

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.

Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸和叔胺（I）的液体流通过将叔胺（I）和甲酸源 ，其中包含的次要组分被分离出来，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中蒸馏装置的底部输出分离成两个液相，上部液相再循环到甲酸 酸源和下液相再循环至次级组分和/或蒸馏装置的分离，其中通过蒸馏从上液相除去低锅炉并再循环至贫化物流。