公开(公告)号：US08835683B2

公开(公告)日：2014-09-16

申请号：US13721296

申请日：2012-12-20

Applicant: BASF SE

Inventor： Daniel Schneider ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Donata Maria Fries ,  Joaquim Henrique Teles ,  Peter Bassler ,  Stefan Rittinger ,  Thomas Schaub

IPC: C07C51/44 ,  C07C51/02

CPC classification number: C07C51/44 ,  C07C51/02 ,  C07C53/06 ,  C07C53/02

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid, tertiary amine (I) and water is produced by combining tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed and formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, wherein the stream comprising water and organic decomposition products of the tertiary amine (I) which have been separated off is separated into two liquid phases, the upper liquid phase is removed and the lower, water-comprising liquid phase is recirculated to the formic acid source.

Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸，叔胺（I）和水的液体流通过将叔胺（I）和甲酸 在水，水和叔胺（I）的有机分解产物存在下，酸源，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中包含水和有机分解产物的流 已经分离出的叔胺（I）分离成两个液相，去除上部液相，将含较低水的液相再循环至甲酸源。

公开(公告)号：US10450252B2

公开(公告)日：2019-10-22

申请号：US16089495

申请日：2017-03-29

Applicant: BASF SE

Inventor： Rolf Pinkos ,  Stefan Rittinger ,  Christoph Nuebling ,  Olivier Abillard

IPC: C07C29/149 ,  C07C29/17

Abstract: Process for the continuous hydrogenation of a carboxylic acid (I) to an alcohol (II) by means of hydrogen at a temperature of from 100 to 300° C. and a pressure of 10 to 33 MPa abs in a reactor tube through which axial flow occurs and which has a fixed-bed catalyst which is fixed therein and comprises at least one element from the group consisting of Re, Co and Cu, and in which the carboxylic acid (I) to be hydrogenated is present in a liquid mixture (III) comprising the carboxylic acid (I), water and alcohol (II), where the mixture (III) has an acid number of from 0.2 to 25 mg KOH/g and comprises at least 15% by weight of water and at least 20% by weight of alcohol (II) and the flow velocity of the flowing liquid calculated on the basis of the geometric cross-sectional area of the empty, catalyst-free reactor tube is from 10 to 50 m/h.

公开(公告)号：US09556136B2

公开(公告)日：2017-01-31

申请号：US14662890

申请日：2015-03-19

Applicant: BASF SE

Inventor： Stefan Rittinger ,  Regina Vogelsang ,  Pierre Fournier ,  Anirudh Acharya ,  Sonja Judat

IPC: C07D295/023 ,  C08F26/10 ,  C08F226/10

CPC classification number: C07D295/023 ,  C08F26/10 ,  C08F226/10

Abstract: A process for the distillation of a mixture which consists to at least 90% by weight of a cyclic N-vinylamide and which comprises a stabilizer, wherein a polyether is added to the mixture before or during distillation and a product is obtained which consists to at least 99.5% by weight of the cyclic N-vinylamide.

Abstract translation: 蒸馏混合物的方法，该混合物由至少90重量％的环状N-乙烯基酰胺组成，并且包含稳定剂，其中在蒸馏之前或期间将聚醚加入到混合物中，并获得产物，其组成为 至少99.5重量％的环状N-乙烯基酰胺。

公开(公告)号：US09428438B2

公开(公告)日：2016-08-30

申请号：US14088805

申请日：2013-11-25

Applicant: BASF SE

Inventor： Donata Maria Fries ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Daniel Schneider ,  Peter Bassler ,  Stefan Rittinger ,  Joaquim Henrique Teles

IPC: C07C53/02 ,  C07C51/44 ,  C07C51/02

CPC classification number: C07C51/44 ,  C07C51/02 ,  C07C53/02

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which, in step (a), a liquid stream comprising formic acid, methanol, water and tertiary amine (I) is produced by combining methyl formate, water and tertiary amine (I), from there in step (b), methanol is separated off and in step (c), formic acid is removed by distillation from the liquid stream obtained in a distillation apparatus, wherein, when methyl formate, water and tertiary amine (I) are combined, methyl formate, water and optionally tertiary amine (I) are first introduced in step (a1) in a molar ratio of 0≦n(amine to a1)/n(mefo to a1)≦0.1, and from 70 to 100% of the hydrolysis equilibrium possible is set and then, in step (a2), tertiary amine (I) is introduced in a molar ratio of 0.1≦n(amine to a2)/n(mefo to a1)≦2, and the mixture is reacted.

Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中在步骤（a）中，包含甲酸，甲醇，水和叔胺（I）的液体流由 在步骤（b）中从甲酸甲酯，水和叔胺（I）组合，分离出甲醇，在步骤（c）中，通过蒸馏从蒸馏设备中得到的液体物流除去甲酸，其中，当 甲酸甲酯，水和叔胺（I）的组合，首先在步骤（a1）中以0≤n（胺与a1）/ n（mefo与n = 1）的摩尔比引入甲酸甲酯，水和任选的叔胺（I） a1）≤0.1，可以设定70〜100％的水解平衡，然后在步骤（a2）中，导入叔胺（I），摩尔比为0.1≤n（胺与a2）/ n（ mefo至a1）≤2，并使混合物反应。

公开(公告)号：US20140148614A1

公开(公告)日：2014-05-29

申请号：US14088874

申请日：2013-11-25

Applicant: BASF SE

Inventor： Daniel Schneider ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Jürgen Paschold ,  Joaquim Henrique Teles ,  Stefan Rittinger

IPC: C07C67/36

CPC classification number: C07C67/36 ,  C07C69/06

Abstract: Process for preparing methyl formate by carbonylation of methanol by means of carbon monoxide in a carbonylation reactor in the presence of a catalyst system comprising alkali metal formate and alkali metal alkoxide to give a reaction mixture (RM) which comprises methyl formate, alkali metal formate, alkali metal alkoxide and possibly unreacted methanol and unreacted carbon monoxide and is taken from the carbonylation reactor, wherein the reaction mixture (RM) comprises at least 0.5% by weight of alkali metal alkoxide based on the total weight of the reaction mixture (RM) and the molar ratio of alkali metal formate to alkali metal alkoxide in the reaction mixture (RM) is greater than 1.

Abstract translation: 在含有碱金属甲酸盐和碱金属醇盐的催化剂体系的存在下，在羰基化反应器中，通过一氧化碳羰基化甲醇制备甲酸甲酯的方法，得到包含甲酸甲酯，碱金属甲酸盐的反应混合物（RM） 碱金属醇盐和可能未反应的甲醇和未反应的一氧化碳，并从羰基化反应器中取出，其中反应混合物（RM）包含至少0.5重量％的碱金属醇盐，基于反应混合物（RM）的总重量和 反应混合物（RM）中碱金属甲酸盐与碱金属醇盐的摩尔比大于1。

公开(公告)号：US20140018456A1

公开(公告)日：2014-01-16

申请号：US13721392

申请日：2012-12-20

Applicant: BASF SE

Inventor： Peter Bassler ,  Stefan Rittinger ,  Daniel Schneider ,  Donata Maria Fries ,  Klaus-Dieter Mohl ,  Joaquim Henrique Teles ,  Martin Schäfer ,  Jürgen Paschold

IPC: C07C51/44

CPC classification number: C07C51/44 ,  C07C53/02

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.

Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸和叔胺（I）的液体流通过将叔胺（I）和甲酸源 ，其中包含的次要组分被分离出来，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中蒸馏装置的底部输出分离成两个液相，上部液相再循环到甲酸 酸源和下液相再循环至次级组分和/或蒸馏装置的分离，其中通过蒸馏从上液相除去低锅炉并再循环至贫化物流。

公开(公告)号：US08957244B2

公开(公告)日：2015-02-17

申请号：US14088874

申请日：2013-11-25

Applicant: BASF SE

Inventor： Daniel Schneider ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Jürgen Paschold ,  Joaquim Henrique Teles ,  Stefan Rittinger

IPC: C07C67/36

CPC classification number: C07C67/36 ,  C07C69/06

Abstract: Process for preparing methyl formate by carbonylation of methanol by means of carbon monoxide in a carbonylation reactor in the presence of a catalyst system comprising alkali metal formate and alkali metal alkoxide to give a reaction mixture (RM) which comprises methyl formate, alkali metal formate, alkali metal alkoxide and possibly unreacted methanol and unreacted carbon monoxide and is taken from the carbonylation reactor, wherein the reaction mixture (RM) comprises at least 0.5% by weight of alkali metal alkoxide based on the total weight of the reaction mixture (RM) and the molar ratio of alkali metal formate to alkali metal alkoxide in the reaction mixture (RM) is greater than 1.

Abstract translation: 在含有碱金属甲酸盐和碱金属醇盐的催化剂体系的存在下，在羰基化反应器中，通过一氧化碳羰基化甲醇制备甲酸甲酯的方法，得到包含甲酸甲酯，碱金属甲酸盐的反应混合物（RM） 碱金属醇盐和可能未反应的甲醇和未反应的一氧化碳，并从羰基化反应器中取出，其中反应混合物（RM）包含至少0.5重量％的碱金属醇盐，基于反应混合物（RM）的总重量和 反应混合物（RM）中碱金属甲酸盐与碱金属醇盐的摩尔比大于1。

公开(公告)号：US08889905B2

公开(公告)日：2014-11-18

申请号：US13721392

申请日：2012-12-20

Applicant: BASF SE

Inventor： Peter Bassler ,  Stefan Rittinger ,  Daniel Schneider ,  Donata Maria Fries ,  Klaus-Dieter Mohl ,  Joaquim Henrique Teles ,  Martin Schäfer ,  Jürgen Paschold

IPC: C07C53/00 ,  C07C51/44

CPC classification number: C07C51/44 ,  C07C53/02

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.

Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸和叔胺（I）的液体流通过将叔胺（I）和甲酸源 ，其中包含的次要组分被分离出来，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中蒸馏装置的底部输出分离成两个液相，上部液相再循环到甲酸 酸源和下液相再循环至次级组分和/或蒸馏装置的分离，其中通过蒸馏从上液相除去低锅炉并再循环至贫化物流。

公开(公告)号：US20140148617A1

公开(公告)日：2014-05-29

申请号：US14088805

申请日：2013-11-25

Applicant: BASF SE

Inventor： Donata Maria Fries ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Daniel Schneider ,  Peter Bassler ,  Stefan Rittinger ,  Joaquim Henrique Teles

IPC: C07C51/44

CPC classification number: C07C51/44 ,  C07C51/02 ,  C07C53/02

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which, in step (a), a liquid stream comprising formic acid, methanol, water and tertiary amine (I) is produced by combining methyl formate, water and tertiary amine (I), from there in step (b), methanol is separated off and in step (c), formic acid is removed by distillation from the liquid stream obtained in a distillation apparatus, wherein, when methyl formate, water and tertiary amine (I) are combined, methyl formate, water and optionally tertiary amine (I) are first introduced in step (a1) in a molar ratio of 0≦n(amine to a1)/n(mefo to a1)≦0.1, and from 70 to 100% of the hydrolysis equilibrium possible is set and then, in step (a2), tertiary amine (I) is introduced in a molar ratio of 0.1≦n(amine to a2)/n(mefo to a1)≦2, and the mixture is reacted.

Abstract translation: 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中在步骤（a）中，包含甲酸，甲醇，水和叔胺（I）的液体流由 在步骤（b）中从甲酸甲酯，水和叔胺（I）组合，分离出甲醇，在步骤（c）中，通过蒸馏从蒸馏设备中得到的液体物流除去甲酸，其中，当 甲酸甲酯，水和叔胺（I）组合，首先在步骤（a1）中以甲酸甲酯，水和任选的叔胺（I）以0和nlE; n（胺至a1）/ n（mefo至 a1）＆nlE; 0.1和70〜100％的水解平衡是可能的，然后在步骤（a2）中，以0.1和nlE的摩尔比引入叔胺（I）; n（胺与a2）/ n（mefo to a1）＆nlE; 2，使混合物反应。