公开(公告)号：US20140183029A1

公开(公告)日：2014-07-03

申请号：US14140908

申请日：2013-12-26

Applicant: BASF SE

Inventor： Jörg Erbes ,  Christoph Sigwart ,  Tobias Kortekamp ,  Cornelis Hendricus De Ruiter ,  Jutta Vonend ,  Annette Kreiner ,  Markus Ottenbacher

IPC: B01D3/34 ,  B01D3/10

CPC classification number: B01D3/34 ,  B01D3/10 ,  B01D3/143 ,  C08G75/20 ,  C08G75/23 ,  C08L81/06

Abstract: A process for treating a recycling stream from a plant for the production of polyarylene ether sulfones comprising 60 to 90% water, 10 to 40% N-alkyl-2-pyrrolidone, up to 5000 ppm by weight of the alkylsuccinimide corresponding to the N-alkyl-2-pyrrolidone, up to 1000 ppm by weight of other substances with higher boiling point than N-alkyl-2-pyrrolidone, giving N-alkyl-2-pyrrolidone which can be recycled via a distillation column , preceded by preliminary purification in evaporator stage(s), giving vapor stream(s) which are introduced as feed streams into the distillation column, the bottom stream from the last evaporator stage being discharged and the bottom stream from the distillation column being recycled into the last evaporator stage, and the vapor stream from the last evaporator stage being introduced fully or partly into an additional column from which a top stream is introduced into the distillation column and a bottom stream is discharged.

Abstract translation: 用于处理来自植物的用于生产聚亚芳基醚砜的再循环流的方法，其包含60至90％的水，10至40％的N-烷基-2-吡咯烷酮，至多5000重量ppm的对应于N-烷基-2-吡咯烷酮的烷基琥珀酰亚胺， 烷基-2-吡咯烷酮，高达1000ppm重量的沸点高于N-烷基-2-吡咯烷酮的其它物质，得到可通过蒸馏塔再循环的N-烷基-2-吡咯烷酮，然后进行初步纯化 蒸发阶段，给出作为进料流引入蒸馏塔的蒸气流，排出最后一个蒸发器阶段的底部物流，并将来自蒸馏塔的塔底物流循环回最后一个蒸发器阶段;以及 来自最后一个蒸发器阶段的蒸汽流被完全或部分地引入另外的塔中，顶部流从该塔引入蒸馏塔并排出底部流。

公开(公告)号：US20140187737A1

公开(公告)日：2014-07-03

申请号：US14141115

申请日：2013-12-26

Applicant: BASF SE

Inventor： Jörg Erbes ,  Cornelis Hendricus De Ruiter ,  Christoph Sigwart ,  Gerhard Lange ,  Jutta Vonend

IPC: C08G75/23

CPC classification number: C08G75/23

Abstract: A process is proposed for the treatment of a recycling stream (1) from a plant for the production of polyarylene ether sulfones via polycondensation of aromatic bishalogen compounds and of aromatic bisphenols or their salts in the presence of at least one alkali metal carbonate or ammonium carbonate or alkali metal hydrogencarbonate or ammonium hydrogencarbonate in an N-alkyl-2-pyrrolidone as solvent, comprising from 60 to 90% by weight of water, from 10 to 40% by weight of the N-alkyl-2-pyrrolidone and, as contaminant detrimental to specification, up to 5000 ppm by weight of the alkylsuccinimide corresponding to the N-alkyl-2-pyrrolidone and, alongside this, up to 1000 ppm by weight of other substances with higher boiling point than N-alkyl-2-pyrrolidone, in particular inorganic salts, based in each case on the total weight of the recycling stream (1), where the entirety of the components gives 100% by weight, giving a pure N-alkyl-2-pyrrolidone stream (2) which can be returned to the plant for the production of polyarylene ether sulfones, via a final distillation process in a final column (K), which comprises preceding the final distillation by a preliminary purification by evaporation in one or more evaporator stages for reducing the level of inorganic salts, where one or more vapor streams (3, 4, 5) are obtained which are introduced as feed streams into the final column (K), and where the bottom stream from the last evaporator stage is removed and the bottom stream from the final column (K) is recycled in full into the last evaporator stage.

Abstract translation: 提出了一种方法，用于在至少一种碱金属碳酸盐或碳酸铵存在下，通过芳族双酚类化合物和芳族双酚或其盐的缩聚来处理来自植物的生产聚亚芳基醚砜的再循环料流（1） 或N-烷基-2-吡咯烷酮作为溶剂的碱金属碳酸氢盐或碳酸氢铵，包含60-90％重量的水，10-40％（重量）的N-烷基-2-吡咯烷酮和作为污染物 对于说明书来说，高达5000ppm重量的对应于N-烷基-2-吡咯烷酮的烷基琥珀酰亚胺，并且除此之外，高达1000ppm重量的沸点高于N-烷基-2-吡咯烷酮的其它物质， 特别是无机盐，基于每种情况下的回收料流（1）的总重量，其中全部组分给出100重量％，得到纯的N-烷基-2-吡咯烷酮流（2），其可以是 回到了 通过在最终塔（K）中的最终蒸馏方法生产聚亚芳基醚砜的装置，其包括在最终蒸馏之前通过在一个或多个蒸发器阶段中蒸发进行初步纯化以降低无机盐的水平，其中一个 或更多的蒸汽流（3,4,5），其作为进料流被引入到最终塔（K）中，并且其中来自最后蒸发器级的底部流被移除并且来自最终塔（K）的底部流 被充分回收到最后一个蒸发器阶段。

公开(公告)号：US20140183032A1

公开(公告)日：2014-07-03

申请号：US14140947

申请日：2013-12-26

Applicant: BASF SE

Inventor： Christoph Sigwart ,  Cornelis Hendricus De Ruiter ,  Jutta Vonend ,  Jörg Erbes

IPC: B01D3/14

CPC classification number: B01D3/141 ,  B01D3/143 ,  C08G65/46 ,  C08G65/48

Abstract: A process is proposed for the treatment of a recycling stream (1) from a plant for the production of polyarylene ether sulfones via polycondensation of aromatic bishalogen compounds and of aromatic bisphenols or their salts in the presence of at least one alkali metal carbonate or ammonium carbonate or alkali metal hydrogencarbonate or ammonium hydrogencarbonate in an N-alkyl-2-pyrrolidone as solvent, comprising from 60 to 90% by weight of water, from 10 to 40% by weight of N-alkyl-2-pyrrolidone and, as contaminant detrimental to specification, up to 5000 ppm by weight of the alkylsuccinimide corresponding to the N-alkyl-2-pyrrolidone and, alongside this, up to 1000 ppm by weight of other substances with higher boiling point than N-alkyl-2-pyrrolidone, in particular inorganic salts, based in each case on the total weight of the recycling stream (1), where the entirety of the components gives 100% by weight, giving a pure N-alkyl-2-pyrrolidone stream (2) which can be returned to the plant for the production of polyarylene ether sulfones, via a final distillation, which comprises carrying out the final distillation process in a partitioned column (TK), with a partition (T) arranged in the longitudinal direction of the column and dividing the space within the partitioned column (TK) into an input region (A), an output region (B), an upper undivided region (C) of the column, and a lower undivided region (D) of the column, the recycling stream (1) being introduced into the column in the input section (A) of the same, and being separated, in the partitioned column (TK), into a bottom stream (7) comprising N-methylsuccinimide, an overhead stream (8) comprising water, and a pure NMP stream, as side stream (2) from the output section (B).

Abstract translation: 提出了一种方法，用于在至少一种碱金属碳酸盐或碳酸铵存在下，通过芳族双酚类化合物和芳族双酚或其盐的缩聚来处理来自植物的生产聚亚芳基醚砜的再循环料流（1） 或N-烷基-2-吡咯烷酮作为溶剂的碱金属碳酸氢盐或碳酸氢铵，包含60至90重量％的水，10至40重量％的N-烷基-2-吡咯烷酮和作为污染物的有害物质 相对于N-烷基-2-吡咯烷酮至多5000重量ppm的烷基琥珀酰亚胺，并且除此之外，高达1000重量ppm的沸点高于N-烷基-2-吡咯烷酮的其它物质，在 特定的无机盐，基于每种情况下的循环流（1）的总重量，其中全部组分给出100重量％，得到纯N-烷基-2-吡咯烷酮流（2），其可以返回 到pla nt用于生产聚亚芳基醚砜，通过最终蒸馏，其包括在分隔塔（TK）中进行最终蒸馏过程，其中分隔壁（T）沿塔的纵向方向排列，并将空间分成 分隔柱（TK）分为输入区域（A），输出区域（B），塔的上部未分割区域（C）和塔的下部不分割区域（D），再循环流 引入其输入部分（A）中的列并在分隔柱（TK）中分离成包含N-甲基琥珀酰亚胺的底部流（7），包含水的塔顶物流（8）和 纯NMP流，作为来自输出部分（B）的侧流（2）。

公开(公告)号：US20140183030A1

公开(公告)日：2014-07-03

申请号：US14140861

申请日：2013-12-26

Applicant: BASF SE

Inventor： Christoph Sigwart ,  Jörg Erbes ,  Martin Weber ,  Gerhard Lange ,  Jutta Vonend ,  Cornelis Hendricus De Ruiter

IPC: C07D207/06

CPC classification number: C07D207/06 ,  C07D207/267

Abstract: N-alkylpyrrolidone and, as contaminant alongside this, the corresponding N-alkyl-succinimide, to give a pure solvent stream which meets the requirements for use in a process for the production of polymers, where compounds of higher and lower boiling point than the N-alkylpyrrolidone are removed by distillation, which comprises, prior to, during, or after the distillative purification process, adding a hydroxide of an alkali metal or of an alkaline earth metal in a molar amount corresponding to a molar ratio of at least 0.1:1 for this hydroxide with respect to the respective N-alkylsuccinimide in the appropriate solvent stream present prior to, during, or after the distillative purification process.

Abstract translation: N-烷基吡咯烷酮，并且作为污染物，与此相应的N-烷基 - 琥珀酰亚胺，得到纯溶剂流，其满足用于生产聚合物的方法的要求，其中高于和低于沸点的化合物比N - 烷基吡咯烷酮通过蒸馏除去，其包括在蒸馏纯化过程之前，期间或之后，加入碱金属或碱土金属的氢氧化物，摩尔量对应于至少0.1:1的摩尔比 在相对于在蒸馏纯化过程之前，期间或之后存在的适当溶剂流中相对于N-烷基琥珀酰亚胺的氢氧化物。

公开(公告)号：US20140187796A1

公开(公告)日：2014-07-03

申请号：US14140642

申请日：2013-12-26

Applicant: BASF SE

Inventor： Christoph Sigwart ,  Jutta Vonend ,  Cornelis Hendricus De Ruiter ,  Jörg Erbes

IPC: C07D207/267

CPC classification number: C07D207/267

Abstract: A process is proposed for the treatment of a recycling stream (1) from a plant for the production of polyarylene ether sulfones via polycondensation of aromatic bishalogen compounds and of aromatic bisphenols or their salts in the presence of at least one alkali metal carbonate or ammonium carbonate or alkali metal hydrogencarbonate or ammonium hydrogencarbonate in an N-alkyl-2-pyrrolidone as solvent, comprising from 60 to 90% by weight of water, from 10 to 40% by weight of N-alkyl-2-pyrrolidone and, as contaminant detrimental to specification, up to 5000 ppm by weight of the alkylsuccinimide corresponding to the N-alkyl-2-pyrrolidone and, alongside this, up to 1000 ppm by weight of other substances with higher boiling point than N-alkyl-2-pyrrolidone, in particular inorganic salts, based in each case on the total weight of the recycling stream (1), where the entirety of the components gives 100% by weight, giving a pure N-alkyl-2-pyrrolidone stream (2) which can be returned to the plant for the production of polyarylene ether sulfones, via a final distillation in a final column (K), which comprises preceding the final distillation by a preliminary purification by evaporation in one or more evaporator stages for reducing the level of inorganic salts, where one or more vapor streams (3, 4, 5) are obtained, which are introduced as feed streams into the final column (K), and where the bottom stream from the last evaporator stage is removed, and where a substream (9) comprising 1.0% by weight to 10% by weight of the bottom stream (7) from the final column (K) is removed, and the rest of the bottom stream from the final column (K) is recycled into the last evaporator stage.

Abstract translation: 提出了一种方法，用于在至少一种碱金属碳酸盐或碳酸铵存在下，通过芳族双酚类化合物和芳族双酚或其盐的缩聚来处理来自植物的生产聚亚芳基醚砜的再循环料流（1） 或N-烷基-2-吡咯烷酮作为溶剂的碱金属碳酸氢盐或碳酸氢铵，包含60至90重量％的水，10至40重量％的N-烷基-2-吡咯烷酮和作为污染物的有害物质 相对于N-烷基-2-吡咯烷酮至多5000重量ppm的烷基琥珀酰亚胺，并且除此之外，高达1000重量ppm的沸点高于N-烷基-2-吡咯烷酮的其它物质，在 特定的无机盐，基于每种情况下的循环流（1）的总重量，其中全部组分给出100重量％，得到纯N-烷基-2-吡咯烷酮流（2），其可以返回 到pla nt用于生产聚芳醚砜，通过在最终塔（K）中进行最终蒸馏，其包括在最终蒸馏之前通过在一个或多个蒸发器阶段中蒸发的初步纯化以降低无机盐的水平，其中一个或 获得更多的蒸气流（3,4,5），其作为进料流引入到最终塔（K）中，并且其中去除最后蒸发器级的底部流，并且其中包含1.0％ 除去最终塔（K）的底部料流（7）的10重量％至最终塔（K）的10重量％，并将来自最终塔（K）的底部料流的其余部分再循环到最后的蒸发器阶段。

公开(公告)号：US20140183028A1

公开(公告)日：2014-07-03

申请号：US14140679

申请日：2013-12-26

Applicant: BASF SE

Inventor： Christoph Sigwart ,  Jutta Vonend ,  Cornelis Hendricus De Ruiter ,  Annette Kreiner ,  Jörg Erbes ,  Tobias Kortekamp

IPC: B01D3/34

CPC classification number: B01D3/143

Abstract: A process is proposed for the treatment of a recycling stream (1) from a plant for the production of polyarylene ether sulfones via polycondensation of aromatic bishalogen compounds and of aromatic bisphenols or their salts in the presence of at least one alkali metal carbonate or ammonium carbonate or alkali metal hydrogencarbonate or ammonium hydrogencarbonate in an N-alkyl-2-pyrrolidone as solvent, comprising from 60 to 90% by weight of water, from 10 to 40% by weight of N-alkyl-2-pyrrolidone and, as contaminant detrimental to specification, up to 5000 ppm by weight of the alkylsuccinimide corresponding to the N-alkyl-2-pyrrolidone and, alongside this, up to 1000 ppm by weight of other substances with higher boiling point than N-alkyl-2-pyrrolidone, in particular inorganic salts, based in each case on the total weight of the recycling stream (1), where the entirety of the components gives 100% by weight, giving a pure N-alkyl-2-pyrrolidone stream (2) which can be returned to the plant for the production of polyarylene ether sulfones, via a final distillation in a final column (K), which comprises preceding the final distillation by a preliminary purification by evaporation in one or more evaporator stages for reducing the level of inorganic salts, where one or more vapor streams (3, 4, 5) are obtained which are supplied as feed streams to the final column (K), and where the bottom stream from the last evaporator stage is removed and the bottom stream from the final column (K) is supplied in part or in full to an additional column (K), in which it is separated into a bottom steam (11), which is removed, and into an overhead stream (12), which is recycled to the final column (K).

Abstract translation: 提出了一种方法，用于在至少一种碱金属碳酸盐或碳酸铵存在下，通过芳族双酚类化合物和芳族双酚或其盐的缩聚来处理来自植物的生产聚亚芳基醚砜的再循环料流（1） 或N-烷基-2-吡咯烷酮作为溶剂的碱金属碳酸氢盐或碳酸氢铵，包含60至90重量％的水，10至40重量％的N-烷基-2-吡咯烷酮和作为污染物的有害物质 相对于N-烷基-2-吡咯烷酮至多5000重量ppm的烷基琥珀酰亚胺，并且除此之外，高达1000重量ppm的沸点高于N-烷基-2-吡咯烷酮的其它物质，在 特定的无机盐，基于每种情况下的循环流（1）的总重量，其中全部组分给出100重量％，得到纯N-烷基-2-吡咯烷酮流（2），其可以返回 到pla nt用于生产聚芳醚砜，通过在最终塔（K）中进行最终蒸馏，其包括在最终蒸馏之前通过在一个或多个蒸发器阶段中蒸发的初步纯化以降低无机盐的水平，其中一个或 获得作为进料流供应到最终塔（K）的更多的蒸汽流（3,4,5），并且其中来自最后一个蒸发器级的底部流被除去并且来自最终塔（K）的底部流是 部分或全部供应到另外的塔（K），其中它被分离成被除去的底部蒸汽（11），并被再循环到最终塔（K）的塔顶物流（12）中， 。