公开(公告)号：US10954256B2

公开(公告)日：2021-03-23

申请号：US15763651

申请日：2016-09-30

Applicant: BASF SE

Inventor： Tobias Lang ,  Karl-Heinrich Schneider ,  Zoltan Baan ,  Philip Muelheims ,  Steffen Tschirschwitz ,  Sascha Shuxia Zhu

IPC: C07F9/22 ,  C07F9/24

Abstract: Provided herein is a use of a high-boiling solvent in a mixture comprising a (thio)phosphoric acid derivative and a process including the addition of a high-boiling solvent to a mixture comprising a (thio)phosphoric acid derivative to recover the (thio)phosphoric acid from the mixture by an evaporation process.

公开(公告)号：US20200331829A1

公开(公告)日：2020-10-22

申请号：US16756961

申请日：2018-10-31

Applicant: BASF SE

Inventor： Daniel Saelinger ,  Philip Muelheims ,  Helmut Zech ,  Roland Goetz

IPC: C07C41/16

Abstract: The present invention relates to a process for preparing 4-chlorobenzyl propargylether comprising a step (a) of reacting 4-chlorobenzyl chloride with propargyl alcohol in the presence of a base and a phase transfer catalyst, wherein the reaction mixture comprises at least two phases, wherein one phase is an organic phase and one phase is an aqueous phase.

公开(公告)号：US09512093B2

公开(公告)日：2016-12-06

申请号：US14899755

申请日：2014-06-17

Applicant: BASF SE

Inventor： Timo Frassetto ,  Maximilian Dochnahl ,  Michael Rack ,  Volker Maywald ,  Bernd Wolf ,  Roland Goetz ,  Philip Muelheims ,  Rudolf Haeberle

IPC: C07D265/36 ,  C07C17/16 ,  C07D413/04

CPC classification number: C07D265/36 ,  C07C17/16 ,  C07D413/04 ,  C07C21/22

Abstract: The present invention relates to a process for manufacturing 4-propargylated amino-benzoxazinones of formula (I), comprising the following steps: step a) preparing propargyl chloride by reacting propargyl alcohol with thionyl chloride optionally in the presence of a catalyst; and step b) reacting the propargyl chloride prepared in step (a) with a NH-benzoxazinone of formula (II); wherein the variables are defined according to the description.

公开(公告)号：US20180319826A1

公开(公告)日：2018-11-08

申请号：US15779306

申请日：2016-12-01

Applicant: BASF SE

Inventor： Tobias Lang ,  Zoltan Baan ,  Philip Muelheims ,  Anton Flajs ,  Hartmut Denecke

IPC: C07F9/22

CPC classification number: C07F9/224

Abstract: Provided herein is a process for isolating at least one (thio)phosphoric acid derivative, which has a boiling point of at least 70° C., from a product mixture including the at least one (thio)phosphoric acid derivative, at least one salt selected from ammonium salts and alkali metal chlorides, at least one polar solvent selected from the group consisting of ester solvents and ether solvents, and optionally at least one HCl scavenger; wherein the process is based on first dissolving the (thio)phosphoric acid derivative to be able to remove the at least one salt, and then causing solids formation of the (thio)phosphoric acid derivative.

公开(公告)号：US20180273557A1

公开(公告)日：2018-09-27

申请号：US15763651

申请日：2016-09-30

Applicant: BASF SE

Inventor： Tobias Lang ,  Karl-Heinrich Schneider ,  Zoltan Baan ,  Philip Muelheims ,  Steffen Tschirschwitz ,  Sascha Shuxia Zhu

IPC: C07F9/22

CPC classification number: C07F9/224 ,  C07F9/242 ,  C07F9/2458 ,  C07F9/2466 ,  C07F9/2475

Abstract: Provided herein is a use of a high-boiling solvent in a mixture comprising a (thio)phosphoric acid derivative and a process including the addition of a high-boiling solvent to a mixture comprising a (thio)phosphoric acid derivative to recover the (thio)phosphoric acid from the mixture by an evaporation process.

公开(公告)号：US11358922B2

公开(公告)日：2022-06-14

申请号：US16756961

申请日：2018-10-31

Applicant: BASF SE

Inventor： Daniel Saelinger ,  Philip Muelheims ,  Helmut Zech ,  Roland Goetz

IPC: C07C41/16 ,  C07C43/176 ,  C07C41/01 ,  C07C43/166

Abstract: The present invention relates to a process for preparing 4-chlorobenzyl propargylether comprising a step (a) of reacting 4-chlorobenzyl chloride with propargyl alcohol in the presence of a base and a phase transfer catalyst, wherein the reaction mixture comprises at least two phases, wherein one phase is an organic phase and one phase is an aqueous phase.

公开(公告)号：US10961264B2

公开(公告)日：2021-03-30

申请号：US15779306

申请日：2016-12-01

Applicant: BASF SE

Inventor： Tobias Lang ,  Zoltan Baan ,  Philip Muelheims ,  Anton Flajs ,  Hartmut Denecke

IPC: C07F9/22

Abstract: Provided herein is a process for isolating at least one (thio)phosphoric acid derivative, which has a boiling point of at least 70° C., from a product mixture including the at least one (thio)phosphoric acid derivative, at least one salt selected from ammonium salts and alkali metal chlorides, at least one polar solvent selected from the group consisting of ester solvents and ether solvents, and optionally at least one HCl scavenger; wherein the process is based on first dissolving the (thio)phosphoric acid derivative to be able to remove the at least one salt, and then causing solids formation of the (thio)phosphoric acid derivative.