公开(公告)号：US20170173491A1

公开(公告)日：2017-06-22

申请号：US15382036

申请日：2016-12-16

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: B01D3/32 ,  B01F3/04

CPC classification number: B01D3/324 ,  B01D3/20 ,  B01D3/205 ,  B01F3/04078 ,  B01F3/04496

Abstract: The present invention relates to a chimney tray (3) for a column (1) for thermal treatment of fluid mixtures, comprising a collecting tray (4) and at least two chimneys (5-1, 5-2) spaced apart horizontally in the collecting tray (4), where each chimney (5-1, 5-2) forms a vertically aligned chimney body (6-1, 6-2) which forms a passage orifice (7-1, 7-2) through the collecting tray (4), and has a cover unit (8-1, 8-2) arranged spaced apart from the chimney body (6-1, 6-2), and where the cover unit (8-1, 8-2) covers the respective passage orifices (7-1, 7-2) in the vertical direction. The chimney tray (3) of the invention is characterized by a screen (9) which extends around the chimney body (6-1) of a first chimney (5-1), with the lower annular edge (14) of the screen (9) below the upper edge (13) of the chimney body (6-1) of the first chimney (5-1) and the upper annular edge (11) of the screen (9) above the lower outer edge (12) of the cover unit (8-1) of the first chimney (5-1) or adjoining the lower outer edge (12) of the cover unit (8-1) of the first chimney (5-1).

公开(公告)号：US20170014729A1

公开(公告)日：2017-01-19

申请号：US15210194

申请日：2016-07-14

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: B01D3/32 ,  C07C51/48 ,  C07C45/80 ,  B01D3/26

CPC classification number: B01D3/32 ,  B01D3/26 ,  B01D3/324 ,  C07C45/80 ,  C07C51/44 ,  C07C51/48 ,  C07C57/04

Abstract: The present invention relates to a column (1) for thermal treatment of fluid mixtures, having a cylindrical, vertical column body (2) which forms a column cavity (3) and a vertical inner surface (16), a plurality of trays (8) mounted in the column cavity (3) and spaced apart vertically from one another, at least one stub (11) disposed within the column body (2) and extending away from the column body (2), and a closable inspection orifice (9) formed in the stub (11). The characteristic feature of the column of the invention is that in the case of a vertical cross section of the column (1) the surface (15) of the lower line of intersection of the stub (11) directed into the column cavity (3) or a tangent to the surface (15) of the lower line of intersection of the stub (11) at least in sections forms an angle within a range from 210° to 267° with the vertical inner surface (16) of the column body (2) which extends downward from the stub (11).

Abstract translation: 本发明涉及一种用于流体混合物的热处理的塔（1），其具有形成柱腔（3）和垂直内表面（16）的圆柱形垂直柱体（2），多个托盘（8） ）安装在所述柱腔（3）中并彼此间隔开，至少一个设置在所述柱主体（2）内并延伸离开所述柱体（2）的短柱（11）和可关闭的检查孔 ）形成在短截线（11）中。 本发明的色谱柱的特征在于，在柱（1）的垂直截面的情况下，短截线（11）相对于柱腔（3）的下方交叉点的表面（15） 或至少部分地与短截线（11）的下部交叉点的表面（15）的切线形成与柱体的垂直内表面（16）在210°至267°的范围内的角度 2），其从短截线（11）向下延伸。

公开(公告)号：US20160090347A1

公开(公告)日：2016-03-31

申请号：US14857967

申请日：2015-09-18

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER ,  Markus OTTENBACHER ,  Frank HUETTEN

IPC: C07C51/487 ,  B01D3/34 ,  B01D3/00 ,  B01D3/14 ,  C07C51/44 ,  B01J19/24

CPC classification number: C07C51/487 ,  B01D3/009 ,  B01D3/143 ,  B01D3/346 ,  B01J19/24 ,  B01J2219/24 ,  C07C51/42 ,  C07C51/44 ,  C07C51/48 ,  C07C57/04

Abstract: The present invention relates to the process for recovering acrylic acid, comprising the steps a) division of a heated mother acid stream in direction of an absorption column (201) and a dissociation column (205), b) feeding of a heated mother acid substream as runback to the dissociation column (205), c) feeding-in of at least one stripping gas stream to the dissociation column (205), d) feeding-in of a secondary component stream comprising oligomeric acrylic acid from the condensation column (201) to the dissociation column (205), e) dissociation of part of oligomeric acrylic acid in the dissociation column (205) to give monomeric acrylic acid, f) removal of secondary components comprised in the secondary component stream in the dissociation column (205), g) discharge of monomeric acrylic acid as gas mixture with introduced circulating stripping gas stream from the dissociation column (205) and h) feeding-in of the gas mixture to the condensation column (201).

Abstract translation: 本发明涉及回收丙烯酸的方法，包括步骤a）在吸收塔（201）和解离塔（205）的方向上分离加热的母体酸流，b）加热加热的母体酸性流 作为分离塔（205）的回流，c）将至少一个汽提气流进料到解离塔（205），d）从冷凝塔（201）中加入包含低聚丙烯酸的二次组分料流 ）解离塔（205），e）解离塔（205）中部分低聚丙烯酸的解离以得到单体丙烯酸，f）除去在解离塔（205）中的次要组分流中包含的次要组分， g）从引入的离解塔（205）的引入的循环汽提气流中排出作为气体混合物的单体丙烯酸，以及h）将气体混合物进入冷凝塔（201）。

公开(公告)号：US20160038852A1

公开(公告)日：2016-02-11

申请号：US14816485

申请日：2015-08-03

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: B01D3/32 ,  C07C51/44 ,  B01D3/26

CPC classification number: B01D3/326 ,  B01D3/26 ,  B01D3/324 ,  C07C51/44

Abstract: The present invention relates to a column (1) for thermal treatment of fluid mixtures, having a cylindrical, vertical column body (2) which forms a column cavity (3), a plurality of trays (8) mounted with vertical spacing in the column cavity (3), and a support construction (9) which supports at least one of the trays (8) in vertical direction. It is a characteristic feature of the inventive column (1) that the support construction (9) has a plurality of orifices (12) which allow horizontal mass transfer through the support construction (9). The invention further relates to a tray device for such a column and to a thermal separation process between at least one gas ascending within such a column (1) and at least one liquid descending within the column (1).

Abstract translation: 本发明涉及一种用于流体混合物的热处理的柱（1），其具有形成柱腔（3）的圆柱形垂直柱体（2），在柱中垂直间隔安装的多个托盘（8） 空腔（3）和支撑结构（9），其在垂直方向上支撑至少一个托盘（8）。 本发明的塔（1）的特征在于，支撑结构（9）具有允许通过支撑结构（9）的水平质量传递的多个孔口（12）。 本发明还涉及一种用于这种塔的托盘装置以及在这种塔（1）内上升的至少一种气体与在塔（1）内下降的至少一种液体之间的热分离过程。

公开(公告)号：US20150266000A1

公开(公告)日：2015-09-24

申请号：US14659753

申请日：2015-03-17

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: B01J19/24

CPC classification number: B01J19/24 ,  B01J8/067 ,  B01J19/0013 ,  B01J19/2425 ,  B01J2208/00176 ,  B01J2208/00256 ,  B01J2219/00081 ,  B01J2219/00094 ,  B01J2219/00103 ,  B01J2219/24

Abstract: The present invention relates to a reactor system (1) comprising a reactor 3, at least one cooler (5) connected to the reactor (3), at least one pump (7) for circulating at least some of a liquid heat-transfer medium (9), wherein the pump (7) is connected to the reactor (3) and/or the at least one cooler (5), and a container (11) for collecting the liquid heat-transfer medium (9), wherein the container (11) is connected to the reactor (3) and/or the at least one cooler (5), wherein the container (11) is disposed substantially below the reactor (3) and/or the at least one cooler (5). Moreover, the use of the reactor system (1) according to the invention for carrying out exothermic reactions is described.

Abstract translation: 本发明涉及一种包括反应器3的反应器系统（1），连接到反应器（3）的至少一个冷却器（5），至少一个泵（7），用于使至少一些液体传热介质 （9），其中泵（7）连接到反应器（3）和/或至少一个冷却器（5）和用于收集液体传热介质（9）的容器（11），其中 容器（11）连接到反应器（3）和/或至少一个冷却器（5），其中容器（11）基本上设置在反应器（3）和/或至少一个冷却器（5）的下方， 。 此外，描述了使用根据本发明的反应器系统（1）进行放热反应。

公开(公告)号：US20170267621A1

公开(公告)日：2017-09-21

申请号：US15615852

申请日：2017-06-07

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER ,  Markus OTTENBACHER ,  Frank HUETTEN

IPC: C07C51/487 ,  B01D3/00 ,  B01D3/14 ,  B01J19/24 ,  C07C51/42 ,  C07C57/04 ,  C07C51/48 ,  C07C51/44 ,  B01D3/34

CPC classification number: C07C51/487 ,  B01D3/009 ,  B01D3/143 ,  B01D3/346 ,  B01J19/24 ,  B01J2219/24 ,  C07C51/42 ,  C07C51/44 ,  C07C51/48 ,  C07C57/04

Abstract: A plant (1) for recovering acrylic acid, which includes: a absorption column (201); a dissociation column (205); a first line (101) connected to the dissociation column (205); a second line (102) connecting the absorption column (201) and the dissociation column (205); a third line (103) feeding a substream of the mother acid obtained in the crystallization into the dissociation column (205); a fourth line (104) connecting the crystallization apparatus and the absorption column (201); and a fifth line (105) connecting the dissociation column (205) and the absorption column (201).

公开(公告)号：US20170173492A1

公开(公告)日：2017-06-22

申请号：US15382073

申请日：2016-12-16

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: B01D3/32 ,  C07C67/52 ,  B01D53/18 ,  B01D3/22 ,  B01D3/26

CPC classification number: B01D3/324 ,  B01D3/20 ,  B01D3/205 ,  B01D3/225 ,  B01D3/26 ,  B01D3/32 ,  B01D53/18 ,  C07C51/42 ,  C07C51/44 ,  C07C67/52 ,  C07C57/04

Abstract: The present invention relates to a column (1) for thermal treatment of fluid mixtures, having a cylindrical, vertically aligned column body (2) which forms a column cavity (3), having a sequence of vertically spaced-apart dual-flow mass transfer trays (8) which are mounted in the column cavity (3) and which have orifices for passage of liquid and gas in countercurrent, and having at least one gas entry orifice (5) disposed below the lowermost of the sequence of dual-flow mass transfer trays (8). It is a characteristic feature of the column of the invention that a gas distribution tray (9) which is disposed between the lowermost of the sequence of dual-flow mass transfer trays (8) and the gas entry orifice (5) has orifices (32) for vertical passage of gas which can be introduced into the column cavity (3) via the gas entry orifice (5), the orifices (32) being formed so as to bring about equal gas distribution over the column cross section. The invention further relates to a process for thermal treatment of fluid mixtures in such a column (1).

公开(公告)号：US20160083267A1

公开(公告)日：2016-03-24

申请号：US14857998

申请日：2015-09-18

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER ,  Christian RAITH

IPC: C02F1/04 ,  B01D3/26 ,  B01D1/00 ,  C02F1/16

CPC classification number: C02F1/048 ,  B01D1/0058 ,  B01D3/26 ,  B01D3/346 ,  C02F1/16 ,  C02F2103/36 ,  C02F2303/10 ,  C07C51/44 ,  C07C57/04 ,  Y02W10/30

Abstract: The present invention relates to a process for treating secondary components obtained in acrolein and/or (meth)acrylic acid production, comprising the steps of: a) contacting at least one wastewater stream (201) comprising at least a portion of the water of reaction removed in a first stage of a saturation column (101) with at least one process offgas stream (203), b) introducing energy by means of a first heat transferer (103) provided in a first saturation circuit (301) into the first stage of the saturation column (101), c) partly vaporizing the wastewater stream (201) into the process offgas stream (203) and passing the combined gas stream (205) into a second stage of the saturation column (101), d) drawing off a concentrated wastewater stream (207) from the bottom (1011) of the first stage of the saturation column (101) and feeding it to the top (1023) of the second stage of the saturation column (101), e) introducing energy by means of a second heat transferer (105) provided in a second circuit (303) into the second stage of the saturation column (101), f) partly vaporizing the concentrated wastewater stream (207) into the combined gas stream (205) to obtain an offgas stream (209), g) superheating the offgas stream (209), after it has been saturated, in a third heat transferer (113) to obtain a superheated offgas stream (211) and h) transferring the offgas stream (209) or the superheated offgas stream (211) from the saturation column (101) to a thermal aftertreatment. The present invention further relates to a plant (1) for treating the secondary components obtained in acrolein and/or (meth)acrylic acid production.

Abstract translation: 本发明涉及一种用于处理由丙烯醛和/或（甲基）丙烯酸生产获得的二次成分的方法，包括以下步骤：a）使至少一个包含至少一部分反应水的废水流（201） 在具有至少一个工艺废气流（203）的饱和塔（101）的第一级中去除，b）通过设置在第一饱和电路（301）中的第一热传递器（103）将能量引入第一级 的饱和塔（101），c）将废水流（201）部分蒸发到工艺废气流（203）中，并将组合气流（205）送入饱和塔（101）的第二级，d） 从饱和塔（101）的第一级的底部（1011）离开浓缩废水流（207）并将其供给到饱和塔（101）的第二级的顶部（1023），e）引入能量 通过设置在其中的第二传热器（105） 第二回路（303）进入饱和塔（101）的第二阶段，f）将浓缩废水流（207）部分汽化成合并气流（205）以获得废气流（209），g）使废气过热 （209）或过热废气流（211）从饱和塔（209）中转移出来，在第三热转移器（113）中， （101）进行热后处理。 本发明还涉及用于处理在丙烯醛和/或（甲基）丙烯酸生产中获得的二次成分的设备（1）。

公开(公告)号：US20160040929A1

公开(公告)日：2016-02-11

申请号：US14817351

申请日：2015-08-04

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: F25J3/02

CPC classification number: F25J3/0271 ,  B01D3/20 ,  B01D3/22 ,  B01D3/32 ,  B01D3/4261 ,  C07C45/783 ,  C07C45/80 ,  C07C45/82 ,  C07C51/44 ,  C07C51/48 ,  C07C67/54 ,  C07C47/22 ,  C07C57/04 ,  C07C69/54

Abstract: The present invention relates to a column (1) for thermal treatment of a fluid, having a cylindrical, vertical column body (2) which forms a column cavity (3), and a mass transfer tray (4) which is disposed in the column cavity (3) and forms a collecting area (5). The inventive column (1) is characterized by a circulation device (9) having at least one drain orifice (10) formed in the column body (2) above the collecting area (5), a circulation line (11) in fluid connection with the drain orifice (10) and at least one recycling orifice (14; 14-1 to 14-3) which is in fluid connection with the circulation line (11) and is formed in the column body (2) above the collecting area (5). The invention also relates to a thermal separating process in which such a column (1) is used. In this separating process, a gas ascends within the column and a liquid descends within the column, said gas and/or liquid especially comprising (meth)acrylic monomers.

Abstract translation: 本发明涉及一种用于热处理流体的柱（1），其具有形成柱腔（3）的圆柱形垂直柱体（2）和设置在柱中的传质托盘（4） （3）并形成收集区域（5）。 本发明的塔（1）的特征在于具有在收集区域（5）上方的柱体（2）中形成的至少一个排水孔（10）的循环装置（9），与流体连通 所述排水孔（10）和至少一个与所述循环管线（11）流体连接并且在所述塔体（2）中的所述收集区域上方形成的再循环孔（14; 14-1至14-3） 5）。 本发明还涉及使用这种塔（1）的热分离方法。 在该分离过程中，气体在柱内上升，液体在柱内下降，所述气体和/或液体特别包含（甲基）丙烯酸单体。

公开(公告)号：US20160010850A1

公开(公告)日：2016-01-14

申请号：US14738050

申请日：2015-06-12

Applicant: BASF SE

Inventor： Ulrich HAMMON ,  Thomas WALTER

IPC: F22B1/02

CPC classification number: F22B1/021 ,  B01D1/0082 ,  F17C2221/035 ,  F17C2223/0153 ,  F17C2223/033 ,  F17C2225/0123 ,  F17C2225/035 ,  F17C2225/036 ,  F17C2227/0393 ,  F17C2265/05

Abstract: The present invention relates to a system (1) for operating a liquid gas evaporator (3), comprising an evaporator (3) for evaporating a liquid gas into its gaseous aggregation state, a trough (5) carrying the evaporator (3), a housing (7) which surrounds the evaporator (3) on three sides and which terminates flush with the trough (5), at least one detector (9) which is sensitive to the liquid gas and its gaseous aggregation state and which is arranged in the trough (5), a line (11) for the distribution of vapor D, which is provided on the fourth, non-housed side of the evaporator (3) and which is arranged at that margin of the trough (5) which is not closed off by the housing (7), a feed (13), connected to the line (11), for the vapor D, and a regulating valve (15) provided on the feed (13) and connected to the detector (9) and at least one shut-off valve (17). The present invention relates furthermore, to a method for operating a liquid gas evaporator (3).

Abstract translation: 本发明涉及一种用于操作液体气体蒸发器（3）的系统（1），包括用于将液体气体蒸发成气态聚集状态的蒸发器（3），承载蒸发器（3）的槽（5） 在三侧围绕蒸发器（3）并且与槽（5）齐平的壳体（7），至少一个对液体气体和其气体聚集状态敏感的检测器（9） 槽（5），用于分配蒸气D的管线（11），其设置在蒸发器（3）的第四非容纳侧上，并且布置在不是的槽（5）的边缘处 通过壳体（7）封闭，连接到管线（11）的用于蒸气D的进料（13）和设置在进料（13）上并连接到检测器（9）的调节阀（15） 和至少一个截止阀（17）。 本发明还涉及一种操作液体气体蒸发器（3）的方法。