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公开(公告)号：US4496776A
公开(公告)日：1985-01-29
申请号：US522130
申请日：1983-08-11
IPC分类号： B01J31/00 , B01J31/02 , C07B61/00 , C07C27/00 , C07C29/56 , C07C33/14 , C07C35/18 , C07C67/00
CPC分类号： C07C29/56 , C07C2101/16
摘要： Di-, tri- and tetra-substituted epoxides are isomerized to allylic alcohols in the presence of a metal alkoxide catalyst in which the metal is selected from early transition metals of Groups 1VA and VA and in the absence of a solvent.
摘要翻译： 二价，三取代和四取代的环氧化物在金属醇盐催化剂存在下异构化成烯丙醇，其中金属选自组1VA和VA的早期过渡金属和不存在溶剂。
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公开(公告)号：US4933502A
公开(公告)日：1990-06-12
申请号：US201248
申请日：1988-06-02
申请人： Charles L. Edwards
发明人： Charles L. Edwards
IPC分类号： B01J31/02 , C07B61/00 , C07C41/00 , C07C41/03 , C07C43/11 , C07C43/13 , C07C67/00 , C11D1/72
CPC分类号： C07C41/03
摘要： An improved process for the preparation of narrow-range alkanol alkoylates by the addition reaction of higher alkanols with alkylene oxides, particularly ethylene oxide. U.S. Pat. No. 4,721,816 describes a process in which alkylene oxides are added to alkanols by reaction in the presence of a catalyst prepared by contacting a sulfur-containing acid such as sulfuric acid with one or more aluminum compounds selected from the group consisting of aluminum alcoholates and aluminum phenolates. Under the present invention, that process is improved by carrying out the process in the further presence of water, provided that certain critical restrictions are placed upon the proportions of the water and of the sulfuric acid and aluminum catalyst components. The process improvement of the invention offers substantial improvement in alkoxylation reaction rate and/or selectivity of the reaction to the desired alkanol alkoxylate products, rather than to by-products such as polyalkylene glycols. The narrow-range alkanol alkoxylate products of the process of the invention have utility, for instance, as nonionic surfactant components of detergent formulations.
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公开(公告)号：US4665236A
公开(公告)日：1987-05-12
申请号：US847980
申请日：1986-04-03
申请人： Charles L. Edwards
发明人： Charles L. Edwards
摘要： Alkylene oxide adducts of organic compounds having an active hydrogen are prepared by a process in which an active hydrogen reactant and an alkylene oxide reactant are reacted in the presence of a catalytically effective amount of one or more bimetallic oxo compounds of the formula (RO).sub.n M--O--M'--O--M(OR).sub.n, wherein each R is (independently) an optionally-substituted organic moiety, M' is a divalent metal selected from the elements of Groups VIII, Ib, IIb, IIIb, and IVb of the Periodic Table, each M is (independently) a trivalent or tetravalent metal, and each n is 2 if the adjacent M is trivalent of 3 if the adjacent M is tetravalent. The products are useful, for instance, as nonionic surfactants in detergent formulations. In certain preferred embodiments, the process yields a product having a very desirable distribution of alkylene oxide adducts.
摘要翻译： 通过以下方法制备具有活性氢的有机化合物的环氧烷加成物，其中活性氢反应物和烯化氧反应物在催化有效量的一种或多种式（RO）nM的双金属氧代化合物存在下反应 -O-M'-OM（OR）n，其中每个R是（独立地）任选取代的有机部分，M'是选自第VIII，Ib，IIb，IIIb和IVb族的元素的二价金属 周期表中，每个M是（独立地）三价或四价金属，如果相邻的M是四价的，相邻的M是三价的，每个n是2。 该产品可用作洗涤剂配方中的非离子表面活性剂。 在某些优选实施方案中，该方法产生具有非常理想的烯化氧加合物分布的产物。
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公开(公告)号：US4689435A
公开(公告)日：1987-08-25
申请号：US847979
申请日：1986-04-03
申请人： Charles L. Edwards
发明人： Charles L. Edwards
摘要： Alkylene oxide adducts of organic compounds having an active hydrogen are prepared by a process in which an active hydrogen reactant and an alkylene oxide reactant are reacted in the presence of a catalytically effective amount of one or more bimetallic oxo compounds of the formula (RO).sub.n M--O--M'--O--M(OR).sub.n, wherein each R is (independently) an optionally-substituted organic moiety, M' is a divalent metal selected from the elements of Groups Va, VIa, and VIIa of the Periodic Table, each M is (independently) a trivalent or tetravalent metal, and each n is 2 if the adjacent M is trivalent of 3 if the adjacent M is tetravalent. The products are useful, for instance, as nonionic surfactants in detergent formulations. In certain preferred embodiments, the process yields a product having a very desirable distribution of alkylene oxide adducts.
摘要翻译： 通过以下方法制备具有活性氢的有机化合物的环氧烷加成物，其中活性氢反应物和烯化氧反应物在催化有效量的一种或多种式（RO）nM的双金属氧代化合物存在下反应 -O-M'-OM（OR）n，其中每个R是（独立地）任选取代的有机部分，M'是选自周期表第Va，VIa和VIIa族元素的二价金属， M是（独立地）三价或四价金属，如果相邻的M是四价的，相邻的M是三价的，每个n是2。 该产品可用作洗涤剂配方中的非离子表面活性剂。 在某些优选实施方案中，该方法产生具有非常理想的烯化氧加合物分布的产物。
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公开(公告)号：US4575569A
公开(公告)日：1986-03-11
申请号：US621316
申请日：1984-06-15
申请人： Charles L. Edwards
发明人： Charles L. Edwards
IPC分类号： C07C148/00
CPC分类号： C07C323/00
摘要： Thiol alkoxylates having utility, for instance, an nonionic surfactants in detergent formulations are prepared by the reaction of alkane thiols with alkylene oxides in the presence of a catalytically effective amount of one or more basic alkoxylation catalysts and additionally in the presence of as a reaction promoter added thiol alkoxylate having in the alkoxylate molecule from one to about 30 adducts of one or more alkylene oxides. The presence of the added thiol alkoxylate promoter improves the handling of the reaction mixture and facilitates the production of thiol alkoxylates having low content of polyalkylene glycol byproduct.
摘要翻译： 在洗涤剂配方中使用例如非离子表面活性剂的硫醇烷氧基化物通过在催化有效量的一种或多种碱式烷氧基化催化剂的存在下，另外在作为反应促进剂存在下，通过烷烃硫醇与环氧烷反应来制备 在烷氧基化物分子中具有一个或多个环氧烷的1至约30个加合物的硫醇烷氧基化物。 加入的硫醇烷氧基化促进剂的存在改善了反应混合物的处理，并促进了具有低聚亚烷基二醇副产物含量的硫醇烷氧基化物的生产。
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6.发明授权Magnesium catalyzed alkoxylation of alkanols in the presence of alkoxylate reaction activators 失效在烷氧基化反应活化剂存在下，烷醇的镁催化烷氧基化
公开(公告)号：US4465877A
公开(公告)日：1984-08-14
申请号：US519884
申请日：1983-08-03
申请人： Charles L. Edwards
发明人： Charles L. Edwards
IPC分类号： C07C41/03
CPC分类号： C07C41/03
摘要： Alkanol alkoxylates having utility, for instance, as nonionic surfactants in detergent formulations are prepared by the reaction of C.sub.6 to C.sub.30 alkanols with C.sub.2 to C.sub.4 alkylene oxides in the presence of a catalytically effective amount of one or more soluble basic compounds of magnesium and additionally in the presence of as a reaction activator at least about 2 percent by mole, calculated on moles of alkanol, of alkoxylates of one or more C.sub.1 to C.sub.30 alkanols having in the alkoxylate molecules from one to about 30 adducts of one or more alkylene oxides selected from the class consisting of C.sub.2 to C.sub.4 alkylene oxides.
摘要翻译： 在洗涤剂配方中用作非离子表面活性剂的烷醇烷氧基化物通过在催化有效量的一种或多种可溶性碱性化合物镁的存在下，通过C 6至C 30链烷醇与C 2至C 4环氧烷的反应来制备， 在烷氧基化物分子中具有一个或多个选自以下的一种或多种环氧烷烃的1至约30个加合物的作为反应活化剂的至少约2摩尔％的烷基醇的烷氧基化物的烷氧基化物的存在： 该类由C2至C4环氧烷烃组成。
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公开(公告)号：US5057628A
公开(公告)日：1991-10-15
申请号：US482378
申请日：1990-02-20
IPC分类号： C07C41/03
CPC分类号： C07C41/03
摘要： Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more compounds of one or more of the rare earth elements. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
摘要翻译： 通过一种方法制备具有活性氢原子的有机化合物的环氧烷加成物，该方法包括使含有一个或多个邻位环氧烷的烯化氧反应物与含有一种或多种具有活性氢原子的化合物在内， 催化有效量的一种或多种一种或多种稀土元素的化合物。 已知产物烷氧基化物可用于例如非离子表面活性剂，润湿和乳化剂，溶剂和化学中间体。
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8.发明授权
公开(公告)号：US5057627A
公开(公告)日：1991-10-15
申请号：US482379
申请日：1990-02-20
申请人： Charles L. Edwards
发明人： Charles L. Edwards
IPC分类号： C07C41/03
CPC分类号： C07C41/03
摘要： Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more of the phosphate salts of the rare earth elements. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.
摘要翻译： 通过一种方法制备具有活性氢原子的有机化合物的环氧烷加成物，该方法包括使含有一个或多个邻位环氧烷的烯化氧反应物与含有一种或多种具有活性氢原子的化合物在内， 催化有效量的一种或多种稀土元素的磷酸盐。 已知产物烷氧基化物可用于例如非离子表面活性剂，润湿和乳化剂，溶剂和化学中间体。
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公开(公告)号：US4931205A
公开(公告)日：1990-06-05
申请号：US230809
申请日：1988-08-09
IPC分类号： C07C323/12
CPC分类号： C07C323/12 , Y10S516/01
摘要： Certain mixtures of the ethylene oxide adducts of higher carbon number tertiary thiols, having a reduced content of free thiols and lower (i.e., 1 to 3 mol) ethylene oxide adducts, exhibit improved detergency performance, particularly in high temperature laundry applications.
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公开(公告)号：US4721817A
公开(公告)日：1988-01-26
申请号：US948378
申请日：1986-12-31
申请人： Charles L. Edwards
发明人： Charles L. Edwards
IPC分类号： B01J31/02 , B01J31/00 , C07B61/00 , C07C41/00 , C07C41/03 , C07C41/08 , C07C43/11 , C07C67/00
CPC分类号： C07C41/03
摘要： Alkylene oxide adducts of higher alkanols are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more C.sub.2 to C.sub.4 vicinal alkylene oxides with an alkanol reactant comprising one or more C.sub.6 to C.sub.30 alkanols in the presence of a catalytically effective amount of a catalyst which combines (i) one or more phosphorus-containing acids with (ii) one or more aluminum compounds selected from the group consisting of aluminum alcoholates and aluminum phenolates, the relative molar ratio of component (i) to component (ii) being in the range from about 0.1:1 to 2.5:1. Alkanol alkoxylates, and particularly alkanol ethoxylates, prepared in this manner are characterized by a relatively narrow-range distribution of alkylene oxide adducts and by a relatively low content of residual alkanol. The products of this process are nonionic surfactants, particularly useful as components of detergent formulations.
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