公开(公告)号：US20240247002A1

公开(公告)日：2024-07-25

申请号：US18561626

申请日：2022-05-20

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Wesley Sattler ,  Nicole M. Herb ,  Matthew T. Kapelewski ,  Aaron W. Peters

IPC: C07F3/02 ,  C01B39/00 ,  C07F11/00 ,  C07F13/00

CPC classification number: C07F3/02 ,  C01B39/00 ,  C07F11/00 ,  C07F13/00 ,  C01P2002/72

Abstract: Provided herein are methods of making metal-organic frameworks comprising forming a suspension capable of producing metal-organic frameworks; inducing flocculation of the suspension to form a plurality of flocs; allowing the flocs to separate from the suspension and produce a solid phase comprising metal-organic frameworks and a supernatant liquid phase; separating the solid phase from the supernatant liquid phase; and recovering the metal-organic frameworks from the solid phase. The present methods include dissolving a metal salt and at least one ligand in a solvent to form the suspension.