公开(公告)号：US20220204855A1

公开(公告)日：2022-06-30

申请号：US17670906

申请日：2022-02-14

Applicant: FUJIFILM Corporation

Inventor： Keisuke KODAMA ,  Yuki FUKUSHIMA ,  Shunya KATOH ,  Yuta TAKAHASHI ,  Shinpei YOSHIDA ,  Satoshi YANOKUCHI ,  Akira MARUYAMA ,  Hiroyuki HAGIO

IPC: C09K19/58 ,  C09K19/20 ,  G02B5/30 ,  H01L51/52

Abstract: Provided is a liquid crystal composition capable of forming an optically anisotropic layer, and method thereof, in which a variation in a twisted angle of liquid crystal compound in an in-plane direction is suppressed an optical film, and a circularly polarizing plate for an organic EL display. The liquid crystal composition contains a liquid crystal, optically active compound A which is a photosensitive optically active compound whose helical twisting power changes upon irradiation with light and has a molar absorption coefficient of 5,000 M−1·cm−1 or more with respect to light having a wavelength of 365 nm, and an optically active compound B having a molar absorption coefficient with respect to light having a wavelength of 365 nm smaller than the molar absorption coefficient of the optically active compound A, in which a mass content ratio of the optically active compound A to the liquid crystal compound is less than 0.01.

公开(公告)号：US20220381953A1

公开(公告)日：2022-12-01

申请号：US17878873

申请日：2022-08-01

Applicant: FUJIFILM Corporation

Inventor： Kazushige NAKAGAWA ,  Hideyuki NISHIKAWA ,  Masato NAKAO ,  Shunya KATOH ,  Hiroyuki HAGIO ,  Yutaka NOZOE ,  Kunihiro KASEZAWA ,  Yuki NAKAMURA

IPC: G02B1/111 ,  C09K19/56 ,  C09K19/38

Abstract: The present invention provides an optical film having a liquid crystal layer having excellent durability, and a liquid crystal film. The optical film of the present invention has an organic base material and a liquid crystal layer disposed on the organic base material, the liquid crystal layer contains a photo-alignment compound, and in the liquid crystal layer, the photo-alignment compound is unevenly distributed on a side of the organic base material.

公开(公告)号：US20240240086A1

公开(公告)日：2024-07-18

申请号：US18612685

申请日：2024-03-21

Applicant: FUJIFILM Corporation

Inventor： Tomonori MIMURA ,  Akio TAMURA ,  Hiroyuki HAGIO ,  Yuta FUKUSHIMA

IPC: C09K19/38 ,  C09K19/04 ,  C09K19/34

CPC classification number: C09K19/3823 ,  C09K19/3491 ,  C09K2019/0448

Abstract: A liquid crystal composition capable of forming a liquid crystal cured layer with suppressed cissing during formation of a liquid crystal cured layer and excellent alignment properties, a liquid crystal cured layer, an optical film, a polarizing plate, and an image display device. The liquid crystal composition includes a liquid crystal compound and a surfactant, in which the surfactant is a copolymer having a repeating unit A including two or more silicon atom-containing groups each having three substituents and a repeating unit B including two or more ring structures consisting of a cycloalkane ring or a monocyclic aromatic ring in which at least one of the ring structures consists of a monocyclic aromatic ring.

公开(公告)号：US20230135489A1

公开(公告)日：2023-05-04

申请号：US18065866

申请日：2022-12-14

Applicant: FUJIFILM Corporation

Inventor： Akio TAMURA ,  Hiroyuki HAGIO ,  Reiko INUSHIMA ,  Mayumi NOJIRI ,  Nobuyuki AKUTAGAWA ,  Yuta FUKUSHIMA

IPC: C08F20/24 ,  C09D127/12

Abstract: A fluorine-containing polymer includes at least one repeating unit represented by any of General Formulae (I) to (III):

公开(公告)号：US20160187537A1

公开(公告)日：2016-06-30

申请号：US15008990

申请日：2016-01-28

Applicant: FUJIFILM Corporation

Inventor： Hiroyuki HAGIO ,  Shinichi ICHIKAWA ,  Masaki NORO ,  Yu NAITO ,  Nobutaka FUKAGAWA ,  Yutaka NOZOE

IPC: G02B1/04 ,  G02B5/30 ,  G02B1/14 ,  G02F1/1335

CPC classification number: G02B1/04 ,  G02B1/14 ,  G02B5/3033 ,  G02F1/133528 ,  Y10T428/105

Abstract: An optical film is provided containing cellulose acylate and at least one type of a compound denoted by the following Formula (I). R1 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy carbonyl group, a carbamoyl group, an alkyl sulfonyl group, or an aryl sulfonyl group, R2 represents an alkyl group or an aryl group, L represents a single bond or a bivalent or more connecting group, and n represents 1 when L is a single bond and n represents an integer of the valence of L−1 when L is a bivalent or more connecting group. s and t each independently represent 1 to 3, and X represents —O— or —N(Ra)-. Ra represents a hydrogen atom or an alkyl group.

Abstract translation: 提供含有纤维素酰化物和至少一种类型由下式（I）表示的化合物的光学膜。 R1表示氢原子，烷基，烯基，芳基，杂环基，酰基，烷氧基羰基，氨基甲酰基，烷基磺酰基或芳基磺酰基，R2表示烷基 基或芳基，L表示单键或2价以上的连接基，当L为单键时，n表示1，当L为2价以上连接基时，n表示L-1的化合价的整数 。 s和t各自独立地表示1〜3，X表示-O-或-N（Ra） - 。 R a表示氢原子或烷基。

公开(公告)号：US20150185368A1

公开(公告)日：2015-07-02

申请号：US14570499

申请日：2014-12-15

Applicant: FUJIFILM Corporation

Inventor： Hisato NAGASE ,  Hiroyuki HAGIO ,  Hiroyuki ISHIKAWA ,  Naoya SHIMOJU ,  Aiko YOSHIDA ,  Yu NAITO

IPC: G02B1/14 ,  G02B5/30 ,  G02F1/1335 ,  C07D239/62

CPC classification number: G02B1/14 ,  B32B2457/202 ,  C07D239/62 ,  G02B5/3025 ,  G02F1/133528 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/105

Abstract: An optical film containing a cellulose acylate, and a compound represented by formula (I); a polarizing plate and a liquid crystal display device using the optical film; and a compound represented by formula (I): wherein R1a and R1a each independently represent a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, or a heterocyclic group; R5a represents a halogen atom, a cyano group, or a substituent, via a heteroatom or the carbon atom, which has a specific unsaturated moiety in an a-position; R5b represents a substituent; and each group of R1a, R3a and R5b may be substituted with a substituent.

Abstract translation: 含有纤维素酰化物的光学膜和由式（I）表示的化合物; 偏光板和使用该光学膜的液晶显示装置; 和由式（I）表示的化合物：其中R1a和R1a各自独立地表示氢原子，烷基，烯基，环烷基，环烯基，芳基或杂环基; R5a表示卤素原子，氰基或取代基，杂原子或碳原子在a位具有特定的不饱和部分; R5b表示取代基; R1a，R3a和R5b的每一个可以被取代基取代。

公开(公告)号：US20220171109A1

公开(公告)日：2022-06-02

申请号：US17670878

申请日：2022-02-14

Applicant: FUJIFILM Corporation

Inventor： Yuta TAKAHASHI ,  Shinpei YOSHIDA ,  Satoshi YANOKUCHI ,  Akira MARUYAMA ,  Keisuke KODAMA ,  Yuta FUKUSHIMA ,  Shunya KATOH ,  Yuki FUKUSHIMA ,  Hiroyuki HAGIO

IPC: G02B5/30 ,  C09K19/38

Abstract: Provided is a method for producing an optically anisotropic layer, with a polarizer, which has a plurality of regions in which alignment states of a liquid crystal compound are fixed and different from one another; laminate, with a polarizer; and a composition. The method includes: 1) forming a composition layer containing a chiral agent containing at least a photosensitive chiral agent and a polymerizable liquid crystal compound on a substrate, 2) subjecting the composition layer to a heat treatment, 3) subjecting the composition layer to light irradiation under oxygen concentration of 1% by volume or more, after step 2), and 4) subjecting the composition layer to a curing treatment to form an optically anisotropic layer, and 5) carrying out step 3) under heating conditions, or subjecting the composition layer to a heat treatment between step 3) and step 4), with a predetermined amount of chiral agent.

公开(公告)号：US20220171096A1

公开(公告)日：2022-06-02

申请号：US17670921

申请日：2022-02-14

Applicant: FUJIFILM Corporation

Inventor： Akira MARUYAMA ,  Keisuke KODAMA ,  Tetsuro OTSUKA ,  Hiroyuki HAGIO ,  Yuta TAKAHASHI ,  Shinpei YOSHIDA ,  Satoshi YANOKUCHI

IPC: G02B1/11 ,  H01J49/40 ,  G02F1/137 ,  C09K19/04 ,  G02F1/1337

Abstract: Provided is an optical film with a resin substrate adhered to an optically anisotropic layer and suppression of occurrence of optical defects in the optically anisotropic layer. The optical film has a resin substrate having an alignment regulating force and an optically anisotropic layer arranged thereon, in which the optically anisotropic layer contains a liquid crystal compound and a compound having a heteroatom different from the liquid crystal compound, and in a case where a surface of the optical film on an optically anisotropic layer side thereof is a first surface and a surface of the optical film on a resin substrate side thereof is a second surface, and components of the optical film in a depth direction are analyzed by time-of-flight secondary ion mass spectrometry while irradiating the optical film with an ion beam from the first surface toward the second surface, the obtained profile satisfies a predetermined requirement.

公开(公告)号：US20180267368A1

公开(公告)日：2018-09-20

申请号：US15984994

申请日：2018-05-21

Applicant: FUJIFILM Corporation

Inventor： Keita TAKAHASHI ,  Hiroshi MATSUYAMA ,  Naozumi SHIRAIWA ,  Taiji KATSUMATA ,  Yuuta FUJINO ,  Hiroshi SATO ,  Kiyoshi TAKEUCHI ,  Hiroyuki HAGIO ,  Aiko YOSHIDA ,  Hiroaki NAKATSUGAWA

IPC: G02F1/1337 ,  F21V8/00 ,  C09K19/14 ,  G02F1/1335

CPC classification number: G02F1/133723 ,  C07C67/14 ,  C07C67/30 ,  C07C2601/14 ,  C09K19/14 ,  C09K19/3068 ,  C09K2019/0448 ,  C09K2219/03 ,  G02B5/3033 ,  G02B6/0056 ,  G02F1/133528 ,  G02F1/13363 ,  G02F1/133788 ,  G02F2001/133637 ,  H01L51/5281 ,  C07C69/75

Abstract: An object of the present invention is to provide an optical film having an optically-anisotropic layer having excellent durability, a polarizing plate and an image display device in which the optical film is used, a polymerizable compound used in the optical film, and a method for manufacturing a 1,4-cyclohexanedicarboxylic acid monoaryl ester. The optical film of the present invention is an optical film having at least an optically-anisotropic layer, in which the optically-anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a polymerizable compound which has a specific structure, a liquid crystal compound which has a specific structure, and a polymerization initiator.

公开(公告)号：US20160124123A1

公开(公告)日：2016-05-05

申请号：US14991544

申请日：2016-01-08

Applicant: FUJIFILM Corporation

Inventor： Masaki NORO ,  Yutaka NOZOE ,  Hiroshi INADA ,  Naoya SHIMOJU ,  Hisato NAGASE ,  Hiroyuki HAGIO ,  Yu NAITO ,  Nobutaka FUKAGAWA

IPC: G02B1/14 ,  G02F1/1335 ,  G02B5/30 ,  C08J5/18

CPC classification number: G02B1/14 ,  C08J5/18 ,  C08J2301/10 ,  C08K5/3462 ,  C08L1/10 ,  G02B5/3033 ,  G02B5/305 ,  G02F1/133528

Abstract: A cellulose acylate film, containing at least: a cellulose acylate; and a compound represented by the following Formula (I): wherein R1, R3 and R5 each independently designate a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, or an aromatic group, which groups may have a further substituent; with the proviso that at least one of R1, R3 and R5 is an alkyl group substituted with a group having a ring structure or a cycloalkyl group, and the total number of the ring structures existing in R1, R3 and R5 is 3 or more.

Abstract translation: 纤维素酰化物膜，至少含有：酰化纤维素; 和由下式（I）表示的化合物：其中R1，R3和R5各自独立地表示氢原子，烷基，环烷基，烯基或芳族基团，该基团可以具有另外的取代基; 条件是R 1，R 3和R 5中的至少一个是被具有环结构或环烷基的基团取代的烷基，并且存在于R 1，R 3和R 5中的环结构的总数为3以上。