Abstract:
A process for preparing a Mn+4 doped phosphor of formula I includes gradually adding a first solution comprising a source of M and HF and a second solution comprising a source of Mn to a reactor, in the presence of a source of A and an anion selected from phosphate, sulfate, acetate, and combinations thereof, to form a product liquor comprising the Mn+4 doped phosphor. The process also includes gradually discharging the product liquor from the reactor while volume of the product liquor in the reactor remains constant. A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
Abstract:
Coating systems suitable for use in generating fluorescent visible light, and lamps provided with such coating systems. The coating systems includes a phosphor-containing coating that contains at least a first phosphor that is predominantly excited by ultraviolet radiation of a first wavelength to emit visible light and absorbs but is less efficiently excited by ultraviolet radiation of a second wavelength. The coating system further includes a second phosphor that absorbs the ultraviolet radiation of the second wavelength and little if any of the ultraviolet radiation of the first wavelength.
Abstract:
A coating system for a fluorescent lamp, and fluorescent lamps provided therewith. The coating system includes a phosphor-containing coating containing a mixture of phosphors that contain less than 10% weight rare earth phosphors. The phosphor-containing coating emits visible light having a color rendering index of at least 87 when excited by UV radiation.
Abstract:
A method includes obtaining particles of a phosphor precursor of formula Ax[MFy]:Mn4+, reducing sizes of the particles of the phosphor precursor by wet milling the particles and annealing the particles that are wet milled by contacting the particles with a fluorine-containing oxidizing agent. Additionally, a manganese doped complex fluoride phosphor prepared by this method is provided. A lighting apparatus and backlight device that include manganese-doped phosphor prepared by this method also are provided.
Abstract:
Coating systems suitable for use in fluorescent lamps, particularly as scattering agents within a UV-reflecting coating for the purpose of improving fluorescent lamp luminosity. Such a coating system is provided on a transparent or translucent substrate and includes a phosphor coating and a scattering agent that scatters UV rays. The scattering agent includes an inorganic powder present in a separate UV-reflecting layer adjacent the phosphor coating and/or dispersed in the phosphor coating so that the scattered UV rays are absorbed by the phosphor coating and cause the phosphor coating to emit visible light. The inorganic powder exhibits low or no absorption to UV rays having wavelengths of 185 nm and 254 nm and is not reactive with mercury.
Abstract:
Phosphor-containing coating compositions and methods capable of changing the lumen maintenance characteristics of phosphor-containing coatings and fluorescent lamps that utilize such coatings. Lumen maintenance of a fluorescent lamp can be modified by forming a phosphor-containing coating to contain at least a first phosphor that depreciates during operation of the fluorescent lamp, and forming the phosphor-containing coating to further contain an additive composition in a sufficient amount and sufficiently uniformly distributed in the phosphor-containing coating to inhibit depreciation of the first phosphor during operation of the fluorescent lamp.
Abstract:
Described are methods and apparatus for providing fluorescent lamps having a two-layer phosphor coating that includes a base coating and a top coating that economically provides a high color rendering index (CRI) of at least 87 with improved brightness. In an embodiment, a low-pressure discharge lamp includes a light transmissive envelope having a basecoat phosphor layer disposed on an inner surface, wherein the basecoat phosphor layer includes less than ten percent weight of a rare earth phosphor. Also included is a topcoat phosphor layer on a surface of the base coat phosphor layer that includes a blend of at least red, green, green-blue and blue emitting rare earth phosphors, and a fill gas composition within the light transmissive envelope.