Method for producing fluoride fluorescent material

    公开(公告)号:US12110432B2

    公开(公告)日:2024-10-08

    申请号:US18149244

    申请日:2023-01-03

    发明人: Tomokazu Yoshida

    IPC分类号: C09K11/61 C01B33/10

    摘要: A method for producing a fluoride fluorescent material comprises: preparing fluoride particles having a composition containing at least one element or ion A selected from the group consisting of alkaline metal elements and NH4+, at least one element M selected from the group consisting of Group-4 elements and Group-14 elements, Mn4+, and F, in which a molar ratio of A in 1 mol of the composition is 2, a total molar ratio of M and Mn4+ is 1, a molar ratio of Mn4+ is in a range of more than 0 and less than 0.2, and a molar ratio of F is 6; subjecting the fluoride particles to a first heat treatment at a temperature of 500° C. or more in an inert gas atmosphere; washing the first heat-treated fluoride particles with a washing liquid; and bringing the washed fluoride particles into contact with a fluorine-containing substance and subjecting the resulting fluoride particles to a second heat treatment at a temperature of 400° C. or more.

    Chlorosilicate fluorescent material, method for producing the same, and light emitting device

    公开(公告)号:US12060509B2

    公开(公告)日:2024-08-13

    申请号:US18341365

    申请日:2023-06-26

    IPC分类号: C09K11/61 C09K11/77 H01L33/26

    CPC分类号: C09K11/617 H01L33/26

    摘要: Provided are a chlorosilicate fluorescent material having high light emission efficiency, a method for producing the same, and a light emitting device. In certain embodiments, the chlorosilicate fluorescent material has a chemical composition comprising Ca, Eu, Mg, Si, O, and Cl, wherein when a molar ratio of Si in 1 mol of the chemical composition is set as 4, the chlorosilicate fluorescent material comprises Ca in a molar ratio range of 7.0 or more and 7.94 or less, Eu in a molar ratio range of 0.01 or more and 1.0 or less, Ca and Eu in a total molar ratio range of 7.70 or more and 7.95 or less, Mg in a molar ratio range of 0.9 or more and 1.1 or less, and Cl in a molar ratio range of more than 1.90 and 2.00 or less.

    Chlorosilicate fluorescent material, method for producing the same, and light emitting device

    公开(公告)号:US11732187B2

    公开(公告)日:2023-08-22

    申请号:US16661063

    申请日:2019-10-23

    IPC分类号: C09K11/61 C09K11/77 H01L33/26

    CPC分类号: C09K11/617 H01L33/26

    摘要: Provided are a chlorosilicate fluorescent material having high light emission efficiency, a method for producing the same, and a light emitting device. In certain embodiments, the chlorosilicate fluorescent material has a chemical composition comprising Ca, Eu, Mg, Si, O, and Cl, wherein when a molar ratio of Si in 1 mol of the chemical composition is set as 4, the chlorosilicate fluorescent material comprises Ca in a molar ratio range of 7.0 or more and 7.94 or less, Eu in a molar ratio range of 0.01 or more and 1.0 or less, Ca and Eu in a total molar ratio range of 7.70 or more and 7.95 or less, Mg in a molar ratio range of 0.9 or more and 1.1 or less, and Cl in a molar ratio range of more than 1.90 and 2.00 or less.