公开(公告)号：US07943802B2

公开(公告)日：2011-05-17

申请号：US11715495

申请日：2007-03-08

申请人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

发明人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

IPC分类号： C07C27/10

CPC分类号： C07F7/21

摘要： A nanoparticle composite includes a host molecule including a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at opposite terminals thereof and a three-dimensional silica network section, and having a structure represented by the following formula (1): where X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group, independent NHR group (where R is alkyl group) or independent OCY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O, independent NH—C═O or independent NR—C═O (where R is alkyl group); n is 1≦n≦10; and m is 1≦m≦n; and a guest molecule included in the host molecule.

摘要翻译： 纳米颗粒复合材料包括主体分子，其包括分别具有相对端的亲水基团和氟代烷基的链低聚物部分和三维二氧化硅网络部分，并具有由下式（1）表示的结构：其中X是 亲水基团，独立的OH基团，独立的NCO基团，独立的NH2基团，独立的NHR基团（其中R是烷基）或独立的OCY基团（其中Y是亲水基团）; RF是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O = C-O，独立的NH-C = O或独立的NR-C = O（其中R是烷基）; n为1＆nlE; n＆nlE; 10; 并且m是1＆nlE; m＆nlE; n; 和宿主分子中包含的客体分子。

公开(公告)号：US20080064903A1

公开(公告)日：2008-03-13

申请号：US11715495

申请日：2007-03-08

申请人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

发明人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

IPC分类号： C07C27/10

CPC分类号： C07F7/21

摘要： A nanoparticle composite includes a host molecule including a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at opposite terminals thereof and a three-dimensional silica network section, and having a structure represented by the following formula (1): where X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group, independent NHR group (where R is alkyl group) or independent OCY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O, independent NH—C═O or independent NR—C═O (where R is alkyl group); n is 1≦n≦10; and m is 1≦m≦n; and a guest molecule included in the host molecule.

摘要翻译： 纳米颗粒复合材料包括主体分子，其包括分别具有相对端的亲水基团和氟代烷基的链低聚物部分和三维二氧化硅网络部分，并具有由下式（1）表示的结构：其中X是 独立的OH基团，独立的NCO基团，独立的NH 2基团，独立的NHR基团（其中R是烷基）或独立的OCY基团（其中Y是亲水基团）; R F是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O-C-O，独立的NH-C-O或独立的NR-C-O（其中R是烷基）; n为1 <= n <= 10; 并且m是1 <= m <= n; 和宿主分子中包含的客体分子。

公开(公告)号：US08247591B2

公开(公告)日：2012-08-21

申请号：US12910739

申请日：2010-10-22

申请人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

发明人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

IPC分类号： C07F7/21 ,  C07F7/10

CPC分类号： C07F7/21

摘要： A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (2): where R′ is independent H or independent alkyl group; X is the hydrophilic group and is selected from the group consisting of an OH group, an NCO group, an NH2 group, an NHR group (where R is alkyl group) and a COY group (where Y is a hydrophilic group); RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is selected from the group consisting of an O, O═C—O, NH—C═O and NR—C═O (where R is alkyl group); E is O, O═C—O, NH—C═O or NR—C═O (where R is alkyl group); L is (CH2O)l—[Si(CH3)2O]k—(CH2O)l-α, (CF2)j-α or (CF2O)h-α where α is COY group (where Y is hydrophilic group), NCO group, NH2 group, NHR group (R is alkyl group), R group (or alkyl group) or H; n is 1≦n≦10; m is 1≦m≦n; k is 1≦k≦500; l is 0≦1≦10; j is 0≦j≦20; and h is 1≦h≦20.

摘要翻译： 纳米颗粒包括在其相对端具有亲水基团和氟代烷基的链寡聚体部分，三维二氧化硅网络部分和具有氟或硅的有机链，并由下式（2）表示：其中R '是独立的H或独立的烷基; X是亲水基团，选自OH基团，NCO基团，NH 2基团，NHR基团（其中R是烷基）和COY基团（其中Y是亲水基团）; RF是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B选自O，O = C-O，NH-C = O和NR-C = O（其中R是烷基）; E是O，O = C-O，NH-C = O或NR-C = O（其中R是烷基）; L是（CH 2 O）1- [Si（CH 3）2 O] k - （CH 2 O）1-α，（CF 2）j-α或（CF 2 O）h-α，其中α是COY基团（其中Y是亲水基团） 基团，NH 2基，NHR基（R为烷基），R基（或烷基）或H; n为1＆nlE; n＆nlE; 10; m为1＆nlE; m＆nlE; n; k是1＆nlE; k＆nlE; 500; l为0＆nlE; 1＆nlE; 10; j为0＆nlE; j＆nlE; 20; h为1＆nlE; h＆nlE; 20。

公开(公告)号：US07825283B2

公开(公告)日：2010-11-02

申请号：US11715496

申请日：2007-03-08

申请人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

发明人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

IPC分类号： C07C27/10

CPC分类号： C07F7/21

摘要： A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (1): where R′ is independent H or independent alkyl group; X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group or the like; RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O or the like; E is O, O═C—O, NH—C═O or the like; G is [(CH2O)1—[Si(CH3)2O]k—(CH2O)1] or the like.

摘要翻译： 纳米颗粒包括在其相对端分别具有亲水基团和氟代烷基的链寡聚体部分，三维二氧化硅网络部分和具有氟或硅的有机链，并由下式（1）表示：其中R '是独立的H或独立的烷基; X是亲水基团，独立的OH基团，独立的NCO基团，独立的NH2基团等; RF是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O = C-O等; E是O，O = C-O，NH-C = O等; G是[（CH 2 O）1- [Si（CH 3）2 O] k - （CH 2 O）1]等。

公开(公告)号：US20080064904A1

公开(公告)日：2008-03-13

申请号：US11715496

申请日：2007-03-08

申请人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

发明人： Hideaki Yaegashi ,  Shoko Kano ,  Masahiko Yamanaka ,  Kentarou Watanabe ,  Hiroshi Yokoyama ,  Hideo Sawada

IPC分类号： C07C27/10

CPC分类号： C07F7/21

摘要： A nanoparticle includes a chain oligomer section having a hydrophilic group and fluoroalkyl groups respectively at its opposite terminals, a three-dimensional silica network section, and an organic chain having fluorine or silicon, and is represented by the following formula (1): where R′ is independent H or independent alkyl group; X is the hydrophilic group and is independent OH group, independent NCO group, independent NH2 group or the like; RF is the fluoroalkyl group having a carbon number of 2 to 10 and a molecular weight of 119 to 1000; 3D-SN is the three-dimensional silica network section; B is independent O, independent O═C—O or the like; E is O, O═C—O, NH—C═O or the like; G is [(CH2O)1—[Si(CH3)2O]k—(CH2O)1] or the like.

摘要翻译： 纳米颗粒包括在其相对端分别具有亲水基团和氟代烷基的链寡聚体部分，三维二氧化硅网络部分和具有氟或硅的有机链，并由下式（1）表示：其中R '是独立的H或独立的烷基; X是亲水基团，是独立的OH基团，独立的NCO基团，独立的NH 2基团等; R F是碳数为2〜10，分子量为119〜1000的氟代烷基; 3D-SN是三维硅网络部分; B是独立的O，独立的O-C-O等; E是O，O-C-O，NH-C-O等; G是[（CH 2）2） - [Si（CH 3 3）2 O] （CH 2 O 2）1 ...等。

公开(公告)号：US06893556B2

公开(公告)日：2005-05-17

申请号：US10244604

申请日：2002-09-17

申请人： Hideaki Yaegashi ,  Tsuneo Sakauchi ,  Osamu Tanaka ,  Hiroyuki Kishi ,  Masahiro Obika

发明人： Hideaki Yaegashi ,  Tsuneo Sakauchi ,  Osamu Tanaka ,  Hiroyuki Kishi ,  Masahiro Obika

IPC分类号： B05C21/00 ,  C23C22/00 ,  C23C22/86 ,  B08B3/10

CPC分类号： C23C22/86 ,  C23C22/00 ,  C23C22/184

摘要： A pretreatment apparatus for performing pretreatment before a painting process includes a treatment tank to be filled with a treatment liquid for degreasing and chemical conversion. A circuit section forms a circulation path for circulating the treatment liquid from the treatment tank to the treatment tank. A purifying section removes dust, chemical sludge and oil from the treatment liquid circulated to the treatment tank through the circulation path.

摘要翻译： 在涂装前进行预处理的预处理装置包括填充有用于脱脂和化学转化的处理液的处理槽。 电路部分形成用于使处理液从处理槽循环到处理槽的循环路径。 净化部通过循环路径从循环到处理槽的处理液中除去灰尘，化学污泥和油。

公开(公告)号：US20130130056A1

公开(公告)日：2013-05-23

申请号：US13638442

申请日：2011-03-21

申请人： Yasuhiro Kimura ,  Hideaki Yaegashi ,  Shinji Matsuda ,  Bernhard Wessling ,  Jörg Posdorfer ,  Monika Schwarzenberg ,  Stephan Nissen ,  Soichiro Sugawara

发明人： Yasuhiro Kimura ,  Hideaki Yaegashi ,  Shinji Matsuda ,  Bernhard Wessling ,  Jörg Posdorfer ,  Monika Schwarzenberg ,  Stephan Nissen ,  Soichiro Sugawara

IPC分类号： C09D5/08

CPC分类号： C09D5/08 ,  C09D191/06 ,  Y10T428/12569 ,  Y10T428/1352 ,  Y10T428/24612 ,  Y10T428/31714 ,  C08L79/02 ,  C08L91/02

摘要： The present invention relates to a corrosion-protective composition containing a wax, an unsubstituted or substituted polyaniline in a doped form and a liquid paraffin, and articles comprising the composition applied on a substrate. It also relates to a process for manufacturing the composition, wherein i) a first dispersion of a polyaniline in a doped form is prepared; and ii) the first dispersion of the polyaniline is combined with a wax component to sufficiently disperse the polyaniline therein, and to the use of the composition as a single layer coating for the protection against corrosion of a substrate in need thereof.

摘要翻译： 本发明涉及含有蜡，未取代或取代的掺杂形式的聚苯胺和液体石蜡的防腐蚀组合物，以及包含组合物的物品，其施加在基材上。 它还涉及制备组合物的方法，其中i）制备掺杂形式的聚苯胺的第一分散体; 和ii）将聚苯胺的第一分散体与蜡组分合并，以充分分散其中的聚苯胺，以及将组合物用作单层涂层以防止有此需要的基材的腐蚀。