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公开(公告)号:US20210151262A1
公开(公告)日:2021-05-20
申请号:US17158558
申请日:2021-01-26
Inventor: Arijit MALLICK , Bilal AHMED , Osama SHEKHAH , Husam N. ALSHAREEF , Mohamed EDDAOUDI
IPC: H01G11/30 , C07D471/06 , C07F7/00 , H01G11/86
Abstract: Embodiments of the present disclosure describe an electrode material comprising a metal ion cluster and an organic linker with a redox-active center associated with the metal ion cluster sufficient to form a metal-organic framework. Embodiments of the present disclosure further describe a method of forming an electrode material comprising contacting a metal ion cluster with an organic linker including a redox-active center sufficient to form a metal-organic framework. Embodiments of the present disclosure also describe a metal-organic framework composition comprising a metal ion cluster and an organic linker with a redox-active center associated with the metal ion cluster.
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2.
公开(公告)号:US20190282949A1
公开(公告)日:2019-09-19
申请号:US16431860
申请日:2019-06-05
Inventor: Mohamed EDDAOUDI , Amandine CADIAU , Prashant M. BHATT , Karim ADIL , Youssef BELMABKHOUT
Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.
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3.
公开(公告)号:US20190270078A1
公开(公告)日:2019-09-05
申请号:US16412512
申请日:2019-05-15
Inventor: Mohamed EDDAOUDI , Karim ADIL , Youssef BELMABKHOUT , Amandine CADIAU
Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands. Methods for capturing chemical species from fluid compositions comprise contacting a metal organic framework characterized by the formula [MaMbF6-n(O/H2O)w(Ligand)x(solvent)y]z with a fluid composition and capturing one or more chemical species from the fluid composition.
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公开(公告)号:US20180264434A1
公开(公告)日:2018-09-20
申请号:US15532839
申请日:2015-12-04
Inventor: Dalal ALEZI , Youssef BELMABKHOUT , Mohamed EDDAOUDI
IPC: B01J20/22 , B01D53/047
CPC classification number: B01J20/226 , B01D53/02 , B01D53/047 , B01D53/0476 , B01D2253/204 , B01D2257/104 , B01D2257/7025 , B01D2258/05 , B01D2259/4525 , F17C11/007 , Y02C20/20
Abstract: B&A: 4053.022PCT1 KAUST: 2014-099-02 26 ABSTRACT Embodiments provide a method of storing a compound using a metal organic framework (MOF). The method includes contacting one or more MOFs with a fluid and sorbing one or more compounds, such as O2 and CH4. O2 and CH4 can be sorbed simultaneously or in series. The metal organic framework can be an M-soc-MOF, wherein M can include aluminum, iron, gallium, indium, vanadium, chromium, titanium, or scandium.
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5.
公开(公告)号:US20180093218A1
公开(公告)日:2018-04-05
申请号:US15564935
申请日:2016-04-07
Inventor: Mohamed EDDAOUDI , Amandine CADIAU , Prashant M. BHATT , Karim ADIL , Youssef BELMABKHOUT
CPC classification number: B01D53/02 , B01D2253/116 , B01D2253/204 , B01D2256/245 , B01D2257/304 , B01D2257/504 , B01D2257/80 , B01D2259/40007 , B01J20/226 , B01J20/28057 , B01J20/28069 , B01J20/3425 , B01J20/3483 , B01J20/3491 , C07F5/066 , C07F9/00 , C07F15/02 , C07F15/04 , Y02C10/08
Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.
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6.
公开(公告)号:US20170246584A1
公开(公告)日:2017-08-31
申请号:US15507411
申请日:2015-09-02
Inventor: Mohamed EDDAOUDI , Youssef BELMABKHOUT , Osama SHEKHAH
IPC: B01D53/02 , B01J20/22 , A61M16/22 , H01M8/0668
CPC classification number: B01D53/02 , A61M16/22 , B01D2253/204 , B01D2257/504 , B01D2258/0283 , B01D2258/06 , B01D2259/4533 , B01J20/226 , B01J20/28057 , B01J20/28083 , B01J2220/62 , H01M8/0668 , Y02C10/08
Abstract: In general, this disclosure describes techniques for removing trace and low concentration CO2 from fluids using SIFSIX-n-M MOFs, wherein n is at least two and M is a metal. In some embodiments, the metal is zinc or copper. Embodiments include devices comprising SIFSIX-n-M MOFs for removing CO2 from fluids. In particular, embodiments relate to devices and methods utilizing SIFSIX-n-M MOFs for removing CO2 from fluids, wherein CO2 concentration is trace. Methods utilizing SIFSIX-n-M MOFs for removing CO2 from fluids can occur in confined spaces. SIFSIX-n-M MOFs can comprise bidentate organic ligands. In a specific embodiment, SIFSIX-n-M MOFs comprise pyrazine or dipryidilacetylene ligands.
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公开(公告)号:US20240316530A1
公开(公告)日:2024-09-26
申请号:US18187798
申请日:2023-03-22
Inventor: Mohamed EDDAOUDI , Prashant BHATT
CPC classification number: B01J20/226 , B01D53/62 , B01D53/81 , B01J20/3085 , C07F15/04 , B01D2253/204 , B01D2257/504
Abstract: Provided herein are mixed ligand metal organic framework (ML-MOF) materials having rectangular grids characterized by the general formula MaMbF6-n(O/H2O)n(Ligand′)x(Ligand″)y(solvent)z, which are effective for capture of carbon dioxide from a fluid composition.
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公开(公告)号:US20240316508A1
公开(公告)日:2024-09-26
申请号:US18579441
申请日:2022-07-13
Inventor: Mohamed EDDAOUDI , Sheng ZHOU , Osama SHEKHAH , Jiangtao JIA
CPC classification number: B01D71/028 , B01D53/228 , B01D67/0079 , B01D69/108 , B01D2256/245 , B01D2257/102
Abstract: Embodiments include a method of making a continuous metal-organic framework membrane, the method including contacting a rare earth- or zirconium-containing compound, an acid, a solvent, and optionally water sufficient to form a hexanuclear cluster solution, contacting the hexanuclear cluster solution with one or more ditopic ligands sufficient to form a metal-organic framework (MOF) solution, contacting the MOF solution with a support, and applying a current to the MOF solution with support, sufficient to provide a continuous metal-organic framework membrane.
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公开(公告)号:US20240239826A1
公开(公告)日:2024-07-18
申请号:US18152933
申请日:2023-01-11
Inventor: Mohamed EDDAOUDI , Prashant BHATT , Tian JIN
CPC classification number: C07F15/045 , B01J20/226
Abstract: A method for producing a fluorinated pillar metal-organic framework (MOF) materials is provided that avoids the need for high temperatures, and eliminates or substantially eliminates the need to use hydrofluoric acid. A reaction mixture comprising one or more sources of a metal Ma, niobium, fluorine and ligand in a solvent forms the fluorinated pillar MOF materials.
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公开(公告)号:US20240173665A1
公开(公告)日:2024-05-30
申请号:US18060092
申请日:2022-11-30
Inventor: Mohamed EDDAOUDI , Prashant BHATT , Aqil JAMAL
CPC classification number: B01D53/1418 , B01J20/226 , B01D2253/204 , B01D2256/10 , B01D2256/12
Abstract: A method for capturing carbon dioxide (CO2) from a humid gas stream is provided. In certain embodiments, the gas stream is a humid natural gas combine cycle (NGCC) exhaust stream. In certain embodiments, the gas stream is a humid air stream. The humid gas stream comprises CO2 and oxygen (O2). In the method, the humid gas stream is contacted with a metal organic framework (MOF) material KAUST-7. The CO2 from the humid gas stream is captured with the KAUST-7 MOF material to generate a CO2-concentrated gas stream comprising approximately 1-30% of CO2.
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