公开(公告)号：US06258873B1

公开(公告)日：2001-07-10

申请号：US09106621

申请日：1998-06-29

申请人： Kurt B. Gundlach ,  Maura A. Sweeney ,  Luis A. Sanchez ,  Richard L. Colt ,  Melvin D. Croucher

发明人： Kurt B. Gundlach ,  Maura A. Sweeney ,  Luis A. Sanchez ,  Richard L. Colt ,  Melvin D. Croucher

IPC分类号： C09D1100

CPC分类号： C09D11/30 ,  C09D11/20 ,  C09D11/328 ,  C09D11/38 ,  C09D179/04

摘要： Disclosed is an ink composition which comprises water, an acid dye, a monovalent salt, a polyquaternary amine compound, and an optional nonionic or cationic surfactant, said ink being substantially free of organic solvents. The ink is particularly suitable for applications such as ink jet printing and marking pens. The disclosed inks in some embodiments are substantially indelible. Also disclosed is a composition for removing the ink compositions from substrates to which they have been applied which comprises water and a dianionic surfactant, optionally further containing a salt, urea, and/or a viscosity building agent such as a gum.

摘要翻译： 公开了一种油墨组合物，其包含水，酸性染料，单价盐，多季胺化合物和任选的非离子或阳离子表面活性剂，所述油基本上不含有机溶剂。 该油墨特别适用于喷墨打印和标记笔等应用。 在一些实施例中所公开的油墨基本上是不可磨灭的。 还公开了一种用于从其已被施加的基材上除去油墨组合物的组合物，其包含水和二阴离子表面活性剂，任选地还含有盐，尿素和/或粘度建立剂如胶。

公开(公告)号：US5766326A

公开(公告)日：1998-06-16

申请号：US961393

申请日：1997-10-30

申请人： Kurt B. Gundlach ,  Richard L. Colt ,  Luis A. Sanchez ,  Danielle Avolio

发明人： Kurt B. Gundlach ,  Richard L. Colt ,  Luis A. Sanchez ,  Danielle Avolio

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/38

摘要： Disclosed is an ink composition which comprises water, a colorant, 1,4-diazabicyclo�2.2.2!octane, and a fluorinated material selected from the group consisting of (a) those of the formula �(F.sub.2n+1 C.sub.n CH.sub.2 S).sub.2 (CH.sub.3)C--CH.sub.2 CH.sub.2 COO.sup.- !�B.sup.+ !, wherein n is an integer of from about 8 to about 20 and B is a cation, and (b) those of the formula �(F.sub.3 C(F.sub.2 C).sub.n CH.dbd.CHCH.sub.2 OCH(OH)CH.sub.2).sub.2 NCH.sub.2 COO.sup.- !�X.sup.+ !, wherein X is a cation and n is an integer of from about 3 to about 20. Also disclosed are processes for preparing the aforementioned ink and ink jet printing processes employing the aforementioned ink.

摘要翻译： 公开了一种油墨组合物，其包含水，着色剂，1,4-二氮杂双环[2.2.2]辛烷和选自（a）式[（F2n + 1CnCH2S）2（CH3 ）C-CH 2 CH 2 COO - ] [B +]，其中n为约8至约20的整数，B为阳离子，（b）式[（F3C（F2C）nCH = CHCH2OCH（OH）CH2） 2NCH 2 COO - ] [X +]，其中X为阳离子，n为约3至约20的整数。还公开了使用上述油墨制备上述油墨和喷墨印刷方法的方法。

公开(公告)号：US6054505A

公开(公告)日：2000-04-25

申请号：US46852

申请日：1998-03-24

申请人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Richard L. Colt ,  Maura A. Sweeney ,  William M. Schwarz, Jr.

发明人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Richard L. Colt ,  Maura A. Sweeney ,  William M. Schwarz, Jr.

IPC分类号： C09D11/00 ,  C08K3/10 ,  C08K3/28 ,  C08L39/04 ,  C08L39/06

CPC分类号： C09D11/328 ,  C09D11/38

摘要： Disclosed is an ink composition which comprises (1) water; (2) a nonpolymeric salt comprising at least one cation and at least one anion; and (3) a colorant comprising an anionic dye complexed with a polyquaternary amine compound. Also disclosed is an ink composition which comprises (1) water; (2) a nonpolymeric salt comprising at least one cation and at least one anion; (3) an anionic dye; and (4) a polyquaternary amine compound. In one embodiment, the polyquaternary amine compound is selected from the group consisting of polydiallyl ammonium compounds, polyquaternized polyvinylamines, polyquaternized polyallylamines, epichlorohydrin/amine copolymers, cationic amido amine copolymers, copolymers of vinyl pyrrolidinone and a vinyl imidazolium salt, and mixtures thereof.

摘要翻译： 公开了一种油墨组合物，其包含（1）水; （2）包含至少一种阳离子和至少一种阴离子的非聚合盐; 和（3）包含与多季胺化合物络合的阴离子染料的着色剂。 还公开了一种油墨组合物，其包含（1）水; （2）包含至少一种阳离子和至少一种阴离子的非聚合盐; （3）阴离子染料; 和（4）聚季胺化合物。 在一个实施方案中，多季胺化合物选自聚二烯丙基铵化合物，聚季铵化聚乙烯胺，聚季铵化聚烯丙胺，表氯醇/胺共聚物，阳离子酰胺胺共聚物，乙烯基吡咯烷酮和乙烯基咪唑鎓盐的共聚物，及其混合物。

公开(公告)号：US6001899A

公开(公告)日：1999-12-14

申请号：US047097

申请日：1998-03-24

申请人： Kurt B. Gundlach ,  Richard L. Colt ,  Luis A. Sanchez ,  Maura A. Sweeney ,  Edward J. Radigan, Jr.

发明人： Kurt B. Gundlach ,  Richard L. Colt ,  Luis A. Sanchez ,  Maura A. Sweeney ,  Edward J. Radigan, Jr.

IPC分类号： C09D11/00 ,  C09D179/04 ,  C09D11/02 ,  C09D11/10

CPC分类号： C09D11/30 ,  C09D179/04

摘要： Disclosed is an ink composition which comprises water, an anionic dye, and a polyquaternary amine compound selected from the group consisting of polydiallyl ammonium compounds, polyquaternized polyvinylamines, polyquaternized polyallylamines, and mixtures thereof. Also disclosed are methods for using the aforementioned ink composition in ink jet printing processes.

摘要翻译： 公开了一种油墨组合物，其包含水，阴离子染料和选自聚二烯丙基铵化合物，聚季铵化聚乙烯胺，聚季铵化聚烯丙基胺及其混合物的聚季胺化合物。 还公开了在喷墨印刷方法中使用上述油墨组合物的方法。

公开(公告)号：US5855656A

公开(公告)日：1999-01-05

申请号：US961118

申请日：1997-10-30

申请人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Cheryl A. Hanzlik ,  Kathy-Jo Brodsky ,  Richard L. Colt ,  Aileen M. Montes ,  Rachael L. McGrath ,  Danielle Avolio

发明人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Cheryl A. Hanzlik ,  Kathy-Jo Brodsky ,  Richard L. Colt ,  Aileen M. Montes ,  Rachael L. McGrath ,  Danielle Avolio

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/38

摘要： Disclosed is an ink composition which comprises (a) water, (b) a colorant, and (c) a material of the formula �(F.sub.3 C(F.sub.2 C).sub.n CH.dbd.CHCH.sub.2 OCH(OH)CH.sub.2).sub.2 NCH.sub.2 COO.sup.- !�X.sup.+ !, wherein X is a cation and n is an integer of from about 3 to about 20. Also disclosed are processes for preparing the ink composition and ink jet printing processes with the ink composition.

摘要翻译： 公开了一种油墨组合物，其包含（a）水，（b）着色剂和（c）式[（F3C（F2C）nCH = CHCH2OCH（OH）CH2）2NCH2COO - ] [X +]的材料，其中X 是阳离子，n是约3至约20的整数。还公开了用油墨组合物制备油墨组合物和喷墨印刷方法的方法。

公开(公告)号：US5810916A

公开(公告)日：1998-09-22

申请号：US960792

申请日：1997-10-30

申请人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Richard L. Colt ,  Danielle Avolio

发明人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Richard L. Colt ,  Danielle Avolio

IPC分类号： B41M5/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/30

摘要： Disclosed is an ink composition which comprises (a) water, (b) a colorant selected from the group consisting of Acid Yellow 23, Acid Yellow 17, Reactive Red 180, Direct Blue 199, Acid Blue 9, and mixtures thereof, (c) imidazole, (d) an additive selected from the group consisting of betaine, polyethylene oxide, and mixtures thereof, and (e) a material of the formula �(F.sub.3 C(F.sub.2 C).sub.n CH.dbd.CHCH.sub.2 OCH(OH)CH.sub.2).sub.2 NCH.sub.2 COO-!�X+!, wherein X is a cation and n is an integer of from about 3 to about 20. Also disclosed are ink jet printing processes employing the aforementioned ink.

摘要翻译： 公开了一种油墨组合物，其包含（a）水，（b）选自酸性黄23，酸性黄17，活性红180，直接蓝199，酸性蓝9及其混合物的着色剂，（c） 咪唑，（d）选自甜菜碱，聚环氧乙烷及其混合物的添加剂，和（e）式[（F3C（F2C）nCH = CHCH2OCH（OH）CH2）2NCH2COO - ] [X + ]，其中X为阳离子，n为约3至约20的整数。还公开了采用上述油墨的喷墨印刷方法。

公开(公告)号：US5888285A

公开(公告)日：1999-03-30

申请号：US961173

申请日：1997-10-30

申请人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Rachael L. McGrath ,  Richard L. Colt

发明人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Rachael L. McGrath ,  Richard L. Colt

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/38

摘要： Disclosed is an ink composition which comprises water, a colorant, a bisquaternary ammonium compound, and a material of the formula �(F.sub.3 C(F.sub.2 C).sub.n CH.dbd.CHCH.sub.2 OCH(OH)CH.sub.2).sub.2 NCH.sub.2 COO.sup.- !�X.sup.+ !, wherein X is a cation and n is an integer of from about 3 to about 20. Also disclosed are ink jet printing processes employing the aforementioned ink.

摘要翻译： 公开了一种油墨组合物，其包含水，着色剂，双季铵化合物和式[（F3C（F2C）nCH = CHCH2OCH（OH）CH2）2NCH2COO - ] [X +]的材料，其中X为阳离子， n为约3至约20的整数。还公开了采用上述油墨的喷墨印刷方法。

公开(公告)号：US5776230A

公开(公告)日：1998-07-07

申请号：US960991

申请日：1997-10-30

申请人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Richard L. Colt

发明人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Richard L. Colt

IPC分类号： B41M5/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/328

摘要： Disclosed is an ink composition which comprises water, a dye selected from the group consisting of Direct Blue 199, Direct Yellow 132, Acid Yellow 17, Reactive Red 180, Acid Red 52, and mixtures thereof, and a material of the formula �(F.sub.3 C(F.sub.2 C).sub.n CH.dbd.CHCH.sub.2 OCH(OH)CH.sub.2).sub.2 NCH.sub.2 COO.sup.- !�X.sup.+ !, wherein X is a cation and n is an integer of from about 3 to about 20, wherein the ink is substantially free of imidazole. Also disclosed are ink jet printing processes employing the aforementioned ink.

摘要翻译： 公开了一种油墨组合物，其包含水，选自直接蓝199，直接黄132，酸性黄17，活性红180，酸性红52及其混合物的染料，以及式[（F3C） （F2C）nCH = CHCH2OCH（OH）CH2）2NCH2COO - ] [X +]，其中X为阳离子，n为约3至约20的整数，其中油墨基本上不含咪唑。 还公开了采用上述油墨的喷墨印刷方法。

公开(公告)号：US5772743A

公开(公告)日：1998-06-30

申请号：US961435

申请日：1997-10-30

申请人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Cheryl A. Hanzlik ,  Kathy-Jo Brodsky ,  Richard L. Colt ,  Aileen M. Montes ,  Edward J. Radigan, Jr.

发明人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Cheryl A. Hanzlik ,  Kathy-Jo Brodsky ,  Richard L. Colt ,  Aileen M. Montes ,  Edward J. Radigan, Jr.

IPC分类号： B41J2/215 ,  B41M5/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/38

摘要： Disclosed is an ink composition which comprises (a) water, (b) a colorant, (c) a fluorinated material selected from: (1) those of the formula �(F.sub.2n+1 C.sub.n CH.sub.2 S).sub.2 (CH.sub.3)C--CH.sub.2 CH.sub.2 COO.sup.- !�B.sup.+ !, wherein n is an integer of from about 8 to about 20 and B is a cation, (2) those of the formula �(F.sub.3 C(F.sub.2 C).sub.n CH.dbd.CHCH.sub.2 OCH(OH)CH.sub.2).sub.2 NCH.sub.2 COO.sup.- !�X.sup.+ !, wherein X is a cation and n is an integer of from about 3 to about 20, and (3) mixtures thereof, and (d) a monomeric compound having at least two carboxylic acid functional groups. Also disclosed is a process for preparing said ink composition which comprises (i) admixing the ink ingredients, and (ii) subjecting the mixture thus formed to ultrasonification, thereby reducing the average particle diameter of liposomes of the fluorinated material in the ink. Further disclosed is a process which entails (i) incorporating into an ink jet printing apparatus the aforementioned ink composition, and (ii) causing droplets of the ink composition to be ejected in an imagewise pattern onto a substrate. In a preferred embodiment, the printing apparatus employs a thermal ink jet process wherein the ink in the nozzles is selectively heated in an imagewise pattern, thereby causing droplets of the ink to be ejected in imagewise pattern.

摘要翻译： 公开了一种油墨组合物，其包含（a）水，（b）着色剂，（c）选自以下的氟化材料：（1）式[（F2n + 1CnCH2S）2（CH3）C-CH2CH2COO - ] [ B +]，其中n为约8至约20的整数，B为阳离子，（2）式[（F3C（F2C）nCH = CHCH2OCH（OH）CH2）2NCH2COO - ] [X +]的那些，其中 X是阳离子，n是约3至约20的整数，和（3）它们的混合物，和（d）具有至少两个羧酸官能团的单体化合物。 还公开了一种制备所述油墨组合物的方法，其包括（i）混合油墨成分，和（ii）使由此形成的混合物经过超声处理，从而降低油墨中氟化材料的脂质体的平均粒径。 进一步公开的方法是（i）将上述油墨组合物结合到喷墨打印设备中，和（ii）使油墨组合物的液滴以成像图案喷射到基材上。 在优选实施例中，印刷设备采用热喷墨工艺，其中喷嘴中的油墨以成像图案选择性加热，从而使油墨的液滴以成像图案喷射。

公开(公告)号：US5769929A

公开(公告)日：1998-06-23

申请号：US961637

申请日：1997-10-31

申请人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Cheryl A. Hanzlik ,  Kathy-Jo Brodsky ,  Richard L. Colt ,  Aileen M. Montes

发明人： Kurt B. Gundlach ,  Luis A. Sanchez ,  Cheryl A. Hanzlik ,  Kathy-Jo Brodsky ,  Richard L. Colt ,  Aileen M. Montes

IPC分类号： B41M5/00 ,  C09D11/00 ,  C09D11/02

CPC分类号： C09D11/328

摘要： Disclosed is an ink composition which comprises water, an anionic dye having at least one anionic functional group and having a cationic counterion associated with each anionic functional group, and a material of the formula �(F.sub.2n+1 C.sub.n CH.sub.2 S).sub.2 (CH.sub.3)C--CH.sub.2 CH.sub.2 COO--!�B+!, wherein n is an integer of from about 8 to about 20 and B is a cation, said ink composition containing alkali metal cations in an amount of no more than about 1.times.10.sup.-3 moles per liter. Also disclosed are ink jet printing processes employing the aforementioned ink.

摘要翻译： 公开了一种油墨组合物，其包含水，具有至少一个阴离子官能团并具有与每个阴离子官能团相关的阳离子抗衡离子的阴离子染料和式[（F2n + 1CnCH2S）2（CH3）C-CH2CH2COO - ] [B +]，其中n为约8至约20的整数，B为阳离子，所述油墨组合物含有不超过约1×10 -3摩尔/升的碱金属阳离子。 还公开了采用上述油墨的喷墨印刷方法。