公开(公告)号：US20150080595A1

公开(公告)日：2015-03-19

申请号：US14326886

申请日：2014-07-09

Applicant: Momentive Performance Materials Inc.

Inventor： Tiberiu Ladislau Simandan ,  Andrea Trotto ,  Ilaria Vecchi ,  Ottavio Ursitti

IPC: C07F7/18

CPC classification number: C07F7/1876 ,  A61B17/07207 ,  A61B17/28 ,  A61B17/29 ,  A61B18/1445 ,  A61B2017/0023 ,  A61B2018/00059 ,  A61B2018/00065 ,  A61B2018/1457 ,  A61B2090/081 ,  A61B2090/0814 ,  A61F2250/009 ,  B01J31/0239 ,  B01J31/1633 ,  B01J2231/49 ,  C07F7/1804 ,  C07F7/1892 ,  Y02P20/582 ,  Y02P20/588

Abstract: The invention is directed to a process for the preparation of thiocarboxylate silane comprising reacting an aqueous solution of a salt of a thiocarboxylic acid with a haloalkylalkoxysilane in the presence of a solid supported catalyst. The invention is also directed to a process for the preparation of an aqueous solution of a salt of a thiocarboxylic acid which comprises reacting an aqueous solution of a sulfide and/or hydrosulfide with a carboxylic acid halide and/or acid anhydride.

Abstract translation: 本发明涉及一种制备硫代羧酸盐硅烷的方法，包括在固体负载催化剂存在下使硫代羧酸的盐的水溶液与卤代烷基烷氧基硅烷反应。 本发明还涉及制备硫代羧酸盐的水溶液的方法，其包括使硫化物和/或氢硫化物的水溶液与羧酸卤化物和/或酸酐反应。

公开(公告)号：US09206203B2

公开(公告)日：2015-12-08

申请号：US14226345

申请日：2014-03-26

Applicant: Momentive Performance Materials Inc.

Inventor： Tiberiu Ladislau Simandan ,  Ilaria Vecchi ,  Holger Jurgen Glatzer

IPC: C07F7/04 ,  C07F7/08 ,  C07C51/41 ,  C07C327/06 ,  C07F7/18 ,  C07C327/16 ,  B01J31/02

CPC classification number: C07F7/081 ,  B01J31/0239 ,  B01J31/0254 ,  C07C51/41 ,  C07C327/06 ,  C07C327/16 ,  C07F7/1804 ,  C07F7/1892 ,  Y02P20/582

Abstract: The invention is directed to a process for the preparation of thiocarboxylate silane comprising reacting an aqueous solution of a salt of a thiocarboxylic acid with a haloalkyl silane in the presence of a solid inorganic oxide-supported phase transfer catalyst. The invention is also directed to a process for the preparation of an aqueous solution of a salt of a thiocarboxylic acid which comprises reacting an aqueous solution of a sulfide and/or hydrosulfide with an acid halide in the presence of a said solid catalyst.

Abstract translation: 本发明涉及一种制备硫代羧酸盐硅烷的方法，包括在固体无机氧化物负载型相转移催化剂存在下使硫代羧酸的盐的水溶液与卤代烷基硅烷反应。 本发明还涉及制备硫代羧酸盐的水溶液的方法，其包括在所述固体催化剂存在下使硫化物和/或氢硫化物的水溶液与酰卤反应。

公开(公告)号：US09193742B2

公开(公告)日：2015-11-24

申请号：US14326886

申请日：2014-07-09

Applicant: Momentive Performance Materials Inc.

Inventor： Tiberiu Ladislau Simandan ,  Andrea Trotto ,  Ilaria Vecchi ,  Ottavio Ursitti

IPC: C07F7/18 ,  B01J31/02

CPC classification number: C07F7/1876 ,  A61B17/07207 ,  A61B17/28 ,  A61B17/29 ,  A61B18/1445 ,  A61B2017/0023 ,  A61B2018/00059 ,  A61B2018/00065 ,  A61B2018/1457 ,  A61B2090/081 ,  A61B2090/0814 ,  A61F2250/009 ,  B01J31/0239 ,  B01J31/1633 ,  B01J2231/49 ,  C07F7/1804 ,  C07F7/1892 ,  Y02P20/582 ,  Y02P20/588

Abstract: The invention is directed to a process for the preparation of thiocarboxylate silane comprising reacting an aqueous solution of a salt of a thiocarboxylic acid with a haloalkylalkoxysilane in the presence of a solid supported catalyst. The invention is also directed to a process for the preparation of an aqueous solution of a salt of a thiocarboxylic acid which comprises reacting an aqueous solution of a sulfide and/or hydrosulfide with a carboxylic acid halide and/or acid anhydride.

Abstract translation: 本发明涉及一种制备硫代羧酸盐硅烷的方法，包括在固体负载催化剂存在下使硫代羧酸的盐的水溶液与卤代烷基烷氧基硅烷反应。 本发明还涉及制备硫代羧酸盐的水溶液的方法，其包括使硫化物和/或氢硫化物的水溶液与羧酸卤化物和/或酸酐反应。