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1.发明申请公开(公告)号：US20150361112A1
公开(公告)日：2015-12-17
申请号：US14737930
申请日：2015-06-12
Applicant: Momentive Performance Materials Inc.
Inventor： Aroop Kumar Roy , Julie L. Boyer , Juergen Koller , David Jenkins , Andrea Trotto , Kenrick M. Lewis
CPC classification number: C07F7/0829 , C07F7/0879 , C07F7/12 , C07F7/14 , C07F7/1804
Abstract: A process for the hydrosilylation of an unsaturated compound comprising reacting (a) a silyl hydride with (b) an unsaturated compound in the presence of (c) a platinum compound and (d) a cyclodiene, with the provisos that (i) when the unsaturated compound is a terminal alkyne, the silyl hydride is other than a halosilane, and (ii) when the platinum compound is a Pt(II)-based compound, the ratio of total moles of cyclodiene to moles of platinum is less than 3:1.
Abstract translation: 一种不饱和化合物的氢化硅烷化方法，包括在（c）铂化合物和（d）环二烯的存在下使（a）甲硅烷基氢化物与（b）不饱和化合物反应，条件是（ⅰ）当 不饱和化合物是末端炔烃，甲硅烷基氢化物不是卤代硅烷，（ii）当铂化合物是基于Pt（II）的化合物时，环二烯的总摩尔数与铂的摩尔数之比小于3： 1。
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2.发明授权Hydrosilylation synthesis of haloalkylorganosilanes using peroxide promoters 有权使用过氧化物促进剂的卤代烷基有机硅烷的氢化硅烷化合成公开(公告)号：US09556208B2
公开(公告)日：2017-01-31
申请号：US13650557
申请日：2012-10-12
Applicant: Momentive Performance Materials Inc.
Inventor： Kenrick Martin Lewis , Jitendra Singh Rathore , Andrea Trotto , Giuseppe D'Agostino
IPC: C07F7/18
CPC classification number: C07F7/1804 , C07F7/1876 , Y02P20/582
Abstract: This invention is directed to a process for producing a haloorganoalkoxysilane product comprising reacting an olefinic halide, an alkoxysilane, a catalytically effective amount of ruthenium-containing catalyst; and a reaction-promoting effective amount of a peroxy compound, optionally in the presence of an electron-deficient aromatic compound.
Abstract translation: 本发明涉及一种制备卤代有机烷氧基硅烷产物的方法，包括使烯卤化物，烷氧基硅烷，催化有效量的含钌催化剂反应; 和反应促进有效量的过氧化合物，任选地在电子缺乏芳族化合物的存在下。
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公开(公告)号：US20150080595A1
公开(公告)日：2015-03-19
申请号：US14326886
申请日：2014-07-09
Applicant: Momentive Performance Materials Inc.
Inventor： Tiberiu Ladislau Simandan , Andrea Trotto , Ilaria Vecchi , Ottavio Ursitti
IPC: C07F7/18
CPC classification number: C07F7/1876 , A61B17/07207 , A61B17/28 , A61B17/29 , A61B18/1445 , A61B2017/0023 , A61B2018/00059 , A61B2018/00065 , A61B2018/1457 , A61B2090/081 , A61B2090/0814 , A61F2250/009 , B01J31/0239 , B01J31/1633 , B01J2231/49 , C07F7/1804 , C07F7/1892 , Y02P20/582 , Y02P20/588
Abstract: The invention is directed to a process for the preparation of thiocarboxylate silane comprising reacting an aqueous solution of a salt of a thiocarboxylic acid with a haloalkylalkoxysilane in the presence of a solid supported catalyst. The invention is also directed to a process for the preparation of an aqueous solution of a salt of a thiocarboxylic acid which comprises reacting an aqueous solution of a sulfide and/or hydrosulfide with a carboxylic acid halide and/or acid anhydride.
Abstract translation: 本发明涉及一种制备硫代羧酸盐硅烷的方法，包括在固体负载催化剂存在下使硫代羧酸的盐的水溶液与卤代烷基烷氧基硅烷反应。 本发明还涉及制备硫代羧酸盐的水溶液的方法，其包括使硫化物和/或氢硫化物的水溶液与羧酸卤化物和/或酸酐反应。
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Patent Agency Ranking
公开(公告)号：US10294251B2
公开(公告)日：2019-05-21
申请号：US15616091
申请日：2017-06-07
Applicant: Momentive Performance Materials Inc.
Inventor： Alain Lejeune , Antonio Chaves , Tiberiu Simandan , Ilaria Vecchi , Lesley Hwang , Andrea Trotto
Abstract: A transesterification process for preparing alkoxysilane includes removal of metal transesterification catalyst from the alkoxysilane transesterification reaction medium.
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公开(公告)号：US09193742B2
公开(公告)日：2015-11-24
申请号：US14326886
申请日：2014-07-09
Applicant: Momentive Performance Materials Inc.
Inventor： Tiberiu Ladislau Simandan , Andrea Trotto , Ilaria Vecchi , Ottavio Ursitti
CPC classification number: C07F7/1876 , A61B17/07207 , A61B17/28 , A61B17/29 , A61B18/1445 , A61B2017/0023 , A61B2018/00059 , A61B2018/00065 , A61B2018/1457 , A61B2090/081 , A61B2090/0814 , A61F2250/009 , B01J31/0239 , B01J31/1633 , B01J2231/49 , C07F7/1804 , C07F7/1892 , Y02P20/582 , Y02P20/588
Abstract: The invention is directed to a process for the preparation of thiocarboxylate silane comprising reacting an aqueous solution of a salt of a thiocarboxylic acid with a haloalkylalkoxysilane in the presence of a solid supported catalyst. The invention is also directed to a process for the preparation of an aqueous solution of a salt of a thiocarboxylic acid which comprises reacting an aqueous solution of a sulfide and/or hydrosulfide with a carboxylic acid halide and/or acid anhydride.
Abstract translation: 本发明涉及一种制备硫代羧酸盐硅烷的方法，包括在固体负载催化剂存在下使硫代羧酸的盐的水溶液与卤代烷基烷氧基硅烷反应。 本发明还涉及制备硫代羧酸盐的水溶液的方法，其包括使硫化物和/或氢硫化物的水溶液与羧酸卤化物和/或酸酐反应。
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公开(公告)号：US20170355720A1
公开(公告)日：2017-12-14
申请号：US15616091
申请日：2017-06-07
Applicant: Momentive Performance Materials Inc.
Inventor： Alain Lejeune , Antonio Chaves , Tiberiu Simandan , Ilaria Vecchi , Lesley HWANG , Andrea Trotto
IPC: C07F7/18
CPC classification number: C07F7/188 , C07F7/1804 , C07F7/20
Abstract: A transesterification process for preparing alkoxysilane includes removal of metal transesterification catalyst from the alkoxysilane transesterification reaction medium.
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7.发明授权公开(公告)号：US09434749B2
公开(公告)日：2016-09-06
申请号：US14737930
申请日：2015-06-12
Applicant: Momentive Performance Materials Inc.
Inventor： Aroop Kumar Roy , Julie L. Boyer , Juergen Koller , David Jenkins , Andrea Trotto , Kenrick M. Lewis
CPC classification number: C07F7/0829 , C07F7/0879 , C07F7/12 , C07F7/14 , C07F7/1804
Abstract: A process for the hydrosilylation of an unsaturated compound comprising reacting (a) a silyl hydride with (b) an unsaturated compound in the presence of (c) a platinum compound and (d) a cyclodiene, with the provisos that (i) when the unsaturated compound is a terminal alkyne, the silyl hydride is other than a halosilane, and (ii) when the platinum compound is a Pt(II)-based compound, the ratio of total moles of cyclodiene to moles of platinum is less than 3:1.
Abstract translation: 一种不饱和化合物的氢化硅烷化方法，包括在（c）铂化合物和（d）环二烯的存在下使（a）甲硅烷基氢化物与（b）不饱和化合物反应，条件是（ⅰ）当 不饱和化合物是末端炔烃，甲硅烷基氢化物不是卤代硅烷，（ii）当铂化合物是基于Pt（II）的化合物时，环二烯的总摩尔数与铂的摩尔数之比小于3： 1。
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8.发明申请Hydrosilylation Synthesis of Haloalkylorganosilanes Using Peroxide Promoters 有权使用过氧化物启动子的氢化烷基有机硅烷的氢化硅烷化合成公开(公告)号：US20140107366A1
公开(公告)日：2014-04-17
申请号：US13650557
申请日：2012-10-12
Applicant: Momentive Performance Materials Inc.
Inventor： Kenrick Martin Lewis , Jitendra Singh Rathore , Andrea Trotto , Giuseppe D'Agostino
IPC: C07F7/18
CPC classification number: C07F7/1804 , C07F7/1876 , Y02P20/582
Abstract: This invention is directed to a process for producing a haloorganoalkoxysilane product comprising reacting an olefinic halide, an alkoxysilane, a catalytically effective amount of ruthenium-containing catalyst; and a reaction-promoting effective amount of a peroxy compound, optionally in the presence of an electron-deficient aromatic compound.
Abstract translation: 本发明涉及一种制备卤代有机烷氧基硅烷产物的方法，包括使烯卤化物，烷氧基硅烷，催化有效量的含钌催化剂反应; 和反应促进有效量的过氧化合物，任选地在电子缺乏芳族化合物的存在下。
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