公开(公告)号：US20240228686A1

公开(公告)日：2024-07-11

申请号：US17928012

申请日：2022-01-19

Applicant: Qingdao University of Technology

Inventor： Dongshuai HOU ,  Cong WU ,  Bing YIN ,  Shaochun LI ,  Xinpeng WANG ,  Pan WANG

IPC: C08F265/06 ,  C09D5/08 ,  C09D151/00

CPC classification number: C08F265/06 ,  C09D5/08 ,  C09D151/003

Abstract: The present disclosure provides a styrene acrylate-siloxane composite emulsion with a core-shell structure, and a preparation method and use thereof, and relates to the technical field of protective coatings. In the present disclosure, a core emulsion is prepared through two-step emulsification with styrene, an acrylate monomer, a first emulsifying agent, a first initiator, a second initiator, an alkaline reagent, and water as raw materials; then a shell emulsion is prepared with a siloxane monomer, a hydroxyl-containing acrylate monomer, an emulsifying agent, and water as raw materials; and then the core emulsion, the shell emulsion, and an initiator are subjected to a grafting reaction to obtain the styrene acrylate-siloxane composite emulsion with a core-shell structure.

公开(公告)号：US20240384055A1

公开(公告)日：2024-11-21

申请号：US18035093

申请日：2022-01-19

Applicant: QINGDAO UNIVERSITY OF TECHNOLOGY

Inventor： Dongshuai HOU ,  Cong WU ,  Bing YIN ,  Shaochun LI ,  Xinpeng WANG ,  Pan WANG

IPC: C08K3/04 ,  C08F2/22 ,  C08F220/18

Abstract: The present disclosure relates to the technical field of protective coatings, and provides a graphene oxide (GO)-modified styrene-acrylic Pickering emulsion and a composite emulsion, and preparation methods and use. In the present disclosure, GO is added during polymerization of a styrene-acrylic monomer, and the GO is attached to an interface of a styrene-acrylic core while forming the styrene-acrylic core; and the GO is “stitched” at the interface of the styrene-acrylic core by a silane coupling agent, thus giving the GO a better dispersion effect. After adding a shell phase emulsion, a part of the styrene-acrylic core that is not completely wrapped by a GO sheet may be grafted with a shell phase, and cross-linking between a core phase and the shell phase can further enhance a steric stability of the GO; and the GO can fully connect the styrene-acrylic core with a siloxane shell, improving the molecular configuration of a siloxane component. In the composite emulsion, GO has desirable dispersibility and is not easy to agglomerate, such that the composite emulsion has an excellent performance and can significantly improve the durability of a cement-based material.